Method for leaching copper from waste printed circuit boards by Thiobacillus ferrooxidans
A technology of Thiobacillus ferrooxidans and printed circuit boards, which is applied in the field of copper recovery from waste printed circuit boards, and can solve the problems of long leaching time, no consideration of bacterial growth, copper leaching rate, and low leaching rate. , to achieve the effect of shortening the leaching time
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Embodiment 1)
[0024] The method for leaching copper in waste printed circuit boards by Thiobacillus ferrooxidans of the present embodiment has the following steps:
[0025] ① Pretreatment of waste printed circuit boards. Remove the electronic components from the waste printed circuit board PCBs from an electronics factory in Changzhou, then crush and grind them into powder, and pass the ground waste PCBs powder through a sieve hole of 100 μm to 200 μm (the waste printed circuit board obtained by grinding in this example The powder passes through a 200μm sieve), and the waste PCBs powder that passes through the sieve is collected for processing.
[0026] After the discarded PCBs processed in this embodiment were ground and sieved, their main metal content was analyzed.
[0027] The main metal content is shown in Table 1 below:
[0028] Table 1 Main metal content in waste printed circuit board powder
[0029]
[0030] ② domestication of strains.
[0031] The sludge extracted from the a...
Embodiment 2)
[0051] The rest of the method for leaching copper in waste printed circuit boards by Thiobacillus ferrooxidans in this embodiment is the same as in Example 1, except that step ④ adds step ① to the strain culture system that has been cultivated in step ③ for 64 hours. When processing the waste PCBs powder obtained, the amount of PCBs powder added is 20g / L; after adding PCBs powder A. ferrooxidans The leaching reaction ended when the culture was continued for 120 hours; after the leaching reaction, the leaching rate of copper in discarded PCBs was determined to be 88.6%.
Embodiment 3)
[0053] The rest of the method for leaching copper in waste printed circuit boards by Thiobacillus ferrooxidans in this embodiment is the same as in Example 1, except that in the leaching process of step ④, the dissolved oxygen in the culture solution in the 5l fermenter is controlled At 30% to 40%, after the leaching reaction, the leaching rate of copper in waste PCBs was determined to be 96.7%.
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