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Preparation method for modified gamma-Al2O3 carrier for mechanical industry

A technology of mechanical industry and modification, which is applied to catalyst carriers, chemical instruments and methods, catalysts for physical/chemical processes, etc., can solve the problems of surface property defects of alumina carrier, decrease in mechanical strength, etc. Increase the effect of expanding the pore size and increasing the specific surface area

Inactive Publication Date: 2015-05-20
华文蔚
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0011] However, there are still defects in the surface properties of the alumina carrier obtained by the above-mentioned treatment method, especially the loading capacity of surface active substances, and the sharp decline in mechanical strength under the condition of excessive specific surface area

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] Weigh 200g of alumina monohydrate dry rubber powder, wash with water to remove impurities, and then use an airflow dryer to quickly dry to a moisture content of 35%; then soak in a mixed solution of 10% acetic acid and 5% sucrose for 1 hour; Wash with water to remove unadsorbed acetic acid and sucrose, and air-dry at 100°C to obtain modified alumina; add 4.0g KCl, 4.0ml H 3 PO 4 , and an appropriate amount of H 2 O, fully mixed, kneaded into a plastic shape and extruded into clover strips (Ф = 1.4mm). After air drying overnight, it was dried at 110°C for 2 hours.

[0030] Place the dried sample in a high-temperature furnace, raise the temperature to 200°C at a rate of 3°C per minute, and

[0031] Roasting at constant temperature for 2.0 hours. Then, the temperature was raised to 485° C. at a rate of 4° C. per minute, and was roasted at a constant temperature at this temperature for 2.0 hours, and then the temperature was raised to 600° C. at a rate of 4° C. per minu...

Embodiment 2

[0033] Weigh 200g of alumina monohydrate dry rubber powder, wash with water to remove impurities, and then use an airflow dryer to quickly dry to a moisture content of 5%; then soak in a mixed solution of 10% acetic acid and 5% sucrose for 1 hour; Wash with water to remove unadsorbed acetic acid and sucrose, and air-dry at 100°C to obtain modified alumina; add 4.0g NaCl, 4.0ml H to the modified alumina 3 PO 4 , and an appropriate amount of H 2 O, fully mixed, kneaded into a plastic shape and then extruded into clover strips (Ф = 2.4mm). After air drying overnight, it was dried at 110°C for 2 hours.

[0034] Place the dried sample in a high-temperature furnace, raise the temperature to 200°C at a rate of 3°C per minute, and

[0035] Roasting at constant temperature for 2.0 hours. Then, the temperature was raised to 485°C at a rate of 4°C per minute, and then roasted at a constant temperature for 2.0 hours at this temperature, and then the temperature was raised to 700°C at ...

Embodiment 3

[0037] Weigh 250g of alumina monohydrate dry rubber powder, wash it with water to remove impurities, and then quickly dry it with an airflow dryer to a moisture content of 5%; then soak it in a mixed solution of 10% acetic acid and 5% sucrose for 1 hour; Wash with water to remove unadsorbed acetic acid and sucrose, and air-dry at 100°C to obtain modified alumina; add 8.0g NaCl, 4.0ml H to the modified alumina 3 PO 4 , and an appropriate amount of H 2 O, fully mixed, kneaded into a plastic shape and then extruded into clover strips (Ф = 1.0mm). After air drying overnight, it was dried at 110°C for 2 hours.

[0038] Place the dried sample in a high-temperature furnace and raise the temperature to 200°C at a rate of 3°C per minute, and at this temperature

[0039]Roasting at constant temperature for 2.0 hours. Then, the temperature was raised to 485° C. at a rate of 4° C. per minute, and was roasted at a constant temperature at this temperature for 2.0 hours, and then the tem...

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Abstract

The invention discloses a preparation method for a modified gamma-Al2O3 carrier for mechanical industry. The preparation method comprises the following steps: (1) performing water washing to remove impurities of alumina monohydrate and quickly drying with a gasflow dryer until moisture content is 3-5%; (2) soaking a product obtained in the step (1) in a mixed solution of acetic acid and saccharose with mass concentrations of 10% and 5% respectively for one hour; (3) removing the acetic acid and saccharose which are not adsorbed in the step (2) by water washing, and drying with gas flow of 100 DEG C to obtain modified aluminum oxide; (4) uniformly mixing the modified aluminum oxide obtained in the step (3) with peptizing acid to form a plastic form, extruding and molding on an extruding machine, drying and roasting to obtain the modified gamma-Al2O3 carrier.

Description

technical field [0001] The invention relates to modified gamma-Al for mechanical industry 2 o 3 The carrier is used for mechanized industrial production of products. Background technique [0002] Catalysts for hydrotreating of petroleum products (hydrodesulfurization, hydrodenitrogenation, hydrodemetallization, hydrogenation saturation, etc.) generally use γ-Al 2 o 3 Or γ-Al containing a small amount of other elements (such as alkali metals, etc.) 2 o 3 As a carrier, metals such as Mo (or w) and Ni (or Co) are used as active components. [0003] When designing hydrotreating catalysts, it is required that: [0004] (1) The metal can be highly dispersed on the surface of the carrier, and its chemical dispersion amount should be as large as possible, and this chemical dispersion amount is determined by the carrier, that is, γ-Al 2 o 3 determined by the surface properties of [0005] (2), for catalysts with large chemical dispersion of metals (such as MoO 3 MoNiP / Al wi...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J32/00B01J21/04
Inventor 华文蔚
Owner 华文蔚