The invention relates to applications of cyclic phosphorus-nitrogen synergic halogen-free flame retardant, and particularly relates to applications of 2,7-bis(N,N-dimethylamine)-1,6,3,8,2,7-octahydrodioxadiazole diphosphinic acid, belonging to the field of synthesizing a novel halogen-free high polymer material. As a hard segment chain extender, 2,7-bis(N,N-dimethylamine)-1,6,3,8,2,7-octahydrodioxadiazole diphosphinic acid is applied to halogen-free flame-retardant modification of water-based polyurethane emulsion. Cyclic phosphamide flame retardant 2,7-bis(N,N-dimethylamine)-1,6,3,8,2,7-octahydrodioxadiazole diphosphinic acid as the hard segment chain extender is embedded into a water-based polyurethane macromolecular chain; the research shows that due to the addition of the flame retardant, the limit oxygen index of a polyurethane membrane can be improved to a greater extent, the thermal stability of the polyurethane membrane is enhanced, the carbon residue rate of the material after which is decomposed at high temperature is increased, and the usage amount of the flame retardant is reduced.