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A kind of epoxy plasticizer wastewater treatment method that can improve the performance of biochemical sludge

A technology of epoxy plasticizer and biochemical sludge, applied in water/sludge/sewage treatment, water/sewage multi-stage treatment, oxidation treatment of sludge, etc. Reduce the trouble of sludge incineration and other problems, and achieve the effect of reducing the amount of ferrous sulfate and generating less sludge

Active Publication Date: 2016-05-18
ZHEJIANG JIAAO ENPROTECH CO LTD
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

In this method, the ferrous sulfate amount that uses is more; And applicant's experiment finds, even if adopt the ferrous sulfate of waste water weight 0.1%-0.4%, the colleague adopts the same condition of this document, the hydrogen peroxide in the waste water obtained at last There are many residues, which cannot meet the standard
[0005] In addition, after biochemical treatment of plasticizer wastewater, a large amount of excess sludge is produced. Usually, after biochemical sludge is digested and concentrated, the moisture content is still as high as 80% after being filtered by a plate and frame filter press. High moisture content sludge Cause a lot of trouble in transfer and subsequent incineration

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  • A kind of epoxy plasticizer wastewater treatment method that can improve the performance of biochemical sludge

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Experimental program
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Embodiment 1

[0022] The mass percentage content of hydrogen peroxide in the epoxy plasticizer production wastewater is about 2.5%, and the pH value is 3 to 4. The above-mentioned epoxy plasticizer wastewater is pumped up to an effective use volume of 15m 3 The reactor was added with 0.06% ferrous sulfate heptahydrate in the mass ratio of waste water, the reactor was heated with steam, and the reactor was started to stir at the same time. Heating to about 75°C, the liquid surface in the reaction kettle began to appear obvious bubbles and tumbling, stop heating, and at the same time add biochemical sludge with a volume ratio of wastewater of 20%, and the water content of biochemical sludge is about 99%. After 2.5 hours of reaction, if the hydrogen peroxide content in the wastewater is ≤0.05% (monitored by the potassium permanganate method), it can be considered that the Fenton reaction is over, and the reactor is cooled by the condensate coil. When the temperature in the reactor drops to 50°C...

Embodiment 2

[0025] The mass percentage content of hydrogen peroxide in the epoxy plasticizer production wastewater is about 2.5%, and the pH value is 3 to 4. The above-mentioned epoxy plasticizer wastewater is pumped up to an effective use volume of 15m 3 The reactor was added with 0.08% ferrous sulfate heptahydrate in the mass ratio of waste water, the reactor was heated with steam, and the reactor was started to stir simultaneously. Heating to about 70°C, the liquid surface in the reaction kettle began to appear obvious bubbles and rolling, stop heating, and add biochemical sludge with a volume ratio of 20% of wastewater at the same time, and the water content of biochemical sludge is about 99%. After 2.5 hours of reaction, if the hydrogen peroxide content in the wastewater is ≤0.05% (monitored by the potassium permanganate method), it can be considered that the Fenton reaction is over, and the reactor is cooled by the condensate coil. When the temperature in the reactor drops to 50°C N...

Embodiment 3

[0028] The mass percentage content of hydrogen peroxide in the epoxy plasticizer production wastewater is about 2.5%, and the pH value is 3 to 4. The above-mentioned epoxy plasticizer wastewater is pumped up to an effective use volume of 15m 3 The reactor was added with 0.06% ferrous sulfate heptahydrate in the mass ratio of waste water, the reactor was heated with steam, and the reactor was started to stir at the same time. Heating to about 80°C, the liquid surface in the reaction kettle began to appear obvious bubbles rolling, stop heating, and at the same time add biochemical sludge with a volume ratio of 20% of wastewater, the water content of biochemical sludge is about 99%. After 2 hours of reaction, if the hydrogen peroxide content in the wastewater is ≤0.05% (monitored by the potassium permanganate method), it can be considered that the Fenton reaction is over, and the reactor is cooled by the condensate coil. When the temperature in the reactor drops to 50°C Next, pre...

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Abstract

The invention discloses an epoxy plasticizer wastewater treatment method capable of improving the properties of biochemical sludge. The epoxy plasticizer wastewater treatment method comprises the following steps: controlling the pH value of the epoxy plasticizer production wastewater within the range of 2-5, adding ferrous sulfate, heating until the temperature is greater than or equal to 70 DEG C, adding the biochemical sludge and stopping heating at the same time, reducing the temperature of the liquid of the reaction system below 50 DEG C after the completion of the reaction, and performing filter pressing on the wastewater by use of a plate-and-frame filter press to obtain the treated sludge, wherein the addition amount of the ferrous sulfate is 0.05-0.09% of the total weight of the epoxy plasticizer production wastewater. Compared with the traditional pretreatment of the epoxy plasticizer wastewater, the epoxy plasticizer wastewater treatment method capable of improving the properties of the biochemical sludge has the advantages that as the conditions of the wastewater treatment process are improved, the desired addition amount of the ferrous sulfate is reduced to be 1 / 10 of the previous amount, and the amount of the generated sludge is reduced. Compared with the traditional filter cake of the biochemical sludge obtained by virtue of filter pressing, the biochemical sludge treated by use of the epoxy plasticizer wastewater treatment method capable of improving the properties of the biochemical sludge has the advantage that the moisture content of the filter cake obtained by virtue of filter pressing is reduced by more than 30% under the condition of the same filter press.

Description

technical field [0001] The invention belongs to the technical field of wastewater treatment, and in particular relates to an epoxy plasticizer wastewater treatment method capable of improving the performance of biochemical sludge. Background technique [0002] Epoxy plasticizer production wastewater contains a large amount of hydrogen peroxide and oil, so it needs to be pretreated before biochemical treatment. The domestic pretreatment of organic wastewater containing hydrogen peroxide usually adopts the Fenton oxidation method, that is, adding ferrous sulfate and hydrogen peroxide The reaction can not only remove hydrogen peroxide, but also produce strong oxidizing hydroxyl radicals to oxidize organic compounds. [0003] There are also existing reports on the treatment of plasticizer wastewater containing hydrogen peroxide: the patent document with the publication number CN102936074A discloses a pretreatment method for epoxy plasticizer production wastewater. The specific s...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C02F9/14C02F11/06
Inventor 沈键钱辰斌
Owner ZHEJIANG JIAAO ENPROTECH CO LTD