Composite collecting agent for bulk floatation of copper sulfide molybdenum ores

A composite collector, copper molybdenum sulfide technology, applied in flotation, solid separation and other directions, can solve the problems of weak selectivity, complicated preparation and addition steps, and weak collection capacity

A composite collector, copper molybdenum sulfide technology, applied in flotation, solid separation and other directions, can solve the problems of weak selectivity, complicated preparation and addition steps, and weak collection capacity

CN104324813AInactive Publication Date: 2015-02-04KUNMING METALLURGY INST
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  • Composite collecting agent for bulk floatation of copper sulfide molybdenum ores
  • Composite collecting agent for bulk floatation of copper sulfide molybdenum ores
  • Composite collecting agent for bulk floatation of copper sulfide molybdenum ores

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0012] The raw ore contains 0.36% by mass of Cu, and 0.014% by mass of Mo, and 160 g / t of collector of the present invention is added. In this collector, thiocarbamate, phosphorothioate, mixed non-polar hydrocarbon The proportions of oil and terpene alcohols were 70%, 2%, 18%, and 20%, respectively. After flotation separation, the separation results in Table 1 were obtained.

[0013] Table 1 Mixed flotation separation index 1 of copper-molybdenum sulfide ore

[0014]

Embodiment 2

[0016] The raw ore contains 0.21% by mass of Cu and 0.018% by mass of Mo, and 80g / t of collector of the present invention is added, in which thiocarbamate, phosphorothioate, mixed non-polar hydrocarbon The proportions of oil and terpene alcohol were 65%, 5%, 20%, and 10% respectively. After flotation separation, the separation results in Table 2 were obtained.

[0017] Table 2 Separation index 2 of mixed flotation of copper-molybdenum sulfide ore

[0018]

Embodiment 3

[0020] The raw ore contains 0.28% by mass of Cu and 0.02% by mass of Mo, and 130g / t of collector of the present invention is added. In this collector, thiocarbamate, phosphorothioate, and mixed nonpolar hydrocarbons The proportions of oil and terpene alcohol were 50%, 10%, 30%, and 10% respectively. After flotation separation, the separation results in Table 3 were obtained.

[0021] Table 3 Separation index 3 of mixed flotation of copper-molybdenum sulfide ore

[0022]

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Abstract

The invention discloses a composite collecting agent for bulk floatation of copper sulfide molybdenum ores. The collecting agent is a stable oily product which is formed by mixing 50%-70% of thiocarbamic acid ester, 2%-10% of thiophosphoric acid ester, 10%-30% of mixed non-polar hydrocarbon oil and 10%-20% of terpene alcohol. The collecting agent has the advantages that the thiocarbamic acid ester has the selective chelation on the exposing active points, such as copper and molybdenum, on the surfaces of minerals, the thiophosphoric acid ester has the selective adsorption function on the copper-containing minerals, the non-polar hydrocarbon oil can be adsorbed on the surface of the copper sulfide molybdenum ores through the Van der Waals force, and the terpene alcohol is a solution medium and has good air bubble property, so under the synergistic effect of the thiocarbamic acid ester, the thiophosphoric acid ester, the mixed non-polar hydrocarbon oil and the terpene alcohol, a good ore selection index can be obtained, and the agent mechanism is simplified; the collecting agent is used at the ore slurry temperature of 5-35 DEG C, and the usage amount is between 80-160g / t according to the change of the contents of usable minerals in the ores.

Description

technical field [0001] The invention belongs to the technical field of flotation reagents, and in particular relates to a composite collector for mixed flotation copper-molybdenum sulfide ore. Background technique [0002] Copper-molybdenum sulfide ore is an important source of copper and molybdenum for human beings. Copper is widely used in electrical, light industry, machinery manufacturing, construction industry, national defense industry and other fields. Copper is second only to aluminum in the consumption of non-ferrous metal materials in China. Molybdenum has the advantages of high strength, high melting point, corrosion resistance, wear resistance, etc. It is often used as an additive to produce various alloy steels, or to form advanced alloys with tungsten, nickel, cobalt, zirconium, titanium, vanadium, rhenium, etc. to improve its High temperature strength, wear resistance and corrosion resistance, widely used in aviation, machinery manufacturing, defense industry...

Claims

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Application Information

Patent Timeline
04 Feb 2015
Publication
CN104324813A
IPC
B03D1/014; B03D101/02
Inventors
简胜; 张旭东