Method for preparing two-layer decorative iron-based magnetic materials
A magnetic material, iron-based technology, applied in the field of preparation of iron-based magnetic materials, can solve the problems of particle agglomeration, unstable solubility of nanoparticles, etc.
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Embodiment 1
[0017] Dissolve ferric chloride and potassium oxalate in ethylene glycol to prepare a mixed solution, the concentration of ferric chloride in ethylene glycol solution is 0.2mol / L, the concentration of potassium oxalate in ethylene glycol solution is 1mol / L, chlorine The molar ratio of ferric chloride to potassium oxalate is 1:4; add ethylenediamine to the above mixed solution, stir and sonicate to obtain a homogeneous suspension, and the molar ratio of ferric chloride to ethylenediamine is 1:6.5.
[0018] Transfer the suspension into a polytetrafluoroethylene-lined stainless steel autoclave for solvothermal reaction at a temperature of 180°C and a reaction time of 15 hours, keeping the pressure of the reaction system within 10 atmospheres, and naturally cooling to room temperature after the reaction; Wash the precipitate by centrifugation with deionized water or absolute ethanol, remove the solvent in the precipitate, and dry at room temperature to obtain magnetic nanoparticles...
Embodiment 2
[0022] Ferric chloride and potassium oxalate are dissolved in ethylene glycol to prepare a mixed solution. The concentration of ferric chloride in ethylene glycol solution is 0.35mol / L, and the concentration of potassium oxalate in ethylene glycol solution is 1.25mol / L. The molar ratio of ferric chloride to potassium oxalate is 1:6; add ethylenediamine to the above mixed solution, stir and sonicate to obtain a homogeneous suspension, and the molar ratio of ferric chloride to ethylenediamine is 1:8.7.
[0023] Transfer the suspension into a polytetrafluoroethylene-lined stainless steel autoclave for solvothermal reaction at a temperature of 210°C and a reaction time of 10 hours, keeping the pressure of the reaction system within the range of 15 atmospheres, and naturally cooling to room temperature after the reaction; Wash the precipitate by centrifugation with deionized water or absolute ethanol, remove the solvent in the precipitate, and dry at room temperature to obtain magne...
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