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Process for rapidly separating sodium aluminate solution and washing red mud in aluminum oxide production

A technology of sodium aluminate and red mud, which is applied to the production of alumina, fly ash, and hydrometallurgical bauxite from nepheline, and can solve the problem of rapid separation of red mud, sufficient washing and alkali consumption of washing water that cannot be completed by a single separation equipment , large consumption of flocculant, large difference in dissolution rate of alumina net dissolution rate, etc., to achieve the effect of shortening separation and settling time, saving new water consumption, and saving bauxite resources

Inactive Publication Date: 2015-09-02
刘永刚 +2
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] The purpose of the present invention is to solve the technical problems existing in the existing alumina production process, and to provide a rapid separation of sodium aluminate solution and red mud washing process in the alumina production process. The difference between the dissolution rate and the actual dissolution rate is large, the secondary reaction is serious, the consumption of alkali, washing water, and flocculant is large, the sedimentation and running mixing and the cleaning of the settling tank are difficult, and a single separation equipment cannot complete rapid separation and full washing of red mud. Technical problems such as high liquid content of discharged red mud and inability to dry stack

Method used

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  • Process for rapidly separating sodium aluminate solution and washing red mud in aluminum oxide production
  • Process for rapidly separating sodium aluminate solution and washing red mud in aluminum oxide production

Examples

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Embodiment 1

[0035] see figure 1 , a sodium aluminate solution rapid separation and red mud washing process, comprising the following steps:

[0036] Step 1: Dilution of the dissolved pulp, the sodium aluminate clinker dissolved pulp is pumped to the mixer and mixed with a washing liquid for dilution, one of which is the first washing filtrate of red mud for washing and filtering equipment behind the process, after dilution The alkali concentration of the dissolved ore pulp is 150-180g / L, and the temperature is 100-110°C; preferably, the mixer is preferably a pipeline forced mixer manufactured by the Venturi principle.

[0037] The second step: separate and filter the diluted pulp, transport the mixed diluted pulp to the separation and filtration equipment for rapid separation, and separate the sodium aluminate solution from the red mud. An unqualified coarse filtration system is added to the separation and filtration equipment (the amount is very small, just the amount at the moment when...

Embodiment 2

[0043] see figure 2 , a sodium aluminate solution rapid separation and red mud washing process, comprising the following steps:

[0044] Step 1: The dissolved ore pulp is diluted and transported to the separation and settling tank, and 40-50g flocculant is added per ton of red mud for sedimentation and separation. The flocculant is preferably a synthetic flocculant, and the separation and sedimentation time is 0.25-1.5 hours; overflow The liquid is the crude liquid, which is sent to the semen control and filtration system in the crude liquid tank, and the floating matter in the crude liquid is controlled at 1-10g / L; the bottom flow of the settling tank enters the separation and filtration equipment, and the rapid separation operation time is 2-10 minutes, and the separation liquid is refluxed It is used for the dilution of the stripping pulp, and the red mud filter cake enters the subsequent process flow, and the liquid content of the filter cake is controlled at 35-45%.

[...

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Abstract

The invention relates to a process for rapidly separating sodium aluminate solution and washing red mud in an aluminum oxide production. According to the process, stable operation of rapid separation of a large-scale industrialized sodium aluminate solution and red mud washing is realized through the steps of mixing dilution, rapid separation, repulping, rapid washing, circulating water balance and the like; a flocculating agent does not need to be added or the addition amount can be reduced; the consumption of the flocculating agent and the investment in a settling tank are avoided or reduced; secondary loss of the aluminum oxide caused by overlong separation and settlement time is avoided; the dissolution rate and the total recovery rate of the aluminum oxide are improved, so that bauxite resources are saved and the production cost is reduced; meanwhile, due to the circulating water balance, a lot of washing water is available for a filtering medium (filter cloth), so as to ensure the filtering property when large filtering and washing equipment continuously runs; through reduction of wastewater in the red mud, and rapid separation and washing, the washing water is greatly reduced; the target of high recovery rate is finished; and the production cost of the aluminum oxide is reduced.

Description

【Technical field】 [0001] The invention belongs to the technical field of alumina production from hydrometallurgical bauxite, fly ash and nepheline, and specifically relates to rapid separation of sodium aluminate solution and red mud washing process in the alumina production process. 【Background technique】 [0002] my country's bauxite resources are naturally scarce, and the current domestic bauxite reserves only account for 2.4% of the world's total reserves. In recent years, foreign countries have imposed restrictions on the export of bauxite resources, making the actual requirements of increasing the dissolution rate of bauxite and reducing production costs more urgent. [0003] According to relevant statistics, in the alumina production process, whether it is sintering method, Bayer method or Bayer sintering combined method, the existing alumina dissolution slurry sedimentation separation technology, the net dissolution rate of alumina is 3% to 5% lower than the actual d...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01F7/06
Inventor 刘永刚杨武柳健康王强张敏刘希泉罗付洪
Owner 刘永刚
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