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A two-stage hydrocracking method for producing high-quality chemical raw materials with low energy consumption

A technology of hydrocracking and chemical raw materials, which is applied in the fields of hydrotreating process, petroleum industry, and hydrocarbon oil treatment, etc. It can solve problems such as complex process flow, achieve high heat transfer efficiency, use less number of units, and widen the range.

Active Publication Date: 2016-11-16
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This method can produce high-aromatic latent heavy naphtha and high-quality tail oil at the same time, but the process is more complicated than the conventional hydrocracking process, and has limitations. More than 60wt%, cetane number <30

Method used

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  • A two-stage hydrocracking method for producing high-quality chemical raw materials with low energy consumption

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Embodiment 1-3

[0039] use figure 1 The process flow diagram shown. The catalyst system of FF-46 hydrocracking pretreatment catalyst and hydrocracking catalyst I / hydrocracking catalyst II in different volume ratios was selected. The volume ratios of hydrocracking catalyst I / hydrocracking catalyst II in Examples 1-3 are 3:2, 1:1 and 2:3, respectively.

[0040] At a total reaction pressure of 15.7MPa, the volume ratio of hydrogen to oil in the refining section and the cracking section is 900:1 and 1200:1 respectively, and the volume space velocity of the refining section and the cracking section are 1.0h -1 and 1.5h -1 , control the nitrogen content of refined oil to 5-8 μg×g -1 , a process test with a conversion rate of about 75wt% at >350°C was carried out, in which the temperature difference between the beds of hydrocracking catalyst I and hydrocracking catalyst II was controlled to maintain 8°C, and the product quality of each fraction was investigated.

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Abstract

The present invention discloses a two-stage hydrocracking method for low energy-consumption production of a high-quality chemical industry raw material. According to the method, a raw material oil and hydrogen gas are subjected to heat exchange two times, and then sequentially pass through a hydrorefining reaction zone and a hydrocracking reaction zone, wherein the hydrocracking reaction zone comprises at least two hydrocracking catalysts, the upstream is filled with a catalyst I, the downstream is filled with a catalyst II, the catalyst I contains 30-70 wt% of a modified Y molecular sieve, the catalyst II contains 15-50 wt% of the modified Y molecular sieve, and the modified Y molecular sieve content in the catalyst I is 10-30% higher than the modified Y molecular sieve content in the catalyst II. According to the method of the present invention, the high temperature high pressure countercurrent heat transfer technology and the hydrocracking catalyst grading technology are organically combined, and the hydrocracking reaction heat is comprehensively utilized, such that the characteristics of the two different types of the hydrocracking catalysts are completely provided, and the catalyst selectivity is maintained while the target product quality is improved, and the project investment and the operating energy consumption are reduced.

Description

technical field [0001] The invention relates to a hydrocracking method, in particular to a low-energy two-stage hydrocracking method capable of producing high-quality chemical raw materials. Background technique [0002] As the market demand for middle distillates continues to increase, refineries are required to produce more middle distillates. The new fuel standard puts forward stricter requirements on the indicators of gasoline and diesel. Obviously, primary processing methods and FCC technology can no longer meet the market's requirements for clean fuels. The hydrocracking process is not only a secondary processing method to lighten heavy raw materials, but also an important means to obtain high-quality chemical raw materials from inferior raw materials. [0003] The one-time investment of the hydrocracking unit is relatively large, and the operating cost is also relatively high. Therefore, major research companies around the world are actively doing a lot of research ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C10G67/00
Inventor 彭冲曾榕辉王仲义崔哲孙士可石友良
Owner CHINA PETROLEUM & CHEM CORP
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