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Water-reducing metakaolin-based micro-expansion compacting agent and preparation method thereof

A metakaolin and micro-expansion technology, which is applied in the field of water-reducing metakaolin-based micro-expansion compacting agent and its preparation, can solve the problems of difficult dispersion, inability to disperse metakaolin, poor concrete workability, etc. The effect of volume stability

Active Publication Date: 2015-04-29
WUHAN UNIV OF TECH +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] 1) Due to the high specific surface area of ​​metakaolin (≥2300m 2 / kg) and layered structure, strong water absorption and layered structure is not conducive to the relative movement between particles, resulting in poor concrete work performance, which affects the pumpability and filling of concrete, and ultimately affects the later performance of concrete;
[0006] 2) Due to the high fineness of metakaolin, it is easy to agglomerate and difficult to disperse, which is not conducive to the exertion of the active effect of metakaolin
[0007] Single mixed metakaolin will significantly reduce the performance of concrete, and even affect the normal construction
In order to ensure the working performance of the concrete mixed with metakaolin, the current method is to use metakaolin and water reducer separately mixed into the concrete for use. This kind of method cannot make the metakaolin evenly dispersed in the cement concrete. The activity of metakaolin and its layered structure characteristics are not well utilized, so this method has no significant effect on improving the performance and strength of concrete in the actual application process

Method used

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  • Water-reducing metakaolin-based micro-expansion compacting agent and preparation method thereof
  • Water-reducing metakaolin-based micro-expansion compacting agent and preparation method thereof
  • Water-reducing metakaolin-based micro-expansion compacting agent and preparation method thereof

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Experimental program
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Effect test

Embodiment 1

[0023] The water-reducing metakaolin-based micro-expansion compacting agent of the present invention is an active slurry prepared by grinding metakaolin, polycarboxylate water-reducer powder, gypsum and water in a ball mill, and then obtains a dry powder by spray drying, and then adds to the dry powder The mass fraction is 3% lime.

[0024] The metakaolin is prepared by grinding kaolin and calcining at a temperature of 500-1000°C for 0.5-6.0 hours and then cooling, wherein the SiO in the metakaolin 2 with Al 2 o 3 The sum of the mass percentages is ≥50wt%, and the specific surface area is ≥2300m 2 / kg; the average molecular weight of the polycarboxylate superplasticizer is 11000-15000, and the number of polyoxyethylene groups as one of the side chains in the molecular structure of the polycarboxylate superplasticizer is greater than 60; the gypsum is two Water gypsum, of which CaSO 4 2H 2 The mass percentage of O is greater than 90%, and the specific surface area is great...

Embodiment 2

[0030]Taking mortar specimens as the object of investigation, metakaolin and water-reducing metakaolin-based micro-swelling compactors are used to replace cementitious materials in equal amounts of 6%, 8%, and 10% to configure mortar. The water reducer is polycarboxylate water reducer powder. Control the water-cement ratio, and test the fluidity of the mixture of the reference sample, metakaolin sample, and water-reducing metakaolin-based micro-expansion compacting agent 1-3 according to GB / T2429-2005 "Measurement Method for Fluidity of Cement Mortar Sand". The experimental group has the same fluidity at 220±10mm; according to GB / T17671-1999 "Cement Mortar Strength Test Method", the 3-day, 7-day and 28-day compressive strength of the reference sample and the example are tested with a universal pressure testing machine. Among them, metakaolin 1-3 is metakaolin and water-reducing agent mixed separately in powder, and metakaolin in water-reducing metakaolin-based micro-expansion ...

Embodiment 3

[0043] A water-reducing metakaolin-based micro-expansion compacting agent wherein metakaolin: gypsum: polycarboxylate water reducer (ie component A) = 90%: 8%: 2%, lime accounts for 3% of the total mass of component A .

[0044] Taking the concrete specimen as the object of investigation, metakaolin and water-reducing metakaolin-based micro-expansion compacting agent are used to replace the cementitious material in an equivalent amount of 10% to configure concrete, and the water-reducing agent is polycarboxylate water-reducing agent. According to GB / T 50080-2002 "Standards for Test Methods of Performance of Ordinary Concrete Mixtures", test the slump of the reference sample and the mixture of Example 1; according to GB / T 50081-2002 "Standards for Test Methods of Mechanical Properties of Ordinary Concrete", The 3-day, 7-day and 28-day compressive strengths of the reference samples and examples were tested with a universal pressure testing machine.

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Abstract

The invention relates to a water-reducing metakaolin-based micro-expansion compacting agent and a preparation method thereof. The water-reducing metakaolin-based micro-expansion compacting agent comprises components A and B, wherein the component A is prepared from the following raw materials in percentage by weight: 85%-94.5% of metakaolin, 0.5%-5% of polycarboxylate water-reducer powder and 5%-10% of gypsum; the component B is prepared from lime; and the component B accounts for 1%-5% of total mass of the component A. The water-reducing metakaolin-based micro-expansion compacting agent has the advantages that (1) the working property of the concrete is significantly improved; (2) the volume stability of the concrete is improved; and (3) the early strength of the concrete is obviously improved.

Description

technical field [0001] The invention belongs to the technical field of building materials, and in particular relates to a water-reducing metakaolin-based micro-expansion compacting agent and a preparation method thereof. Background technique [0002] The cement industry is a typical resource and energy-consuming industry, and it is an industry that pollutes the environment seriously. The production of 1 ton of cement needs to consume 1.1 tons of limestone and emit nearly 1 ton of CO2. In recent years, major industrially developed countries and regions in the world have attached great importance to the research and development of green building materials, and climate change has also sounded the alarm for people all over the world. Actively develop and utilize high-performance auxiliary cementitious materials, use low clinker to produce high-quality products, reduce energy consumption and material consumption, and reduce negative effects on the environment. Taking the road of...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B24/24
Inventor 王桂明包明张伟明曾伟能水中和杨增良梅明军
Owner WUHAN UNIV OF TECH