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Steel and iron surface phosphating agent and preparation method thereof

A technology of phosphating treatment and steel surface, which is applied in the direction of metal material coating process, etc., can solve the problems of large amount of acid mist, affecting the effect of phosphating, and destroying the active components of phosphating solution, so as to achieve good corrosion resistance and improve the quality of the workshop. The effect of the production environment

Inactive Publication Date: 2015-12-30
HUNAN JINHUA SCI & TECH GRP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Phosphating solution is required for phosphating treatment. Currently commonly used phosphating solutions (including the above-mentioned commonly used phosphating solutions) usually have some deficiencies during transportation, storage and use. The specific performance is as follows: the storage time of phosphating solution is mostly It should not exceed one month. After a long storage time, gray sediment will be produced due to oxidation and disproportionation reactions. As a result, the active ingredients in the phosphating solution will be damaged, resulting in a decrease in the phosphating effect, and the resulting phosphating film becomes loose
At present, the following methods are usually used for phosphating and passivation treatment of steel pipes in the industry: 1. After phosphating treatment, concentrated acid is used for passivation treatment. This method needs to control the concentration of acid in the treatment tank. If the concentration of acid If it is lower than the critical value, not only will it fail to achieve a passivation effect, but it will also aggravate the corrosion of the steel pipe surface, and this treatment method will generate a large amount of acid mist and the working environment will be harsh
2. Add an appropriate amount of passivation treatment agent to the treatment tank during phosphating treatment, which requires that the ratio of phosphating treatment agent and passivation treatment agent must be within an appropriate range, otherwise it will lead to a reduction in the effectiveness of each other, for example Too much dose of passivation treatment will affect the phosphating effect, resulting in too thin phosphating film

Method used

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Embodiment approach

[0011] As an embodiment of the present invention, a steel surface phosphating treatment agent, the weight proportion of its components is: potassium dichromate 3%, composite phosphate 3.5%, concentration is 65% nitric acid 16%, concentration It is 85% phosphoric acid 18%, CyDTA complexing agent 0.1%, sodium sulfite 7%, and the balance is water.

[0012] As another aspect of the present invention, the method for preparing above-mentioned iron and steel surface phosphating treatment agent comprises the following steps:

[0013] In the first step, prepare each component according to the above weight ratio and put them in corresponding containers, take a part of water from the container filled with water and add it to the reactor and heat the water in the reactor to 42-47 ℃, then while stirring, successively add phosphoric acid, compound phosphate, CyDTA complexing agent, sodium sulfite, potassium dichromate to the reaction kettle;

[0014] In the second step, after the above-men...

Embodiment 1

[0018] Under normal pressure, according to: 3% potassium dichromate, 3.5% compound phosphate, 16% nitric acid with a concentration of 65%, 18% phosphoric acid with a concentration of 85%, 0.1% CyDTA complexing agent, 7% sodium sulfite, and The amount is the weight ratio of water. Prepare each component, and put the above components in the corresponding container, then take a part of water from the water container and add it to the reactor and heat the water in the reactor to 42-47°C, then while stirring, add phosphoric acid, complex phosphate, CyDTA complexing agent, sodium sulfite, potassium dichromate to the reaction kettle successively, after the above components are completely dissolved, cool the resulting solution to room temperature, then in Add nitric acid under ventilated conditions, and finally add the remaining water to obtain the steel surface phosphating treatment agent of this embodiment, and the above steps should be carried out under normal pressure.

[0019] Th...

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Abstract

The invention provides a steel and iron surface phosphating agent and a preparation method thereof, relating to the technical field of metal surface treating agents. The steel and iron surface phosphating agent comprises the following components in percentage by weight: 3% of potassium dichromate, 3.5% of composite phosphate, 16% of 65% nitric acid, 18% of 85% phosphoric acid, 0.1% of a CyDTA complexing agent, 7% of sodium sulfite and the balance of water. The steel and iron surface phosphating agent can be used for simultaneously phosphating and passivating the surface of a steel pipe; the quantity of acid fog generated by the phosphating agent in the actual production process is relatively low, so that the production environment of a workshop is greatly improved; more importantly, the steel and iron surface phosphating agent can form a uniform and compact phosphating film on the surface of a steel and iron workpiece after being stored for two months, and the problem of effect lowering caused by overlong storage time can be avoided; and in addition, the phosphating agent can also form a compact passivating film on the surface of the steel pipe, and the steel pipe treated by using the phosphating agent has favorable corrosion resistance.

Description

technical field [0001] The invention relates to the technical field of a metal surface treatment agent, in particular to a steel surface phosphating treatment agent and a preparation method thereof. Background technique [0002] Steel parts need to undergo comprehensive surface treatment before painting. The current comprehensive surface treatment process usually includes rust removal, degreasing, phosphating, passivation and other processes. [0003] Phosphating solution is required for phosphating treatment. Currently commonly used phosphating solutions (including the above-mentioned commonly used phosphating solutions) usually have some deficiencies during transportation, storage and use. The specific performance is as follows: the storage time of phosphating solution is mostly It should not exceed one month. After a long storage time, gray sediment will be produced due to oxidation and disproportionation reactions. As a result, the active ingredients in the phosphating s...

Claims

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Application Information

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IPC IPC(8): C23C22/33
Inventor 赵端泉
Owner HUNAN JINHUA SCI & TECH GRP
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