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Application of heat-resistant porous diaphragm to lithium ion battery

A technology of lithium-ion batteries and porous diaphragms, which is applied to battery components, circuits, electrical components, etc., can solve the problems of battery micro-short circuit, large diaphragm pore size, self-discharge, etc., and achieve improved adsorption rate, high porosity, and easy Magnified effect

Active Publication Date: 2016-02-03
DALIAN INST OF CHEM PHYSICS CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the pore size of this type of separator is relatively large, and most of them are straight through holes, which can easily lead to micro-short circuit, self-discharge and liquid leakage in the battery.

Method used

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  • Application of heat-resistant porous diaphragm to lithium ion battery
  • Application of heat-resistant porous diaphragm to lithium ion battery
  • Application of heat-resistant porous diaphragm to lithium ion battery

Examples

Experimental program
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Effect test

Embodiment 1

[0029] 10 g of polyetherimide was dissolved in 40 ml of nitrogen methylpyrrolidone to form a polymer solution. Spread the solution on a glass plate (scratch thickness 80um), and then put the glass plate in a constant temperature and humidity box with a temperature of 50° C. and a humidity of 100% for 5 minutes to obtain a porous diaphragm. The cross-sectional structure of the film was analyzed by scanning electron microscopy ( figure 1 ), the membrane cross-section is a highly symmetrical sponge-like structure. Lithium-ion coin cells were assembled for testing, wherein the assembly of the lithium-ion coin cells was carried out in an argon-filled glove box. Using LiFePO4 as the positive electrode material and lithium sheet as the negative electrode, the TC-E269 electrolyte provided by Guangzhou Tinci and the prepared separator were used to assemble a half-cell for testing. The cycle test is carried out between 2.5-4.2V, and the battery is charged and discharged at a rate of ...

Embodiment 2

[0034] Others are the same as embodiment 1, polyetherimide is changed into polyimide.

Embodiment 3

[0036] Others are the same as in Example 1, except that polyetherimide is changed to polyethersulfone.

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Abstract

The invention relates to application of a heat-resistant porous diaphragm to a lithium ion battery. The porous diaphragm is prepared from one or more than two of heat-resistant high-molecular polymers such as polysulfone, polyketone, polyimide, polybenzimidazole and polyetherimide; the pore diameter of the porous diaphragm is 5-500 nm, and the porosity rate is 30-70%. The porous diaphragm is high in porosity rate, the pore structure of porous diaphragm is easy to regulate, and obtained pores have a certain degree of curvature, so that when the porous diaphragm is applied to the lithium ion battery, micro short circuit and self-discharge phenomena can be effectively avoided, and meanwhile, higher electrolyte affinity and cycling stability are realized. A preparation method for the diaphragm is simple, environment-friendly, and easy to popularize; the porous diaphragm has a relatively good application prospect in the field of lithium ion batteries.

Description

technical field [0001] The invention relates to the application of a porous diaphragm in lithium ion batteries, in particular to the application of a heat-resistant porous diaphragm in lithium ion batteries. Background technique [0002] In recent years, as a high specific energy power source, lithium-ion batteries have been widely used in portable electronic devices, electric tools, electric vehicles, energy storage power stations and other fields. [0003] The separator in the lithium-ion battery mainly plays the role of blocking the positive and negative electrodes to prevent the short circuit of the battery, and conducting the lithium ions to form a battery circuit. Therefore, the diaphragm material is required to have good electrical insulation and maintain chemical stability in a wide temperature and voltage range. For a porous diaphragm material that can be used in practice, the following requirements must be met: suitable pore size, high porosity to ensure sufficien...

Claims

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Application Information

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IPC IPC(8): H01M2/16H01M2/18H01M50/403H01M50/463H01M50/491
CPCY02E60/10
Inventor 李先锋张华民段寅琦
Owner DALIAN INST OF CHEM PHYSICS CHINESE ACAD OF SCI
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