Automobile bumper

A technology for automobile bumpers and bumpers, which is applied in the field of auto parts materials, can solve the problems of small elongation at break, insufficient impact strength, and low thermal deformation temperature, and achieve hardness and melt flow rate improvement, resistance Effects of improved chemical properties and high heat deflection temperature

Inactive Publication Date: 2015-08-05
CHONGQING JIAOTONG UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, most of the materials used for bumpers have problems such as poor shrinkage control, low paint adhesion, poor weather resistance, poor toughness, unsatisfactory impact resistance, small elongation at break and low thermal deformation temperature.
Chinese invention patent application CN1566196A discloses a new type of polypropylene composite material, which is composed of the following components by weight: copolymerized polypropylene pellets 25-60, thermoplastic elastomer 5-20, high-density polyethylene 0-20, Mineral filler 0-40, polar polymer material 0-10, anti-heat oxidant 0.1-0.6, coupling agent 0.1-0.3, light stabilizer 0.1-0.3, which have strong adhesion, but the volume change of the material is relatively small Large, poor impact resistance; and poor fluidity during molding, complicated preparation process
Chinese invention patent CN1235989A discloses a paintable modified polypropylene composition, which contains 100 parts of polypropylene, 10-50 parts of rubber-type toughening agent, 5-15 parts of oligomer, 5-20 parts Parts of grafted modified polypropylene, 1-15 parts of inorganic fillers, which are uniformly mixed with the above-mentioned various materials in proportion, melted and blended at a processing temperature of 180-220°C, and then extruded into pellets or internal mixer It is produced by granulation; the impact strength of the composition prepared by the above method is up to 629.6J / m, and when it is used as a material for preparing automobile bumpers, its impact strength is not high enough to absorb more impact energy , thereby reducing the safety performance of the car

Method used

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  • Automobile bumper

Examples

Experimental program
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Effect test

Embodiment 1

[0015] The bumper material includes the following components in parts by weight: 45 parts polypropylene, 8 parts bis(p-hydroxyphenyl)phenyl phosphine oxide, 10 parts thermoplastic polyurethane, 7 parts ultrafine magnesium hydroxide, 8 parts polyamide , 1-6 parts of acrylonitrile-butadiene-styrene, 6 parts of ethylene propylene rubber, 6 parts of polyethylene, 7 parts of shear thickening fluid, 14 parts of polymetaphenylene isophthalamide fiber, 3 parts Antistatic agent, 3 parts antioxidant, 6 parts dispersant, 3 parts plasticizer, 3 parts UV absorber.

[0016] In this embodiment, the antistatic agent is ethoxylauramide in ethoxylated alkylamine.

[0017] In this embodiment, the antioxidant is a mixture of dilauryl thiodipropionate and tetra[β-(3,5-di-tert-butyl-4-hydroxyphenyl)propionic acid] pentaerythritol ester. In the example, replace dilauryl thiodipropionate with one of dilauryl thiodipropionate, lauryl thiodipropionate, and didodecyl thiodipropionate in equal parts by weigh...

Embodiment 2

[0024] The bumper material includes the following components in parts by weight: 35 parts polypropylene, 2 parts bis(p-hydroxyphenyl)phenyl phosphine oxide, 5 parts thermoplastic polyurethane, 2 parts ultrafine magnesium hydroxide, 4 parts polyamide , 1 part of acrylonitrile-butadiene-styrene, 3 parts of ethylene propylene rubber, 3 parts of polyethylene, 4 parts of shear thickening fluid, 10 parts of poly(metaphenylene isophthalamide) fiber, 1 part of antistatic Agent, 1 part antioxidant, 4 parts dispersant, 1 part plasticizer, 1-5 parts stabilizer;

[0025] In this embodiment, the antistatic agent is glycerol monostearate (GMS).

[0026] In this embodiment, the antioxidant is a mixture of dilauryl thiodipropionate and tetra[β-(3,5-di-tert-butyl-4-hydroxyphenyl)propionic acid] pentaerythritol ester. In the example, replace dilauryl thiodipropionate with one of dilauryl thiodipropionate, lauryl thiodipropionate, and didodecyl thiodipropionate in equal parts by weight. Species, or...

Embodiment 3

[0033] The bumper material includes the following components in parts by weight: 55 parts of polypropylene, 10 parts of bis(p-hydroxyphenyl)phenyl phosphine oxide, 15 parts of thermoplastic polyurethane, 10 parts of ultrafine magnesium hydroxide, 12 parts of polyamide , 6 parts of acrylonitrile-butadiene-styrene, 11 parts of ethylene propylene rubber, 11 parts of polyethylene, 10 parts of shear thickening fluid, 16 parts of polymetaphenylene isophthalamide fiber, 6 parts of antistatic Agent, 4 parts antioxidant, 10 parts dispersant, 5 parts plasticizer, 5 parts stabilizer.

[0034] In this embodiment, the antistatic agent is an ethoxylated alkylamine.

[0035] In this embodiment, the antioxidant is a mixture of didodecyl thiodipropionate and tetrakis[β-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate]pentaerythritol, In this example, according to the same parts by weight, the dilauryl thiodipropionate was replaced with dilauryl thiodipropionate, dilauryl thiodipropionate, and lauryl ...

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Abstract

The invention discloses an automobile bumper which is made of materials including polypropylene, bis (p-hydroxyphenyl) phenyl phosphine oxide, thermoplastic polyurethane, ultrafine magnesium hydroxide, polyamide, acrylonitrile-butadiene-styrene, ethylene propylene rubber, polyethylene, shear thickening fluids, poly (m-phenylene isophthalamide) fibers, antistatic agents, antioxidants, dispersing agents, plasticizers and stabilizers. The materials of the bumper are low in shrinkage, high in flowability, fine in weather resistance and fine in paint performance, and have the advantages of high flexibility, strength, breaking elongation and heat distortion temperature. The bumper cannot fracture when an automobile is slightly collided. Compared with existing bumper materials, bending modulus, tensile strength, hardness and melt flow rate are greatly increased, and low-temperature impact resistance and chemical resistance are remarkably improved.

Description

Technical field [0001] The invention relates to the field of auto parts materials, in particular to automobile bumpers. Background technique [0002] PP is a semi-crystalline material. It is harder than PE and has a higher melting point. Since homopolymer PP is very brittle when the temperature is below 0°C, many commercial PP materials are random copolymers with 1 to 4% ethylene or clamp copolymers with higher ethylene content. Copolymer PP material has lower thermal distortion temperature (100°C), low transparency, low gloss, low rigidity, but has stronger impact strength. The strength of PP increases with the increase of ethylene content. The Vicat softening temperature of PP is 150°C. Due to the high crystallinity, the surface stiffness and scratch resistance of this material are very good. PP does not have the problem of environmental stress cracking. Usually, the PP is modified by adding glass fiber, metal additives or thermoplastic rubber. The flow rate MFR of PP ra...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/12C08K13/02C08K5/5397C07F9/53
CPCC08L23/12C07F9/53C08L2201/08C08L2205/02C08L2205/035
Inventor 邓涛韩海硕罗卫兴黄希光李德才
Owner CHONGQING JIAOTONG UNIVERSITY
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