Composite complexing agent and chemical nickel-plating solution containing same

A compound complexing agent and electroless nickel plating technology, which is applied in the direction of liquid chemical plating, metal material coating process, coating, etc., can solve the problems that cannot meet the development requirements of energy saving, consumption reduction, pollution reduction and efficiency enhancement, etc., and achieve high Hardness, high hardness, good stability

Inactive Publication Date: 2011-04-20
GUANGZHOU JINHUI CHEM SCI TECH
View PDF4 Cites 7 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The Chinese patent application with publication number CN1600899A discloses a composite additive for electroless nickel plating, which is composed of complexing agents such as citric acid, buffers such as sodium acetate, accelerators such as succinic acid, and stabilizers such as thiourea; Although it avoids the trouble of a lot of analysis and adjustment of various components, it is more convenient to use; but the service life of the plating solution is only 6-8 cycles, which cannot meet the development requirements of "energy saving, consumption reduction, pollution reduction and efficiency increase".

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] The environmental protection electroless nickel plating solution of the present invention, formula consists of:

[0029] Nickel sulfate 35g / L

[0030] Lactic acid 7ml / L

[0031] Sodium acetate 5g / L

[0032] Sodium hypophosphite 30g / L

[0033] Compound Complexing Agent 8g / L

[0034] Stabilizer 0.1g / L

[0035] Sodium laurate sulfate 0.2g / L

[0036] The environment-friendly electroless nickel plating solution of the present invention weighs raw materials according to the above formula, and dilutes to 1 L to obtain the electroless nickel plating solution.

[0037] The composite complexing agent consists of:

[0038] The content of each component in one liter of aqueous solution is: adipic acid 5g, tartaric acid 10g, malic acid 4g, citric acid 10g, succinic acid 5g.

[0039] Take by weighing 35g of nickel sulfate, 7ml of lactic acid, 5g of sodium acetate, 30g of sodium hypophosphite, 8g of complex complexing agent, 0.1g of stabilizer (sodium thiosulfate), 0.2g of sodi...

Embodiment 2

[0041] The environmental protection electroless nickel plating solution of the present invention, formula consists of:

[0042] Nickel sulfate 25g / L

[0043] Lactic acid 10ml / L

[0044] Sodium acetate 10g / L

[0045] Sodium hypophosphite 20g / L

[0046] Compound Complexing Agent 30g / L

[0047] Stabilizer 1.5g / L

[0048] Sodium Lauryl Sulfate 1g / L

[0049] The environment-friendly electroless nickel plating solution of the present invention weighs raw materials according to the above formula, and dilutes to 1 L to obtain the electroless nickel plating solution.

[0050] The composite complexing agent consists of:

[0051] The content of each component in one liter of aqueous solution is: adipic acid 100g, tartaric acid 3g, malic acid 8g, succinic acid 6g.

[0052] Take by weighing nickel sulfate 25g, lactic acid 10ml, sodium acetate 10g, hypophosphorous acid 20g, composite complexing agent 30g, stabilizer (thiourea 1g and potassium iodate 0.5g), sodium lauryl sulfate 1g, d...

Embodiment 3

[0054] The environmental protection electroless nickel plating solution of the present invention, formula consists of:

[0055] Nickel sulfate 30g / L

[0056] Lactic acid 8ml / L

[0057] Sodium acetate 5g / L

[0058] Sodium hypophosphite 40g / L

[0059] Compound complexing agent 20g / L

[0060] Stabilizer 1g / L

[0061] Sodium Lauryl Sulfate 0.2g / L

[0062] The environment-friendly electroless nickel plating solution of the present invention weighs raw materials according to the above formula, and dilutes to 1 L to obtain the electroless nickel plating solution.

[0063] The composite complexing agent consists of:

[0064] The contents of each component in one liter of aqueous solution are: 5 g of succinic acid, 50 g of adipic acid, 15 g of tartaric acid, and 5 g of malic acid.

[0065] Take by weighing nickel sulfate 30g, lactic acid 8ml, sodium acetate 5g, sodium hypophosphite 40g, composite complexing agent 20g, stabilizer (molybdenum oxide 0.2g, sodium thiosulfate 0.1g, p...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

No PUM Login to view more

Abstract

The invention discloses a composite complexing agent and a chemical nickel-plating solution containing the same. In the invention, the composite complexing agent comprises the following components: 5-100g of adipic acid, 3-15g of tartaric acid, 4-15g of one or two of malic acid and citric acid and 5-6g of succinic acid or propionic acid. The invention solves the problem of short circulation cycleof a plating solution in the prior art, and meanwhile, the chemical nickel-plating solution does not contain 18 pollutants, such as lead, cadmium and the like to which high global attention is paid, therefore, the invention has the advantages that the work temperature is lower, the hardness is high and the corrosion-resistance performance is high, and the requirement on cleaning production is met.

Description

technical field [0001] The invention relates to the field of electroless nickel plating, in particular to a composite complexing agent and an electroless nickel plating solution containing the composite complexing agent. Background technique [0002] Electroless plating is a chemical treatment process that uses a suitable reducing agent to reduce the metal ions in the solution and deposit them on the surface of the catalytically activated plating. [0003] In recent years, as a surface treatment technology, electroless plating has been paid more and more attention in industry, and its application range covers various fields of industrial production. The continuous development of electroless nickel plating is attributed to the good manufacturability of the technology. The electroless nickel plating layer has unique physical, chemical and mechanical properties, and the process equipment is simple, easy to control and master, and the coating is uniform and flat, suitable for pa...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Applications(China)
IPC IPC(8): C23C18/36
Inventor 陈少慧
Owner GUANGZHOU JINHUI CHEM SCI TECH
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products