Retarding-swelling salt-tolerant high-viscoelasticity particles with interpenetrating network structure and preparation method thereof
A technology of interpenetrating network structure and viscoelastic particle is applied in the field of preparation of superabsorbent resin with interpenetrating network structure. Effects of migratory capacity, strong shear capacity, high acid and salt resistance
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[0033] The preparation method of viscoelastic particles of the present invention comprises the following steps:
[0034] 1) Add 1% to 10% of polyalcohol by mass to 20mL of distilled water, cover with a watch glass, dissolve completely in a water bath at 60°C to 95°C, and then cool to below 50°C to obtain solution A;
[0035] 2) Neutralize 5% to 15% of unsaturated carboxylic acid with NaOH solution to pH 6-7 in an ice-water bath to obtain solution B;
[0036] 3) Stir 40% to 60% attapulgite with 20mL of distilled water to form a uniformly dispersed phase;
[0037] 4) After completely dissolving 15% to 35% unsaturated amide, 0.01% to 0.5% crosslinking agent 1, and 0.02% to 1% initiator, stir evenly with solution B that has been neutralized to a pH value of 6-7 Mix with the attapulgite in step 2) to obtain solution C;
[0038] 5) Mix liquids A and C evenly, add 0.01% to 0.5% of crosslinking agent 2, cover with a watch glass, and react in a water bath at 65°C to 90°C for 0.5 to 6...
Embodiment 1-5
[0042]
[0043]
[0044] The interpenetrating network structure novel slow-swelling salt-resistant high-viscosity elastic particle of the present invention has good slow expansion performance, high water absorption expansion ratio, good viscoelasticity and toughness, high strength, and is suitable for deep water injection profile control, and is low in cost, convenient to prepare, and suitable for The environment is pollution-free.
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