A method for harmless treatment of electroplating sludge using metallurgical sintering blast furnace
A technology of harmless treatment and electroplating sludge, applied in blast furnaces, blast furnace details, furnaces, etc., can solve the problems of incomplete treatment of metallurgical waste, environmental pollution of electroplating sludge, etc., prevent secondary diffusion pollution, and have obvious environmental benefits , Improve the effect of detoxification effect
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example 1
[0068] Example 1: 40% electroplating sludge and 60% reducing metallurgical waste are used as raw materials for the ball core, the weight of the ball core is 1 kg, and the particle size is (3-6) mm. 30% (0.3kg) of the weight of the core is added with a pre-coating material (gravity dust removal) for pre-coating. Then the ball core is pre-coated according to the weight ratio of 1:1 (1.3kg) to cover the spherical shell with sulfuric acid Slag and sintering dust to form secondary composite pellets. After sintering, the hexavalent chromium is 1.31mg / L (less than the national standard 5mg / L), and the nickel is 0.5mg / L (less than the national standard 5mg / L).
example 2
[0070] Example 2: 50% of electroplating sludge and 50% of reducing metallurgical waste are used as raw materials for the core, the weight of the core is 1 kg, and the particle size is (3-6) mm; 25% (0.25 kg) of the weight of the core is added with pre-coating material (gravity dust removal) for pre-coating. Then, according to the ratio of 1:1 (1.25kg) of the pre-coated ball core, add spherical shell material sulfuric acid slag and sintering dust to form a secondary composite pellet. After sintering, it is detected that the hexavalent chromium is 1.5mg / L (less than the national standard 5mg / L), and the nickel is 1.1mg / L (less than the national standard 5mg / L)
[0071] Comparative example: 50% of electroplating sludge and 50% of reducing metallurgical waste are used as raw materials for the ball core, the weight of the ball core is 1 kg, and the particle size is (3-6) mm; After sintering, it was detected that hexavalent chromium was 2.80mg / L and nickel was 1.98mg / L.
example 3
[0072] Example 3: 60% of electroplating sludge and 40% of reducing metallurgical waste are used as raw materials for the ball core, the weight of the ball core is 1 kg, and the particle size is (3-6) mm; pre-coating material gravity dust is added according to 40% of the weight of the ball core material 0.4kg, pre-coated. Then add the sulfuric acid slag of the spherical shell material and 2.8 kg of sintering dedusting ash according to the weight ratio of 1:2 to the pre-coated ball core to form a secondary composite pellet. After sintering, the hexavalent chromium is 0.21mg / L (less than the national standard 5mg / L), and the nickel is 0.8mg / L (less than the national standard 5mg / L).
[0073] Comparative example: 60% of electroplating sludge and 40% of reducing metallurgical waste are used as raw materials for the ball core, the weight of the ball core is 1kg, and the particle size is (3-6) mm; then the spherical shell material is added in a ratio of 1:2 to the weight of the spher...
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