Super-gravity type desulfurization and decarburization device integrating hydrate method and membrane method

A technology of supergravity and hydration, which is applied in the direction of gas fuel, separation methods, chemical instruments and methods, etc., can solve the problems of corroded pipelines and equipment, easy to cause environmental pollution, and difficult to obtain high purity, etc., to achieve high safety and reduce Initial investment cost, easy operation effect

Active Publication Date: 2016-03-09
CHANGZHOU UNIV
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Problems solved by technology

[0002] Natural gas extracted from oil and gas fields is mainly composed of hydrocarbons and a variety of impurity gases, the main component of which is methane, in addition to H 2 S, organic sulfur, CO 2 etc. The existence of these acidic substances will not only corrode pipelines and equipment, but also cause serious pollution to the environment. Therefore, the country has strict indicators for the content of acidic gases in commercial natural gas. With the introduction of the emission reduction concept, the country’s requirements in this regard are becoming more and more stringent. Efficient desulfurization and decarbonization of the exploited natural gas has become the key to rational utilization of natural gas resources; traditional oilfield natural gas desulfurization technologies mainly use chemical absorption and membrane Absorption method, chemical absorption method was proposed earlier to remove H in natural gas 2 S and CO 2 The literature (Peng Shujing, Ren Ailing. Research on recovery technology of carbon dioxide in flue gas chemical absorption method [D]. Hebei University of Science and Technology, 2007) describes in d

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  • Super-gravity type desulfurization and decarburization device integrating hydrate method and membrane method
  • Super-gravity type desulfurization and decarburization device integrating hydrate method and membrane method
  • Super-gravity type desulfurization and decarburization device integrating hydrate method and membrane method

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[0032] The specific implementation plan is as follows:

[0033] Under the set pressure, the natural gas vented from the oil field enters the stirred hydrate reactor 2 through the inlet channel 1 at a speed of 1.0~2.5m / s, and at the same time, the solution containing the kinetic promoter SDS is passed through the inlet 5 The annular liquid inlet pipe 4 enters the stirred hydrate reactor 2, where the concentration of SDS is controlled within the range of 300~500mg / L, 500mg / L is the best; the stirred hydrate reactor adopts external water-cooled jacketed cooling, That is, the water-cooled jacket 6 is placed in the cavity formed by the double-layer casing to achieve the cooling effect. The temperature of the stirred hydrate reactor is controlled at 0.5~4℃, and the pressure in the stirred hydrate reactor 2 is controlled at 1. Within the range of ~4MPa, after sufficient hydration reaction, H in natural gas 2 S and CO 2 When the acid gas is solidified in the hydrate, the formed hydrate i...

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Abstract

The invention belongs to the field of natural gas curing separation, and in particular relates to a device for desulfurizing and decarburizing industrial flue gases, oilfield exploitation gases and gases generated in other processes by combining a hydrate method with a membrane method and introducing a super-gravity technology. By combining the hydrate method with the membrane method and introducing the super-gravity technology based thereon to perform deep desulfurization and deacidification on natural gas, the removal rates of acid gases including H2S and CO2 in the natural gas are greatly improved, so that the device can be applied to purification and separation of onshore and marine oilfield natural gases, particularly the treatment of natural gases in remote districts and certain small gas fields; and the device can be used for removing the acid gases including H2S and CO2 in the natural gases effectively to ensure that the natural gases reach a pipeline transportation standard.

Description

technical field [0001] The invention belongs to the field of solidification and separation of natural gas, and here refers to a device for desulfurization and deacidification of gas in the process of industrial flue gas and oil field exploitation gas by combining the hydrate method with the membrane method and introducing the supergravity technology. The device can be used Purification and separation of natural gas in onshore and offshore oil and gas fields, especially for natural gas treatment in remote areas and some small gas fields, can efficiently remove H in natural gas 2 S and CO 2 Wait for the acid gas to make it meet the pipeline transportation standard. Background technique [0002] Natural gas extracted from oil and gas fields is mainly composed of hydrocarbons and a variety of impurity gases, the main component of which is methane, in addition to H 2 S, organic sulfur, CO 2 etc. The existence of these acidic substances will not only corrode pipelines and equip...

Claims

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Application Information

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IPC IPC(8): C10L3/10B01D53/14
CPCB01D53/1462B01D2252/10C10L3/103C10L3/104
Inventor 周诗岽张锦于雪薇李青岭刘珈铨王树立
Owner CHANGZHOU UNIV
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