Chemically amplified i-line positive photoresist composition containing diphenol acetal polymer

A photoresist and acetal polymer technology is applied in the field of offset printing ultraviolet photosensitive computer-to-plate imaging materials and chemically amplified i-line positive photoresist compositions, and can solve the problem of low resolution, Can not meet the high resolution and high sensitivity, low sensitivity and other issues
CN104181775AInactive Publication Date: 2014-12-03HANDAN DEV ZONE LIYE CHEM

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
HANDAN DEV ZONE LIYE CHEM
Publication Date
2014-12-03
Estimated Expiration
Not applicable · inactive patent

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Abstract

The invention relates to a novel chemically amplified i-line positive photoresist composition which mainly comprises (A) a diphenol divinyl ether acetal polymer obtained by reaction of a diphenol compound with various divinyl ether compounds, wherein the acetal polymer is easily subjected to acid-induced decomposition reaction; (B) a 2,1,4-diazo naphthoquinone sulfonate photosensitizer obtained by esterifying 2,1,4-diazo naphthoquinone sulfonyl chloride and a phenolic compound, wherein the photosensitizer can generate a small amount of sulfonic acid under illumination and cause acidolysis of the acetal polymer and also can serve as a photo-acid generator; and (C) a phenolic resin. The chemically amplified i-line positive light-sensitive imaging material has the advantages of high sensitivity, high resolution ratio, high transparency and the like and can be used for near ultraviolet photoresists and offset print ultraviolet light-sensitive computer-to-plate (CTP) imaging materials for semiconductor processing.
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Description

technical field

[0001] The technical field to which the invention belongs is the field of polymer photosensitive imaging materials. Specifically, the present invention relates to a novel chemically amplified i-line positive photoresist composition, and this type of novel photosensitive imaging material can be used for semiconductor processing near-ultraviolet positive photoresist (also It is called photoresist), and can also be used for offset printing of ultraviolet photosensitive computer-to-plate (CTP) imaging materials. Background technique

[0002] The diazonaphthoquinone sulfonate-novolac resin system is the mainstream photoresist for i-line (365nm) lithography technology. This is a non-chemical amplification system, which is a photodecomposition photosensitive material with novolac resin as the film-forming material and diazonaphthoquinone sulfonate product as the photosensitive component. The imaging principle is that the diazo group of diazonaphthoquinone sulfonat...

Claims

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