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Moisture curing polyacrylate/polyurethane composite waterproof coating and preparation method thereof

A polyacrylate, waterproof coating technology, applied in the direction of polyurea/polyurethane coatings, coatings, etc., can solve the problems of poor solvent resistance, poor flexibility, poor adhesion, etc., to avoid carcinogenic effects, good mechanical properties, Great adhesion effect

Active Publication Date: 2017-10-03
国科广化(南雄)新材料研究院有限公司 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In waterproof coatings, polyacrylate waterproof coatings are weather-resistant, alkali-resistant, water-resistant and powder-resistant, but there are also some shortcomings: 1. Poor adhesion, the coating film will fall off after a long time, and the wet base surface cannot be coated; 2. Flexibility Not good, the coating film is rigid and not impact-resistant; 3. The solvent resistance is poor, and the coating film is easily damaged after being soaked in solvent
Polyurethane waterproof coatings have the advantages of good abrasion resistance, flexibility, oil resistance, and strong adhesion. The disadvantages are: 1. Poor weather resistance, which will pulverize after a period of use; Foaming occurs, resulting in poor waterproof effect; 3. Poor alkali resistance, brushing in an alkaline environment will cause the coating film to become hard and brittle, and the elasticity will be greatly reduced
The crosslinking agent commonly used in polyurethane waterproof coatings is mocha, which is expensive, toxic and carcinogenic, and also has the risk of burning and explosion.
The existing research adopts the method of moisture curing to reduce the cost and be environmentally friendly, but this method has not been able to combine with polyacrylate

Method used

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  • Moisture curing polyacrylate/polyurethane composite waterproof coating and preparation method thereof
  • Moisture curing polyacrylate/polyurethane composite waterproof coating and preparation method thereof
  • Moisture curing polyacrylate/polyurethane composite waterproof coating and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0040] The synthetic method steps of polyurethane prepolymer are as follows: add 95 parts by weight of polyether diol N220 of water removal, 5 parts by weight of polyether glycol L44 of water removal, and 18 parts by weight of toluene diisocyanate into a reaction vessel, and heat to React at 70°C for 4 hours to obtain a polyurethane prepolymer.

[0041]The synthetic method step of the polyacrylate containing isocyanate group is as follows: 80 weight parts of methyl methacrylate, 20 weight parts of hydroxyethyl methacrylate, 200 weight parts of methyl ethyl ketone, 2 weight parts of azobisisoheptanonitrile are added to In the reactor, the temperature was raised to 60° C., and the reaction was carried out for 4 hours, then 26 parts by weight of toluene diisocyanate was added, and finally methyl ethyl ketone was removed to obtain isocyanate group-containing polyacrylate.

[0042] Add 25 parts by weight of polyacrylate containing isocyanate group, 3 parts by weight of white carbon...

Embodiment 2

[0044] The steps for synthesizing the polyurethane prepolymer are as follows: Add 100 parts by weight of polyether diol N220 and 9 parts by weight of naphthalene diisocyanate into a reaction vessel, heat to 95°C, and react for 8 hours to prepare the polyurethane prepolymer .

[0045] The synthetic method step of the polyacrylate containing isocyanate group is as follows: 50 parts by weight of butyl methacrylate, 46 parts by weight of isooctyl methacrylate, 4 parts by weight of hydroxyethyl methacrylate, 200 parts by weight of 3-pentanone 2 parts by weight of azobisisobutyronitrile were added to the reactor, the temperature was raised to 80°C, and the reaction was carried out for 7 hours, then 5 parts by weight of isophorone diisocyanate was added, and 3-pentanone was finally removed to obtain isocyanate group-containing Polyacrylate.

[0046] Add 12 parts by weight of polyacrylate containing isocyanate group, 4 parts by weight of white carbon black, 4 parts by weight of silic...

Embodiment 3

[0048] The steps of the synthetic method of polyurethane prepolymer are as follows: 90 parts by weight of polyether glycol N220 for water removal, 6 parts by weight of polyether glycol N210 for water removal, 4 parts by weight of polyether glycol L44 for water removal, Add 13 parts by weight of xylylene diisocyanate into the reaction vessel, heat to 85° C., and react for 7 hours to prepare a polyurethane prepolymer.

[0049] The synthetic method step of the polyacrylate containing isocyanate group is as follows: 60 parts by weight of methyl acrylate, 34 parts by weight of isooctyl methacrylate, 6 parts by weight of hydroxypropyl methacrylate, 200 parts by weight of 2-pentanone, Add 2 parts by weight of nitrogen diisoheptanonitrile into the reactor, heat up to 68°C, react for 5 hours, then add 8 parts by weight of xylylene diisocyanate, and finally remove 2-pentanone to obtain isocyanate group-containing poly Acrylate.

[0050] Add 15 parts by weight of polyacrylate containing...

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Abstract

The invention belongs to the technical field of waterproof coatings, and discloses a moisture-curing polyacrylate / polyurethane composite waterproof coating and a preparation method thereof. The coating comprises the following components by weight: 100 parts of polyurethane prepolymer; 12-25 parts of polyacrylate containing isocyanate groups; 5-25 parts of filler; 0.1-0.5 parts of defoaming agent; 0.1-0.4 parts of leveling agent ; 0.1-0.4 parts of ultraviolet absorber; 0.1-0.5 parts of antioxidant. In the invention, the diisocyanate is connected to the polyacrylate through a chemical reaction, then compounded with the polyurethane prepolymer, cured by moisture, and bonded together by water to realize an effective combination. The obtained coating not only has the advantages of weather resistance and chalking resistance of polyacrylate waterproof coating, but also has the advantages of flexibility and strong adhesion of polyurethane waterproof coating. At the same time, it has good mechanical properties and high solid content. Products, especially suitable for waterproofing in special fields.

Description

technical field [0001] The invention belongs to the technical field of waterproof coatings, in particular to a moisture-curing polyacrylate / polyurethane composite waterproof coating and a preparation method thereof. Background technique [0002] Waterproof coating is a kind of protective material that forms a dense coating film after construction, and it is used more and more in the field of building waterproofing. In waterproof coatings, polyacrylate waterproof coatings are weather-resistant, alkali-resistant, water-resistant and powder-resistant, but there are also some shortcomings: 1. Poor adhesion, the coating film will fall off after a long time, and the wet base surface cannot be coated; 2. Flexibility Not good, the coating film is rigid and not resistant to impact; 3. The solvent resistance is poor, and the coating film is easily damaged after being soaked in solvent. Polyurethane waterproof coatings have the advantages of good abrasion resistance, flexibility, oil ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D175/08C09D7/12C08G18/48C08F220/14C08F220/28C08F220/18
Inventor 刘伟区王世建
Owner 国科广化(南雄)新材料研究院有限公司