Iron smelting flue gas treatment method

A technology for flue gas treatment and flue gas, which is applied in the field of iron smelting flue gas treatment, and can solve the problems of low mercury removal efficiency

Inactive Publication Date: 2015-03-25
朱忠良
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The efficiency of mercury removal by fly ash adsorption is low, and it is still in the stage of laboratory research

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0015] A method for treating flue gas from iron smelting. First, a dust collector is used to remove dust from the flue gas, and then the SCR method is used to remove nitrogen oxides in the flue gas. After the nitrogen oxides are removed, the flue gas is sent to a desulfurization device. The flue gas is emptied, and there is a nozzle in the desulfurization device. While desulfurization, the nozzle sprays a mixture of hydrogen chloride and hypochlorous acid into the desulfurization device. The molar ratio of hydrogen chloride and hypochlorous acid is 5:3, and the desulfurization device A composite adsorbent is arranged at the outlet of the flue gas. The specific composition of the composite adsorbent is 60wt% activated carbon, 20wt% MCM-41 and 20wt% NaY type zeolite. The preparation method of the composite adsorbent is a mixing method.

Embodiment 2

[0017] A method for treating flue gas from iron smelting. First, a dust collector is used to remove dust from the flue gas, and then the SCR method is used to remove nitrogen oxides in the flue gas. After the nitrogen oxides are removed, the flue gas is sent to a desulfurization device. The flue gas is evacuated, and there is a nozzle in the desulfurization device. The mixed solution of hydrogen chloride and hypochlorous acid is sprayed from the nozzle into the desulfurization device at the same time as desulfurization. The molar ratio of hydrogen chloride and hypochlorous acid is 7:3, and the desulfurization device A composite adsorbent is arranged at the outlet of the flue gas, and the specific composition of the composite adsorbent is 50wt% activated carbon, 25wt% MCM-41 and 25wt% NaY type zeolite, and the preparation method of the composite adsorbent is a mixing method.

Embodiment 3

[0019] A method for treating flue gas from iron smelting. First, a dust collector is used to remove dust from the flue gas, and then the SCR method is used to remove nitrogen oxides in the flue gas. After the nitrogen oxides are removed, the flue gas is sent to a desulfurization device. The flue gas is evacuated, and there is a nozzle in the desulfurization device. While desulfurization, the nozzle sprays a mixture of hydrogen chloride and hypochlorous acid into the desulfurization device. The molar ratio of hydrogen chloride and hypochlorous acid is 8:5, and in the desulfurization device A composite adsorbent is arranged at the outlet of the flue gas, and the specific composition of the composite adsorbent is 50wt% activated carbon, 25wt% MCM-41 and 25wt% NaY type zeolite, and the preparation method of the composite adsorbent is a mixing method.

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PUM

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Abstract

The invention discloses an iron smelting flue gas treatment method. The iron smelting flue gas treatment method comprises the following steps: firstly, dust removal is carried out on flue gas by a dust remover; then, nitric oxide in the flue gas is removed by adopting an SCR method; after the nitric oxide is removed, the flue gas is conveyed into a desulfurization device; the flue gas subjected to desulfurization treatment is discharged into air, wherein the desulfurization device is provided with a nozzle; in a desulfurization process, a mixed solution of hydrogen chloride and hypochlorous acid is sprayed into the desulfurization device, wherein the mol ratio of hydrogen chloride to hypochlorous acid is (5-10) to (3-4); a compound adsorbent is arranged at a flue gas outlet of the desulfurization device and is specifically formed by 20wt%-60wt% of active carbon, 20wt%-40wt% of MCM-41 and 20wt%-30wt% of NaY type zeolite; and a preparation method of the compound adsorbent is a mixing method. By virtue of the method, when more than 80% of denitration efficiency and more than 95% of desulfurization efficiency are reached, more than 80% of demercuration efficiency and more than 95% of dechloridation and defluorination efficiency are reached and partial volatile organic pollution is oxidized and degraded, so that the environment protection standards which are increasingly strict in the future can be met.

Description

technical field [0001] The invention relates to a method for treating iron smelting flue gas. Background technique [0002] The sulfur oxides and nitrogen oxides produced in the process of energy utilization have caused increasingly serious harm to my country's atmospheric environment. In addition, trace amounts of heavy metals such as mercury Hg, HCl, HF and volatile organic pollutants VOC have also increasingly caused harm. people's attention. At present, large-scale treatment and control of sulfur dioxide have been carried out, and the control of nitrogen oxides has also been increasingly put on the agenda. Mercury, chlorine, fluorine, and volatile organic pollutants have not yet been clearly required in coal-fired boilers in my country. With the development of my country's economy and society and the enhancement of people's awareness of environmental protection, these pollutants are bound to be gradually controlled. [0003] At present, the existing desulfurization tech...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01D53/75B01D53/90B01D53/78B01D53/56B01D53/50B01D53/68B01D53/44B01D53/64B01J20/20
Inventor 朱忠良
Owner 朱忠良
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