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Aromatic hydrogenation catalyst and preparation method thereof

A technology for hydrogenation of aromatics and catalysts, applied in the fields of hydrogenation and refining of aromatics, chemical instruments and methods, metal/metal oxide/metal hydroxide catalysts, etc., can solve the problems of complex preparation process and poor sulfur resistance, Achieve the effects of simple preparation method, strong anti-sulfur poisoning ability, and shortened preparation process

Inactive Publication Date: 2015-04-01
XIAMEN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0009] The purpose of the present invention is to overcome the complex preparation process and poor sulfur resistance of the aromatic hydrocarbon hydrogenation catalyst of the supported Ni-B amorphous alloy in the prior art, and provide an aromatic hydrocarbon hydrogenation catalyst and a preparation method thereof. Reduced non-noble metal arene hydrogenation catalyst with high activity and high sulfur resistance

Method used

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  • Aromatic hydrogenation catalyst and preparation method thereof
  • Aromatic hydrogenation catalyst and preparation method thereof
  • Aromatic hydrogenation catalyst and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0041] The preparation process of aromatic hydrocarbon hydrogenation catalyst is as follows:

[0042] 1) according to the proportioning of each component in the catalyst prepared as required, measure 13.5mL of nickel nitrate solution of 1mol / L, 172mL of boric acid solution of 1mol / L, 45mL of tetraethyl orthosilicate solution of 4.4mol / L; Measured 13.5mL nickel nitrate solution, 152mL boric acid solution and 45mL tetraethyl orthosilicate solution were uniformly mixed to obtain the mixed material;

[0043] 2) Stir the mixed material in step 1) at 60°C for 5h, then dry at 110°C for 12h;

[0044] 3) Take the dried solid matter in step 2) and place it in a muffle furnace, heat it up to 400°C at a rate of 10°C / min, and then roast it at a constant temperature for 4 hours;

[0045] 4) Take the roasted solid matter in step 3), mix it with 1g of binder pseudo-boehmite and the remaining 20ml of boric acid solution with a concentration of 1mol / L in step 1), and place it in the muffle In...

Embodiment 2

[0049] The preparation process of aromatic hydrocarbon hydrogenation catalyst is as follows:

[0050] The difference between embodiment 2 and embodiment 1 is: in step 1), measure the tetraethyl orthosilicate solution of the nickel nitrate solution 33.5mL of 1mol / L, the boric acid solution 360mL of 1mol / L, 4.4mol / L 52mL; the measured 33.5mL nickel nitrate solution, 225mL boric acid solution and 52mL tetraethyl orthosilicate solution are uniformly mixed to obtain a mixed material; in step 4), the solid matter after roasting in step 3) is mixed with 1g of After the boric acid solution of 1mol / L is mixed in the remaining 135ml concentration of binder pseudo-boehmite and step 1), it is placed in a muffle furnace for roasting; all the other are with embodiment 1, and the content of each component of the catalyst obtained is as follows: Table 1 shows.

[0051] The activity evaluation process of the obtained aromatic hydrocarbon hydrogenation catalyst is the same as in Example 1, and...

Embodiment 3

[0053] The preparation process of aromatic hydrocarbon hydrogenation catalyst is as follows:

[0054] The difference between embodiment 3 and embodiment 1 is: in step 1), measure 80 mL of nickel nitrate solution of 1 mol / L, 460 mL of boric acid solution of 1 mol / L, 53 mL of tetraethyl orthosilicate solution of 4.4 mol / L ; 80mL nickel nitrate solution, 300mL boric acid solution and 53mL tetraethyl orthosilicate solution are uniformly mixed to obtain the mixed material; in step 4), the solid matter after roasting in step 3) is bonded with 4g Remaining 160ml concentration in the agent pseudo-boehmite and step 1) is after the boric acid solution of 1mol / L mixes, and is placed in the muffle furnace to roast; All the other are with embodiment 1, and the content of each component of the catalyzer that obtains is as table 1 shown.

[0055] The activity evaluation process of the obtained aromatic hydrocarbon hydrogenation catalyst is the same as in Example 1, and the reaction results ...

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Abstract

The invention discloses an aromatic hydrogenation catalyst and a preparation method thereof. The catalyst comprises a carrier and active components loaded on the carrier, wherein silicon dioxide serves as the carrier; the active components include nickel oxide and boron oxide. Nickel in the catalyst exists in a crystalline phase form, the catalyst is applicable to an aromatic hydrogenation reaction process and has high sulfur resistance and high hydrogenation activity, and the preparation method is simple to operate and easy to implement.

Description

technical field [0001] The invention relates to an aromatic hydrocarbon hydrogenation catalyst and a preparation method thereof. Background technique [0002] In the oil refining industry, the hydrogenation technology of aromatics has been paid more and more attention, mainly because the excessively high aromatics content in oil products has caused environmental problems. In order to reduce environmental pollution caused by incomplete combustion of aromatics, European and American countries have strictly limited the content of aromatics in fuel. Moreover, since there is a certain amount of sulfide in the oil, the catalyst will inevitably be affected by sulfur poisoning during the hydrogenation process. Therefore, it is currently a priority to develop aromatic hydrogenation catalysts with high sulfur resistance and high activity. One of the research hotspots. [0003] At present, aromatic hydrogenation catalysts mainly include traditional metal sulfidation catalysts and met...

Claims

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Application Information

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IPC IPC(8): B01J23/755C10G45/48
Inventor 陈秉辉李阳郑进保方维平伊晓东赖伟坤
Owner XIAMEN UNIV
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