Reclaimed ABS (acrylonitrile butadiene styrene) environment-friendly modified material and preparation method thereof

A modified material and environmentally friendly technology, which is applied in the field of recycled ABS environmentally friendly modified materials and its preparation, can solve the problems of environmental damage and low mechanical properties, and achieve the effects of high purity, high gloss and enhanced flame retardancy of ABS

Inactive Publication Date: 2015-02-25
GUANGDONG GUOLI SCI & TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, for recycled ABS materials, its mechanical properties are much lower than those of fresh ABS raw materials. If you want to continue to use ABS recycled materials in electronics, electrical appliances, automobiles and other industries after modification, you must improve their flame retardancy, toughness, etc. Effective modification of impact resistance and impact resistance to meet material performance requirements for different uses
[0005] However, most of the flame retardants currently used are bromine and red phosphorus flame retardants. Although they have a more obvious effect on the regeneration and modification of ABS, they have certain damage to the environment. People are looking for a more environmentally friendly ABS modification. method

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0057] A recycled ABS environmentally friendly modified material, consisting of the following substances by weight:

[0058] ABS recycled material 100 copies

[0059] Flame retardant 5 parts

[0060] Flame retardant synergist 20 parts

[0061] Compound anti-aging agent 1 part

[0062] Antioxidant 0.4 parts

[0063] Toughener 10 parts

[0064] 2 parts of coupling agent.

[0065] The flame retardant is the modified graphene of the present invention.

[0066] The modified graphene is modified through the following methods:

[0067] (1) Put the graphene in absolute ethanol, and ultrasonically react for 1 hour to obtain a graphene suspension;

[0068] (2) After mixing deionized water, acetic acid with a mass concentration of 36%, and a silane coupling agent according to the mass percentage of 1:3:20, add it to the graphene suspension prepared in the first step, and continue the ultrasonic reaction for 20 minutes;

[0069] (3) Then keep the solution after the second step rea...

Embodiment 2

[0082] A recycled ABS environmentally friendly modified material, consisting of the following substances by weight:

[0083] ABS recycled material 100 copies

[0084] Flame retardant 8 parts

[0085] Flame retardant synergist 25 parts

[0086] Composite anti-aging agent 0.8 parts

[0087] Antioxidant 2 parts

[0088] Toughener 20 parts

[0089] 1 part of coupling agent.

[0090] The flame retardant is the modified graphene of the present invention.

[0091] The modified graphene is modified through the following methods:

[0092] (1) Put the graphene in absolute ethanol, and ultrasonically react for 1 hour to obtain a graphene suspension;

[0093] (2) After mixing deionized water, acetic acid with a mass concentration of 36%, and a silane coupling agent according to the mass percentage of 1:3:20, add it to the graphene suspension prepared in the first step, and continue the ultrasonic reaction for 20 minutes;

[0094] (3) Then keep the solution after the second step re...

Embodiment 3

[0107] A recycled ABS environmentally friendly modified material, consisting of the following substances by weight:

[0108] ABS recycled material 100 copies

[0109]Flame retardant 8 parts

[0110] Flame retardant synergist 18 parts

[0111] Composite anti-aging agent 0.5 parts

[0112] Antioxidant 1 part

[0113] Toughener 17 parts

[0114] 1.5 parts of coupling agent.

[0115] The flame retardant is the modified graphene of the present invention.

[0116] The modified graphene is modified through the following methods:

[0117] (1) Put the graphene in absolute ethanol, and ultrasonically react for 1.5 hours to obtain a graphene suspension;

[0118] (2) After mixing deionized water, acetic acid with a mass concentration of 36%, and a silane coupling agent according to the mass percentage of 1:3:20, add it to the graphene suspension prepared in the first step, and continue the ultrasonic reaction for 35 minutes;

[0119] (3) Then keep the solution after the second ste...

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PUM

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Abstract

The invention relates to the technical field of recycling of ABS reclaimed materials, in particular to a reclaimed ABS (acrylonitrile butadiene styrene) environment-friendly modified material and a preparation method thereof. The material comprises ABS reclaimed materials, flame retardant, flame-retardant synergist, compound antiager, antioxygen, flexibilizer and coupling agent. Environment-friendly modified graphene is adopted as the flame retardant, so that flame retardation of the material is improved, and the material is environmentally friendly; waste nitrile rubber is adopted as the flexibilizer, so that mechanical property of the material is improved, waste turns into wealth, and the requirement on environmental protection is met; being added with the compound antiager, the material is high in ageing resistance. The reclaimed ABS material is equivalent to a new flame-retardant material in flame retardance and mechanical properties, the reclaimed ABS material prepared by the method is excellent in performance, the preparation technique is simple and easy to operate, production cost is low, economic benefit is high, and industrialization is easy to realize.

Description

technical field [0001] The invention relates to the technical field of recycling ABS recycled materials, in particular to a recycled ABS environmentally friendly modified material and a preparation method thereof. Background technique [0002] Today, China has entered the peak period of discarding household appliances, and more than 30 million discarded household appliances will be produced every year. Such a huge waste of household appliances will inevitably produce a large amount of waste plastics. There are three ways to recycle waste plastics: sanitary landfill, incineration for heat, and resource recycling. Among them, landfill and incineration are likely to cause waste of resources and secondary pollution, which is contrary to the theme of the era of green environmental protection. [0003] Nowadays, the recycling of waste plastics mainly adopts the method of recycling, mainly including direct regeneration, modified regeneration, gasification and oil treatment. Howeve...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L55/02C08L9/02C08K13/06C08K9/06C08K3/04C08K7/08C08K3/22B29B9/06B29C47/92B29C48/92
Inventor 周乾桃
Owner GUANGDONG GUOLI SCI & TECH CO LTD
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