Tire rubber composite and pneumatic tire

A technology for rubber composition and tire, applied in the field of rubber composition for tires and pneumatic tires, can solve the problems of reduced wear resistance, poor dispersibility, low carbon black reinforcement, etc., and achieves improved wear resistance and improved dispersion. improved performance, wet grip and abrasion resistance

Active Publication Date: 2014-12-24
THE YOKOHAMA RUBBER CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, silica has a silanol group on its surface, which is easy to aggregate, and because it lacks affinity with diene rubber, there are cases where the dispersibility becomes insufficient. The problem of sufficiently obtaining the effect of improving the dynamic viscoelastic properties such as the loss tangent (tan δ) of the rubber composition
In addition, silica may be less reinforcing than carbon black and may have insufficient wear resistance, and if the dispersibility is poor, there is a problem that the wear resistance will further decrease.

Method used

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  • Tire rubber composite and pneumatic tire
  • Tire rubber composite and pneumatic tire
  • Tire rubber composite and pneumatic tire

Examples

Experimental program
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Embodiment

[0043] Will Figure 4 The shown complexing agents are used as common complexes by Figure 1~3 The 25 kinds of rubber compositions for tires (Examples 1-9, Comparative Examples 1-16) formed by the compounding shown are prepared in the following manner: put the ingredients except sulfur and vulcanization accelerator in a 1.8L internal mixer Mix for 5 minutes, add sulfur and vulcanization accelerator to the discharged masterbatch, and mix with an open mill. in addition, Figure 1~3 In, since the modified S-SBR1 and the unmodified SBR contain 37.5 parts by weight of oil-extending oil, the actual compounding amount is shown in the column of compounding amount, and the net weight of each SBR after removing the oil-extending oil is shown in parentheses. With the amount. In addition, the compounding quantity of aromatic oil was adjusted suitably so that the total oil quantity and / or rubber hardness in a rubber composition may become a comparable level. The ratio of silica to the t...

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Abstract

Provided is a tire rubber composition that has lower rolling resistance, and improved wet performance and abrasion resistance compared to conventional levels. The composition is characterized in that: 2-50 parts by weight of an aromatic modified terpene resin with a softening point of at least 100 DEG C and a total of 60-130 parts by weight of two types of silica, silica X and silica Y, are added to 100 parts by weight of a diene rubber that includes 5-50 wt% of a terminal-modified S-SBR having a vinyl unit content of at least 25 wt% and a glass transition temperature of - 50 DEG C or below; the functional group of the modified S-SBR is reactive with a silanol group; a reinforcing filler comprising of silica X, silica Y and optionally added carbon black includes the silica at a proportion of at least 85 wt%; the specific surface area of silica X as determined by nitrogen absorption is at least 140m<2> / g; the specific surface area of silica Y as determined by nitrogen absorption is 100-140m<2> / g exclusive; and if the respective masses of silica X and silica Y per 100 parts by weight of the diene rubber are expressed as x parts by weight and y parts by weight, the relationship x / 7 < y <=x is satisfied.

Description

technical field [0001] The present invention relates to a rubber composition for tires and a pneumatic tire having low rolling resistance, improved wet grip and wear resistance compared to conventional levels. Background technique [0002] In recent years, for pneumatic tires for passenger cars, the marking (marking method) system established by JATMA (Japan Automobile Tire Manufacturers Association, Japan Automobile Tire Manufacturers Association) has been started, and low rolling resistance and wet road grip are required to be improved. horizontally. In particular, the level of demand for wet grip is very high, and a pneumatic tire satisfying the wet grip class a based on the marking system has not yet been developed. In addition, at the same time, in order to prolong the life of the tire, it is required to improve wear resistance. [0003] Conventionally, in order to improve the balance between low rolling resistance and wet grip, it has been known to incorporate silica...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L15/00B60C1/00C08K3/04C08K3/36C08L47/00
CPCB60C1/0016C08C19/44C08K3/36C08K2201/006C08L15/00C08L57/02C08L93/00Y02T10/86B60C1/00C08K3/04C08L9/06C08L47/00C08L2205/025C08L2205/03
Inventor 武田 慎也
Owner THE YOKOHAMA RUBBER CO LTD
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