The invention relates to a methanesulfonic acid tin-plating solution. The methanesulfonic acid tin-plating solution comprises 10-40 g/L of Sn2+, 1-5% of methanesulfonic acid, 0.5-15% of a compound antioxidant and 0.5-4% of a grain refiner, wherein the compound antioxidant comprises a main antioxidant body and an auxiliary antioxidant body; the main antioxidant body is prepared from one or more of phenol, catechol, resorcinol, hydroquinone and carboxyl, amidogen, nitro and sulfonate group substitutes thereof; and the auxiliary antioxidant body is prepared from (2R, 3S)-2-(3,4- dihydroxy phenyl)-3,4-dihydro-2H-benzopyran-3,5,7-triol and (2S,3R)-2-(3,4-ihydroxy phenyl)-3,4-dihydro-1(2H)-benzo-3,5,7-triol3-(3,4,5-trihydroxybenzoic acid). The tin-plating solution contains the compound antioxidant, tin slurry in the plating solution can be effectively reduced, and meanwhile after the grain refiner is added, a tin-plated plate with a coating having excellent quality can be obtained.