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Production technology of thermal-insulation PU (polyurethane) material capable of absorbing harmful gases

A technology of thermal insulation and production process, which is applied in the production process of polyurethane thermal insulation materials, can solve problems such as cell collapse and loss of material mechanical properties, and achieve a product that is not easy to migrate and fall off, uniformly dispersed, and has good cohesion Effect

Inactive Publication Date: 2015-07-29
QUANGANG PETROCHEM RES INST OF FUJIAN NORMAL UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Especially in polyurethane thermal insulation materials, due to the existence of cells, if the combination of negative ion mineral powder and polyurethane is not good, it will easily lead to the collapse of the cells of polyurethane thermal insulation materials and the loss of mechanical properties of the material.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0034] Add 100 parts of polyol, 0.5 parts of silicone oil, 5.0 parts of blowing agent, 4.0 parts of tertiary amine catalyst, and 1.0 part of organotin catalyst into reaction vessel A, stir evenly under high-speed stirring and set aside.

[0035] Add 150 parts of polymethylene polyphenyl isocyanate (PAPI) to reaction vessel B, add 20 parts of PAPI-modified anion mineral powder after heating up to 50°C, stir and react at 120°C for 20 minutes, and then set aside.

[0036] Mix components A and B, stir for a while, pour into a mold to foam, mature and cut into certain sizes.

[0037] After testing, the toluene absorption rate of the polyurethane thermal insulation material prepared by the invention reaches 92.3%.

Embodiment 2

[0039] Add 100 parts of polyol, 0.2 parts of silicone oil, 15.0 parts of blowing agent, 3.0 parts of tertiary amine catalyst, and 1.5 parts of organotin catalyst into reaction vessel A, stir evenly under high-speed stirring and set aside.

[0040] Add 130 parts of polymethylene polyphenyl isocyanate (PAPI) into reaction vessel B, add 50 parts of PAPI-modified anion mineral powder after heating up to 50°C, stir and react at 100°C for 10-60 minutes, and then set aside.

[0041] Mix components A and B, stir for a while, pour into a mold to foam, mature and cut into certain sizes.

[0042] After testing, the polyurethane thermal insulation material prepared by the invention has an absorption rate of 90.5% for formaldehyde.

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PUM

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Abstract

The invention provides a production technology of a thermal-insulation PU (polyurethane) material capable of absorbing harmful gases. A formula (in parts by mass) and a technological process are as follows: 100 parts of polyalcohol, 0.1-1.0 part of silicone oil, 5-20 parts of a foaming agent, 3.0-5.0 parts of a tertiary amine catalyst and 1.0-3.0 parts of an organic tin catalyst are added to a reaction container A and evenly stirred at the high speed for use; 100-150 parts of PAPI (polyaryl polymethylene isocyanate) are added to a reaction container B, 2-20 parts of PAPI modified negative ion mineral powder are added after the reaction container B is heated to the temperature of 50 DEG C, and the mixture is stirred at the temperature of 100-120 DEG C for a reaction for 10-60 min for use; a component A and a component B are mixed and then stirred for a period of time, poured into a mold for foaming and cut into certain sizes after cured. Tests indicate that the absorptivity of the thermal-insulation PU material prepared with the technology to toxic and harmful gases is higher than 90%.

Description

technical field [0001] The invention belongs to the field of new building materials and the like, and in particular relates to a process for preparing a polyurethane thermal insulation material capable of absorbing harmful gases. Background technique [0002] With the strengthening of environmental protection and the popularization of the concept of energy saving and emission reduction, building insulation materials have begun to expand. Polyurethane thermal insulation materials are not only used for external wall insulation, but also for interior decoration. [0003] The irritating gases such as benzene, formaldehyde, ketone, ammonia volatilized from the decoration materials used in the interior decoration process, as well as the sour smell of leftovers in daily life, cigarettes and other harmful odors have seriously affected people's physical and mental health. For this reason, people adopt various methods to absorb toxic and harmful gases, such as the patent CN20131067171...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08G18/76C08G18/48C08G18/42C08K9/04C08K3/00
CPCC08G18/7664C08G18/4018C08G18/42C08G18/48C08G2101/00C08K3/00C08K9/04
Inventor 陈登龙伍毓强杜鹏飞白昕
Owner QUANGANG PETROCHEM RES INST OF FUJIAN NORMAL UNIV