66results about How to "Increase electrophilicity" patented technology

The invention provides an organometallic iridium complex and a simple synthesis method and uses thereof, the method comprising: step (a): subjecting a t-Bu-Ar1-MgX and a nitrogen-containing heterocyclic aromatic salt to a nucleophilic reaction to obtain an intermediate product, wherein Ar1 is an arylene group having 5 to 16 carbon atoms or a sulfur-containing heteroarylene group having 4 to 14 carbon atoms; X is a halogen atom; the nitrogen-containing heterocyclic aromatic salt is a salt that contains a t-Bu-Ar2 group, and Ar2 is a nitrogen-containing heteroarylene group having 5 to 14 carbonatoms; t-Bu is a tertiary butyl group; step (b): subjecting the intermediate product and an oxidizing agent to an aromatic cyclization reaction to obtain a coordination compound; and step (c): reacting the coordination compound with iridium acetylacetonate to obtain an organometallic iridium complex. The organometallic iridium complex has a structure represented as formula (I).

The invention discloses an allopurinol impurity C and its preparation method, which belongs to the field of compound synthesis. The key point of the technical scheme is that S1: 3-aminopyrazole-4-formamide hemisulfate is dissolved in formamide, and 80wt% Hydrazine hydrate and 98wt% concentrated sulfuric acid are heated up to react; S2: After the reaction of S1 is completed, cool to room temperature, add sodium hydroxide solution to adjust the pH value of the solution to alkaline, add water and ethyl acetate, extract and separate the liquid, and collect the water phase; S3: Add n-butanol to the water phase in S2, extract and separate the liquids, collect the n-butanol phase, concentrate the n-butanol phase until solids are precipitated, filter with suction, and dry to obtain the product. The invention has mild reaction conditions, is easy to operate, has high product purity, can replace the official reference substance, and the obtained product has great significance for the quality research of allopurinol.

The invention discloses a method for modifying a grid-shaped lithium-ion battery diaphragm with high wettability, and belongs to the technical field of modification of the lithium-ion battery diaphragm. The key points of the technical scheme of the present invention are: soak the lithium-ion battery diaphragm in the mixed solution formed by nitric acid and potassium permanganate, seal it and place it in a constant temperature water bath at 20-60°C for 6-72h, and then use hydrogen peroxide or hydrochloric acid solution After cleaning, decompression and suction filtration, air dry naturally, trim the edges and vacuum dry at 30-60°C for 12-72 hours to obtain a highly wettable grid-shaped lithium-ion battery separator with a thickness of 25-32 μm and a porosity of 40%-70%. . The highly wettable lithium-ion battery diaphragm prepared by the invention has uniform pore size, good wettability and high ion conductivity, which improves the hydrophilicity and electrophilicity of the lithium-ion battery diaphragm, and also improves the charge-discharge capacity of the lithium-ion battery , the prepared highly wettable lithium-ion battery separator is resistant to electrolyte corrosion, has a simple process, strong stability and is easy for industrial application.

The invention provides a method for preparing a low-foaming cleaning agent, wherein the formula of the low-foaming cleaning agent is: anhydrous sodium metasilicate 1.6%-2.0%, polytricarboxylic acid ester 2%-4%, carboxylic acid amine Corrosion inhibitor 1%-3%, benzotriazole 1%-3%, polyacrylic acid 1%-3%, polyether modified silicone type defoamer 5%-8%, foam inhibitor 2%- 4%, water balance; wherein the preparation method of polyether modified silicone type defoamer is: prepare hydrogen-containing silicone oil; prepare mixed solution A; synthesis reaction; obtain viscous solid B which is polyether modified silicone Type defoamer. The object of the present invention is to provide a preparation method of a low-foam cleaning agent with low foam height and good cleaning effect.