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A method for removing dyestuffs in waste water by using camellia oleifera cake

A technology for camellia cake and wastewater, which is applied in chemical instruments and methods, water/sewage treatment, adsorbed water/sewage treatment, etc., to achieve the effects of low price, abundant sources and simple operation

Active Publication Date: 2016-05-18
山西晋精晟达环保设备有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

At present, oil tea cake has been used as heavy metal nickel (Ran Xiuzhi, Yuan Hongjiang, Quan Xuejun. Camellia oleifera cake biosorbent for Ni 2+ Adsorption properties of [J]. Acta Chemical Industry. 2011 (04): 986-993.) Adsorbent research, but the use of oil tea cake treatment of dye wastewater has not been reported

Method used

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  • A method for removing dyestuffs in waste water by using camellia oleifera cake
  • A method for removing dyestuffs in waste water by using camellia oleifera cake
  • A method for removing dyestuffs in waste water by using camellia oleifera cake

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] The camellia cake that has been washed with distilled water to remove impurities is baked at 100°C for 12 hours, crushed, and sieved to a particle size of 0.3-0.6mm to obtain the camellia cake adsorbent A.

[0034] Get the camellia cake adsorbent A and sodium chloride and add the pH value to be 1, 2, 3, 5, 7, 9, 11 respectively, in the wastewater containing 300mg / L active red 15, wherein, the camellia cake adsorbent A is in the waste water The content is 2g / L, and the mass percentage of sodium chloride is 2%. After stirring or shaking at 20°C for 24 hours, filter and separate, adjust the filtrate to neutral and discharge it, and complete the adsorption of reactive red 15 in wastewater.

[0035] The influence of the initial pH of wastewater on the removal effect of reactive red 15 is as follows: figure 1 shown. Depend on figure 1 It can be seen that pH has a great influence on the removal effect of reactive red 15. When the initial pH value increased from 1 to 5, the ...

Embodiment 2

[0037] The camellia cake that has been washed with distilled water to remove impurities is baked at 100°C for 24 hours, then crushed and sieved to a particle size of 0.3-0.6mm to obtain the camellia cake adsorbent B.

[0038] Get camellia oleifera cake adsorbent B and add pH=1, contain 300mg / L active red 15, in the waste water that the mass percent concentration of sodium chloride is respectively 0%, 2%, 5%, 10%, 20%, 30%, wherein, The content of Camellia Cake Adsorbent B in wastewater is 3g / L. After stirring or shaking at 35°C for 24 hours, filter and separate, adjust the filtrate to neutral and discharge it to complete the adsorption of reactive red 15 in wastewater.

[0039] The influence of sodium chloride concentration on the removal effect of reactive red 15 is as follows figure 2 As shown, it can be seen that with the gradual increase of the mass concentration of sodium chloride, the ability of the camellia cake adsorbent B to adsorb and remove reactive red 15 decrease...

Embodiment 3

[0041] The camellia cake that has been washed with distilled water to remove impurities is baked at 80°C for 24 hours, crushed, and sieved to a particle size of 0.3-0.6mm to obtain the camellia cake adsorbent C.

[0042] Take camellia oleifera cake adsorbent C and add it to pH=1, respectively containing 100, 150, 200, 250, 300mg / L active red 15 in the waste water, wherein, the content of camellia oleifera cake adsorbent C in waste water is 6g / L, under 50 ℃ After stirring or shaking for 24 hours, separate by filtration, adjust the filtrate to neutrality and discharge.

[0043] The effect of the initial concentration of reactive red 15 on the removal effect of reactive red 15 is as follows: image 3 As shown, it can be seen that a considerable proportion of reactive red 15 is removed within the initial 30 minutes, indicating that the method for adsorbing and removing reactive red 15 of the present invention is efficient and rapid. As the initial concentration of Reactive Red 15...

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Abstract

The invention relates to a method for removing dyes in wastewater by using an oil-tea cake, belonging to the technical field of wastewater treatment. The method comprises the following steps: cleaning the oil-tea cake, and grinding and screening to obtain an oil-tea cake adsorbent; adding the oil-tea cake adsorbent into the wastewater containing reactive red 15 and sodium chloride, stirring or vibrating for 24 hours at 20-50 DEG C, filtering and separating, regulating filtrate to be neutral, and then discharging to complete the adsorption of reactive red 15 in the wastewater. According to the method disclosed by the invention, in a process that the reactive red 15 dyes in the wastewater are removed by the oil-tea cake adsorbent by virtue of adsorption, the maximum mono-molecular layer adsorption quantity of the reactive red 15 dyes at 20 DEG C is 74.63mg / g; the method is simple to operate, is low in cost, and is efficient and environment-friendly.

Description

technical field [0001] The invention belongs to the technical field of waste water treatment, and relates to a method for removing dyes in waste water by using camellia oleifera cake, in particular to a method for removing active red 15 dye in waste water by using camellia oleifera cake adsorbent. Background technique [0002] Printing and dyeing wastewater is one of the main harmful industrial wastewater in my country. According to the source, it is divided into printing and dyeing industrial wastewater and dye production wastewater. According to statistics, there are now more than 10,000 kinds of commercial dyes widely used in industries such as textiles, papermaking, rubber, plastics, leather, cosmetics, pharmaceuticals and food industries. Such widespread use of dyes has led to the discharge of large amounts of dye wastewater into natural water bodies. Most of the pollutants in dye wastewater are synthetic organic matter, which is difficult to treat and has poor biodegr...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C02F1/28C02F1/58
Inventor 高景峰司春英李洪禹
Owner 山西晋精晟达环保设备有限公司