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Lead-free and low-toxicity polyvinyl chloride composite material and preparation method thereof

A technology of polyvinyl chloride and composite materials, applied in the field of lead-free and low-toxicity polyvinyl chloride composite materials and their preparation, can solve the problems of deposition, producer injury, hidden dangers of human and animal health, etc., achieve strong weather resistance, reduce dust , the effect of excellent static thermal stability

Active Publication Date: 2015-09-02
杭州鸿雁管道系统科技有限公司 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the current national standards for rain and drainage pipe systems do not limit the content of heavy metals such as lead, and the current production of PVC rain and drainage pipes uses a large number of lead salt stabilizers, which not only may cause great harm to producers during the production process but also to The surrounding environment, including water, soil and air, causes the deposition of heavy metals, which poses immeasurable health risks to humans and animals living in this environment

Method used

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  • Lead-free and low-toxicity polyvinyl chloride composite material and preparation method thereof
  • Lead-free and low-toxicity polyvinyl chloride composite material and preparation method thereof
  • Lead-free and low-toxicity polyvinyl chloride composite material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0059] Add 0.1mol sodium metal to 100ml absolute ethanol, stir and reflux for 0.5h to prepare a concentrated sodium ethylate / ethanol solution; 0.1mol urea, 0.2mol cyanoacetic acid, and 0.1mol acetic anhydride are reacted and refluxed for 40min at 80°C in a 500ml three-necked flask Finally, add 100ml of the prepared concentrated sodium ethylate / ethanol solution and continue to heat and reflux for 3h, then slowly add hydrochloric acid solution dropwise to adjust the pH to 7, then add 0.1mol of stearic acid until it completely melts and dissolves; after raising the temperature to 95°C, Slowly add 0.1mol of zinc chloride dropwise, and then stir for 2.5h after dropping, after cooling to room temperature, filter the product with suction, soak and wash with water mist, dry at 80-90°C to constant weight, and prepare N,N-di Methyl-6-aminouracil zinc salt, yield 83%.

[0060] Convert the anion to CO 3 2- 0.95 kg of hydrotalcite, 0.05 kg of bisphenol A epoxy resin (E44) with an epoxy v...

Embodiment 2

[0063] Add 0.1mol sodium metal to 100ml absolute ethanol, stir and reflux for 0.5h to obtain a concentrated sodium ethylate / ethanol solution; add 0.1mol urea and continue to reflux for 0.5h, then add 10.6ml of ethyl cyanoacetate dropwise and continue to reflux for 3h before cooling Slowly add hydrochloric acid solution dropwise to adjust the pH to 7, then add 0.1mol of stearic acid until it is completely melted and dissolved; after raising the temperature to 90-95°C, slowly add 0.1mol of zinc chloride dropwise, and then stir for 2.5h after the dropwise completion. After cooling to room temperature, the product was suction-filtered, soaked and washed with water mist, and dried at 80-90° C. to constant weight to prepare N-methyl-6-aminouracil zinc salt with a yield of 93%.

[0064] Convert the anion to CO 3 2- 0.95 kg of hydrotalcite, 0.05 kg of bisphenol A epoxy resin (E44) with an epoxy value of 0.4 to 0.6, pre-mixed evenly, and sheared and mixed for 20 minutes on a mixer at ...

Embodiment 3

[0068] Add 0.1mol sodium metal to 100ml absolute ethanol, stir and reflux for 0.5h to obtain a concentrated sodium ethylate / ethanol solution, then add 0.1mol thiourea and continue to reflux for 0.5h, then add 10.6ml of ethyl cyanoacetate dropwise and continue to reflux for 3h . After cooling, add 4mol / L hydrochloric acid solution dropwise to adjust the pH to 7, then add 0.1mol stearic acid until it completely melts and dissolves; after raising the temperature to 90-95°C, slowly add 0.1mol zinc sulfate heptahydrate dropwise. Stir for another 2.5h, after cooling to room temperature, filter the product with suction, soak and wash with water mist, and dry at 80-90°C to constant weight to prepare N-methyl-6-thiosemicarbazide zinc salt with a yield of 95% .

[0069] Convert the anion to CO 3 2- 0.95 kg of hydrotalcite, 0.05 kg of bisphenol A epoxy resin (E44) with an epoxy value of 0.4 to 0.6, after pre-mixing uniformly, shear and knead for 20 minutes on a mixer at 140 ° C to obt...

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PUM

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Abstract

The present invention discloses a lead-free and low-toxicity polyvinyl chloride composite material and a preparation method thereof. The lead-free and low-ticity polyvinyl chloride composite material comprises the following components in part: 100 parts of polyvinyl chloride resin, 8-12 parts of chlorinated polyvinyl chloride, 3.0-5.0 parts of organic composite heat stabilizer, 5-12 parts of organic hydrotalcite, 1-2 parts of polyhydroxy stearate, 3-8 parts of chlorinated polyethylene, and the 0.7-1.3 parts of TiO2. The above materials, as raw materials, are mixed up through the hot-mixing process in a high-speed mixer to be uniformly dispersed. When the temperature of the mixture reaches 123-126 DEG C, the mixture is put to a cold pot to be further stirred till the temperature thereof lowered to 50-60 DEG C. After that, the mixture is put into an anti-clockwise conical twin-screw extruder to be mixed up, extruded and granulated at 165-180 DEG C. The above composite material is lead-free, low in toxicity and good in mechanical performance. The zinc-burning phenomenon of the conventional polyvinyl chloride composite material is improved. Meanwhile, the lead-free and low-toxicity polyvinyl chloride composite material is more environment-friendly.

Description

technical field [0001] The invention relates to the field of polyvinyl chloride composite materials, in particular to a lead-free and low-toxicity polyvinyl chloride composite material and a preparation method thereof. Background technique [0002] Polyvinyl chloride (PVC) is one of the five general-purpose resins (PE, PVC, PP, PS, ABS) in the world. However, the structure of PVC is unstable, and it is easy to degrade during processing and molding. When the processing temperature reaches 90°C, a slight thermal decomposition reaction occurs; when the temperature reaches 120°C, an obvious thermal decomposition reaction occurs, making the color of PVC gradually deepen. Therefore, heat stabilizers must be used to prevent thermal decomposition of PVC during processing. [0003] For example, the Chinese invention patent application with the publication number CN 102382398A discloses a modified polyvinyl chloride composite material and a preparation method, wherein the components ...

Claims

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Application Information

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IPC IPC(8): C08L27/06C08L27/24C08L23/28C08K13/06C08K9/04C08K3/26C08K3/22C08K5/098C08K5/3462C08K5/07
CPCC08K2201/011C08L27/06C08L2201/08C08L2205/02C08L2205/03C08L27/24C08L23/286C08K13/06C08K9/04C08K3/26C08K2003/2237C08K5/098C08K5/3462C08K5/07
Inventor 朱杭琦盛仲夷马骥徐康郭芷含谢松桂
Owner 杭州鸿雁管道系统科技有限公司
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