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Method for controlling ammonia-process desulfurization aerosol discharge and dedicated absorption tower thereof

A desulfurization absorption tower and ammonia desulfurization technology are applied in the field of aerosol control in ammonia desulfurization flue gas desulfurization. Solve the problem of aerosol emission and the effect of simple process

Active Publication Date: 2015-02-11
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, under the existing ammonia desulfurization operating conditions, it is difficult to achieve the supersaturated water vapor environment required for the condensation and growth of aerosol particles; the selection of desulfurization operating conditions also mainly focuses on improving the desulfurization efficiency, and does not involve reducing the formation of aerosols
The Chinese invention patent with the application number 201010557866.4 proposes a method of using flue gas to achieve supersaturation in the desulfurization process and adding steam to the desulfurized clean flue gas to achieve supersaturation to promote the removal of ammonia-based aerosols. Supersaturation is reached during the desulfurization process, and the flue gas needs to be close to saturation before entering the desulfurization tower. It is not easy to realize the single-tower process without a pre-scrubber; simply adding steam to the desulfurized flue gas will cause a lot of water vapor to condense at the micron level The above coarse particles, and this part of the particles can be removed by conventional dust removal (fog removal) methods without condensation and growth.

Method used

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  • Method for controlling ammonia-process desulfurization aerosol discharge and dedicated absorption tower thereof
  • Method for controlling ammonia-process desulfurization aerosol discharge and dedicated absorption tower thereof
  • Method for controlling ammonia-process desulfurization aerosol discharge and dedicated absorption tower thereof

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Embodiment 1

[0025] According to the present invention, a kind of control method of aerosol in flue gas desulfurization by ammonia process, its equipment and process are such as figure 2 The flue gas is cooled to 100-120 ℃ by the atomized water sprayed by the atomizing water nozzle 2, and then enters the desulfurization zone B of the desulfurization absorption tower 1, and the desulfurization liquid sprayed from the top to bottom by the desulfurization liquid nozzle 4. Countercurrent contact to absorb SO in flue gas 2 ; A 3-stage spray system is set up in desulfurization zone B, and each stage of the spray system is equipped with a layer of corrugated structured packing 3, and the specific surface area of ​​the packing is 125m 2 / m 3 , the height of each layer is 1500mm; the air velocity of the superficial tower is 2.5m / s, and the operating liquid-gas ratio is 5L / Nm 3 , the pH of the desulfurization solution is 5.2 to 6.0, and the temperature of the desulfurization solution is 45 to 55°...

Embodiment 2

[0027] like image 3 As shown, the difference from Example 1 is that each level of spray system in desulfurization zone A is equipped with a non-overflow sieve plate 11, the sieve aperture is 10-12mm, and the opening rate is 10-15%, and the rest are the same as the embodiment. 1.

Embodiment 3

[0029] The flue gas is produced by a fully automatic coal-fired boiler with a flue gas volume of 150Nm 3 / h, the diameter of the desulfurization absorption tower is 150mm, the tower height is 4000mm, and there are two built-in sprays; each level of spray system is equipped with a layer of corrugated structured packing, and the specific surface area of ​​the packing is 125m 2 / m 3 , the height of each layer is 300mm; the upper part of the desulfurization tower is provided with a packing washing area and a water-vapor phase change area, and two metal orifice corrugated structured packings are installed in the packing washing area, and the packing specific surface area is 250m 2 / m 3 , the total height of the packing layer is 300mm, and the outlet of the water vapor phase change zone is equipped with a DP type (high-efficiency) wire mesh demister, the height of the demister is 150mm, and the specific surface area of ​​the demister is 625m. 2 / m 3 . The high-temperature coal-f...

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Abstract

A method for controlling ammonia-process desulfurization aerosol discharge is a method for controlling the aerosol discharge in an ammonia-process flue gas desulfurization technology, and comprises the steps: flue gas subjected to spray temperature reduction and cooled to 100-120 DEG C by atomized water is introduced to a desulfurization zone of a desulfurization absorption tower, flue gas from bottom to top in the desulfurization zone is subjected to countercurrent contact with a desulfurization liquid sprayed from top to bottom so as to absorb SO2 in the flue gas, and a packing or a sieve plate is arranged in the desulfurization zone; the flue gas enters a packing washing zone after desulfurization, and washing water is injected to remove coarse-grained aerosol generated in ammonia-process desulfurization; then the treated aerosol enters a water vapor phase transformation zone, vapor is injected from the middle part of the water vapor phase transformation zone, a supersaturated water vapor environment needed by water vapor phase transformation is established, and fine-grained aerosol micro-particles which are not removed are congealed, grow up and are removed from a silk screen mist eliminator at a flue gas outlet of the water vapor phase transformation zone; and the purified flue gas is discharged through a chimney from a flue gas outlet at the top of the desulfurization absorption tower. The method can effectively solve the discharge problem of the aerosol in the ammonia-process flue gas desulfurization. The invention discloses the dedicated desulfurization absorption tower of the method.

Description

technical field [0001] The invention relates to a method for controlling fine particles in coal-fired flue gas, in particular to a method for controlling aerosol in flue gas desulfurization by ammonia method. Background technique [0002] In recent years, the ammonia-based flue gas desulfurization process has been gradually popularized in coal-fired power plants due to its fast gas-liquid or gas-gas reaction speed, high desulfurization efficiency, and recyclable desulfurization by-products. It has become a technical bottleneck affecting the popularization and application of ammonia desulfurization process. Generally, the aerosol particles formed in ammonia desulfurization are mainly sub-micron particles from the quantitative point of view, but from the mass concentration distribution, the particles are mainly micron and larger than 10 μm, and the particle concentration after desulfurization can be increased several times compared with that before desulfurization to more tha...

Claims

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Application Information

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IPC IPC(8): B01D53/78B01D53/50B01D50/00B01D47/14B01D47/05
Inventor 张文武杨林军鲍静静曹平沙志强朱忠益
Owner CHINA PETROLEUM & CHEM CORP
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