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A kind of modified rubber material for automobile rubber hose and preparation method thereof

A technology of modified rubber and automobile rubber hose, which is applied in the field of rubber materials, can solve the problems of restricting the use of industrial products, the effect is not ideal, and it is difficult to meet the performance requirements, and achieves low cost, improved high temperature resistance and oil resistance, and simple process Effect

Active Publication Date: 2018-02-16
SUZHOU GOODTIME TECH DEV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

With the rapid development of modern industry, the environmental conditions of industrial products are getting worse and worse, and higher requirements are put forward for the performance of products. The existing rubber materials have some defects of their own, and the products produced by them are often difficult to meet. Performance requirements restrict its use in industrial products to a large extent
[0003] At present, in the prior art, there have been researches on the use of EPDM rubber and chlorinated polyethylene rubber to make rubber hoses for automobiles. Although compared with conventional automobile rubber hoses, its high temperature resistance and oil resistance have been improved to a certain extent. But the effect is still not ideal enough to meet higher requirements

Method used

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  • A kind of modified rubber material for automobile rubber hose and preparation method thereof

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Experimental program
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Effect test

Embodiment 1

[0020] Party:

[0021] EPDM rubber 40 parts, maleic anhydride 10 parts, chlorinated polyethylene rubber 40 parts, silane coupling agent 2 parts, perfluoroether rubber 20 parts, zinc oxide 1 part, stearic acid 2 parts, carbon black 15 parts 2 parts of sulfur, 0.2 parts of butylated hydroxytoluene, 0.3 parts of zinc methacrylate, and 30 parts of acetone.

[0022] Preparation:

[0023] (1) Take EPDM rubber and maleic anhydride, add them to half the amount of acetone, react at 30°C for 10 hours, raise the temperature to 50°C, and continue to react for 10 hours to obtain the initial reaction solution;

[0024] (2) Take chlorinated polyethylene rubber and perfluoroether rubber, add them to the remaining acetone, mix them with the above initial reaction solution, and then add silane coupling agent, zinc oxide, stearic acid, carbon black, butyl Hydroxymethanol and zinc methacrylate are fully mixed and smelted at 60°C to obtain masterbatch;

[0025] (3) Molding the above-mentioned m...

Embodiment 2

[0027] Party:

[0028] EPDM rubber 40 parts, maleic anhydride 20 parts, chlorinated polyethylene rubber 60 parts, titanate coupling agent 8 parts, perfluoroether rubber 40 parts, zinc oxide 9 parts, stearic acid 6 parts, carbon Black 35 parts, sulfur 6 parts, butylated hydroxytoluene 0.8 parts, zinc methacrylate 0.7 parts, acetone 40 parts.

[0029] Preparation:

[0030] (1) Take EPDM rubber and maleic anhydride, add them to half the amount of acetone, react at 40°C for 20 hours, heat up to 60°C, and continue to react for 20 hours to obtain the initial reaction solution;

[0031] (2) Take chlorinated polyethylene rubber and perfluoroether rubber, add them to the remaining acetone, mix them with the above-mentioned initial reaction solution, and then add titanate coupling agent, zinc oxide, stearic acid, carbon black, Butylated hydroxymethyl and zinc methacrylate are fully mixed and melted at 80°C to obtain masterbatch;

[0032] (3) Molding the above-mentioned masterbatch, a...

Embodiment 3

[0034] Party:

[0035] 40 parts of EPDM rubber, 15 parts of maleic anhydride, 50 parts of chlorinated polyethylene rubber, 5 parts of aluminate coupling agent, 30 parts of perfluoroether rubber, 5 parts of zinc oxide, 4 parts of stearic acid, carbon Black 25 parts, sulfur 4 parts, butylated hydroxytoluene 0.5 parts, zinc methacrylate 0.5 parts, acetone 35 parts.

[0036] Preparation:

[0037] (1) Take EPDM rubber and maleic anhydride, add them to half the amount of acetone, react at 35°C for 15 hours, raise the temperature to 55°C, and continue to react for 15 hours to obtain the initial reaction solution;

[0038] (2) Take chlorinated polyethylene rubber and perfluoroether rubber, add them to the remaining acetone, mix with the above-mentioned initial reaction liquid, then add aluminate coupling agent, zinc oxide, stearic acid, carbon black, Butylated hydroxymethyl and zinc methacrylate are fully mixed and melted at 70°C to obtain masterbatch;

[0039] (3) Molding the abov...

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Abstract

The present invention discloses an automobile rubber hose modified rubber material and a preparation method thereof, the rubber material is mainly made from the following components by weight: 40 parts of EPDM rubber, 10-20 parts of maleic anhydride , 40 to 60 parts of chlorinated polyethylene rubber, 2-8 parts of a coupling agent, 20-40 parts of Kalrez, 1-9 parts of zinc oxide, 2-6 parts of stearic acid, 15-35 parts of carbon black, 2-6 parts of sulfur, 0.2 to 0.8 part of butylated hydroxytoluene, 0.3 to 0.7 part of zinc methacrylate, and 30 to 40 parts of acetone. Compared with the prior art, the automobile rubber hose modified rubber material obtained by the preparation method is simple in process and low in cost, not only has the advantages of the prior art rubber material, and can further enhance the high temperature resistance and oil resistance of a rubber material.

Description

technical field [0001] The invention relates to a modified rubber material for automobile rubber hoses and a preparation method thereof, belonging to the technical field of rubber materials. Background technique [0002] Hose is a type of tubular rubber product used to transport gas, liquid, slurry or granular materials. It is composed of inner and outer rubber layers and a skeleton layer. The material of the skeleton layer can be cotton fiber, various synthetic fibers, carbon fiber or asbestos, steel wire, etc. Generally, the inner and outer rubber layers of rubber hoses are made of natural rubber, styrene-butadiene rubber or butadiene rubber; oil-resistant hoses are made of neoprene, nitrile rubber, etc. With the rapid development of modern industry, the environmental conditions of industrial products are getting worse and worse, and higher requirements are put forward for the performance of products. The existing rubber materials have some defects of their own, and the p...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L23/28C08L51/04C08L71/00C08K13/02C08K5/09C08K3/04C08K3/06C08K5/07C08K3/22
CPCC08L23/286C08L51/04C08L2201/08C08L2205/03C08L71/00C08K13/02C08K5/09C08K3/04C08K3/06C08K5/07C08K2003/2296
Inventor 周波
Owner SUZHOU GOODTIME TECH DEV
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