Chip four-corner binding glue and preparation method thereof

A technology of binding glue and four corners, which is applied in the direction of adhesives, epoxy glue, adhesive types, etc., can solve the problems of surface stickiness, non-curing, and affecting the performance of other components, and achieve fast curing speed and low curing temperature , Stable and long-term storage effect

Inactive Publication Date: 2015-04-22
YANTAI TIGHTSEN FINE CHEM
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] At present, the traditional four-corner binding glue on the market is: 1. Epoxy resin is cured at high temperature, but due to the high curing temperature of the epoxy-cured system, after the digital product is assembled, the high temperature will affect the performance of other components; 2. UV ultraviolet curing, due to the fast curing speed of UV ultraviolet curing glue, the curing room will not generate high temperature, this process should be the best way to protect the chip, but due to the polymerization inhibition effect of oxygen in the air, the surface of the UV ultraviolet glue after curing Sticky, and there will be no curing phenomenon where the ultraviolet light is not irradiated

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] A chip four-corner binding adhesive, the components of which are calculated in parts by weight: bisphenol A epoxy resin 828EL (Shell brand, produced in the Netherlands) 22.5g, bisphenol F epoxy resin 830S (Japan DIC brand) 37.0g , black paste (Degussa T4 black pigment) 0.5g, white carbon black (R202, Degussa) 4.8g, silica spherical filler (Toyota Tsusho, FED45B) 88.0g, mercaptoester (TMPTMA, Japan) 47.6 g, 1.5 g of barbituric acid, 6.0 g of curing agent PN-H (Ajinomoto of Japan) and 2.0 g of coupling agent KH560.

[0028] Bake 22.5 g of bisphenol A epoxy resin (Shell brand, produced in the Netherlands) and 37.0 g of bisphenol F epoxy resin 830S (Japan DIC brand) at 75°C for 12 h, and then bake 22.5 g of the baked bisphenol A epoxy resin, 37.0g bisphenol F epoxy resin, 4.8g white carbon black and 0.5g black paste were mixed at 20°C for 20-40min, then 88g silica spherical filler, 47.6g mercaptoester TMPTMA, 1.5g Barbituric acid, 6.0g curing agent PN-H and 2.0g coupling a...

Embodiment 2

[0031] A chip four-corner binding adhesive, the components of which are calculated in parts by weight: bisphenol A epoxy resin 828EL (Shell brand, produced in the Netherlands) 20.0g, bisphenol F epoxy resin 830S (Japan DIC brand) 40.0g , black paste (Degussa T4 black pigment) 1.0g, white carbon black (R202, Degussa) 5.0g, silica spherical filler (Toyota Tsusho, FED45B) 80.0g, mercaptoester (TMPTMA, Japan) 48.0 g, 1.5 g of barbituric acid, 4.0 g of curing agent PN-H (Ajinomoto of Japan) and 1.0 g of coupling agent KH550.

[0032] Bake 20.0 g of bisphenol A epoxy resin (Shell brand, produced in the Netherlands) and 40.0 g of bisphenol F epoxy resin 830S (Japan DIC brand) at 75°C for 12 hours, and then bake 20.0 g of the baked bisphenol A epoxy resin, 40.0g bisphenol F epoxy resin, 5.0g white carbon black and 1.0g black paste were mixed at 30°C for 20-40min, then 80.0g silica spherical filler, 48.0g mercaptoester TMPTMA, 1.5 g barbituric acid, 4.0g curing agent PN-H and 1.0g cou...

Embodiment 3

[0035] A chip four-corner binding adhesive, the components of which are calculated in parts by weight: bisphenol A epoxy resin 828EL (Shell brand, produced in the Netherlands) 25.0g, bisphenol F epoxy resin 830S (Japan DIC brand) 35.0g , black paste (Degussa T4 black pigment) 0.8g, white carbon black (R202, Degussa) 10.0g, silica spherical filler (Toyota Tsusho, FED45B) 60.0g, mercaptoester (TMPTMA, Japan) 30.0g g, 1.0 g of barbituric acid, 4.0 g of curing agent PN-H (Ajinomoto of Japan) and 1.5 g of coupling agent KH570.

[0036]Bake 25.0g of bisphenol A epoxy resin (Shell brand, produced in the Netherlands) and 35.0g of bisphenol F epoxy resin 830S (Japanese DIC brand) at 70°C for 12h, and then bake 25.0g of bisphenol A epoxy resin, 35.0g bisphenol F epoxy resin, 10.0g white carbon black and 0.8g black paste were mixed at 20°C for 20-40min, then 60.0g silica spherical filler, 30.0g mercapto ester TMPTMA, 1.0 g of barbituric acid, 4.0g of curing agent PN-H and 1.5g of coupli...

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Abstract

The invention belongs to the technical field of chip protective glue and particularly relates to chip four-corner binding glue and a preparation method thereof. The chip four-corner binding glue is prepared from the following components in parts by weight: 20-25 parts of bisphenol A epoxy resin, 35-40 parts of bisphenol F epoxy resin, 0.5-1.0 part of pigment, 4-10 parts of white carbon black, 60-100 parts of spherical filler, 30-50 parts of sulfydryl ester, 1-2 parts of a stabilizer, 4-10 parts of a curing agent and 1-3 parts of a coupling agent. The four-corner binding glue prepared by the preparation method disclosed by the invention is not high in viscosity, good in thixotropy and relatively high in cross-linking density, so that the weather resistance is extremely good, the curing temperature is low, the bonding strength is high, the shrinking percentage is low, the storage is relatively stable and lasting, the preparation process is simple and environmentally friendly, the cost is low and the applied range is wide. Moreover, a product obtained by the preparation method disclosed by the invention is in liquid state, and beneficial to site construction and avoiding generating gas bubbles.

Description

technical field [0001] The invention belongs to the technical field of chip protection adhesives, and in particular relates to a chip four-corner binding adhesive and a preparation method thereof. Background technique [0002] China has become the world's largest producer of digital products, among which the production of mobile digital products accounts for more than half of the world's output. According to data, the development trend of modern digital products is "thin, light, and small". This development also requires chips. It tends to be "thin, light, and small", and this trend also greatly increases the protection requirements for chips. [0003] Since mobile digital products will be pressed, bent, twisted, dropped and other phenomena during use, and this stress change will naturally be applied to the chip, the chip will creep when the stress changes, and long-term application will lead to chip solder balls The chip is broken and the function of the chip is lost, and ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J163/02C09J11/04C09J11/06
Inventor 周建忠林志秀林绍盛
Owner YANTAI TIGHTSEN FINE CHEM
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