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Preparation method of synthetic grease dispersed hafnium carbide boron carbide-carbon fiber friction material

A technology of hafnium carbide, boron carbide, and friction materials, which is applied in the field of friction material preparation, can solve problems such as safety hazards and friction performance reduction, and achieve the effect of improving wear resistance and high manufacturing costs

Inactive Publication Date: 2018-03-23
SHANDONG UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In addition, the friction performance of C / C composite materials will be reduced in a humid environment, which will bring serious safety hazards to the use.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0019] (1) Set the density to 1.8g / cm 3 The graphitized carbon fiber blanket is fed with a mixed gas of propane gas and nitrogen at a temperature of 900°C. The molar ratio of propane gas: nitrogen is 1:4, the flow rate is controlled at 50ml / min, and the carburizing treatment is performed for 24 hours to obtain a carburized carbon fiber blanket. ;

[0020] (2) Pass the above-mentioned carburized carbon fiber blanket into a mixed gas of boron trichloride, methane, hydrogen and argon at a temperature of 900 °C, and the molar ratio of boron trichloride: methane: hydrogen: argon is 1:1: 3:4, the flow rate is controlled at 50ml / min, and the deposited boron carbide is treated for 24 hours to obtain a deposited boron carbide carbon fiber blanket;

[0021] (3) Immerse the above-mentioned deposited boron carbide carbon fiber blanket into a synthetic slurry with a particle size of less than 0.3 μm and a content of 5% hafnium carbide, place it in an ultrasonic cleaner and fill it with ha...

Embodiment 2

[0025] (1) Set the density to 0.8g / cm 3 The graphitized carbon fiber blanket is fed with a mixture of propane gas and nitrogen at a temperature of 1000°C. The molar ratio of propane gas: nitrogen is 1:5, the flow rate is controlled at 350ml / min, and the carburizing treatment is performed for 18 hours to obtain a carburized carbon fiber blanket. ;

[0026] (2) Pass the above-mentioned carburized carbon fiber blanket into a mixed gas of boron trichloride, methane, hydrogen and argon at a temperature of 1000 °C, and the molar ratio of boron trichloride: methane: hydrogen: argon is 1:1.5: 4.5:5, the flow rate is controlled at 350ml / min, and the deposited boron carbide is treated for 18 hours to obtain a deposited boron carbide carbon fiber blanket;

[0027] (3) Immerse the above-mentioned deposited boron carbide carbon fiber blanket into a synthetic slurry with a particle size of less than 0.3 μm and a content of 12% hafnium carbide, place it in an ultrasonic cleaner and fill it ...

Embodiment 3

[0031] (1) Set the density to 0.1g / cm 3 The graphitized carbon fiber blanket is passed into a mixed gas of propane gas and nitrogen at a temperature of 1100 ° C. The molar ratio of propane gas: nitrogen is 1: 6, the flow rate is controlled at 600ml / min, and the carburizing treatment is performed for 10 hours to obtain a carburized carbon fiber blanket. ;

[0032] (2) Pass the above-mentioned carburized carbon fiber blanket into a mixed gas of boron trichloride, methane, hydrogen and argon at a temperature of 1100 °C, and the molar ratio of boron trichloride: methane: hydrogen: argon is 1:2: 6:6, the flow rate is controlled at 600 ml / min, and the deposited boron carbide is treated for 10 hours to obtain the deposited boron carbide carbon fiber blanket;

[0033] (3) Immerse the above-mentioned deposited boron carbide carbon fiber blanket into a synthetic slurry with a particle size of less than 0.3 μm and a content of 20% hafnium carbide, place it in an ultrasonic cleaner and f...

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Abstract

The invention relates to a preparation method of a synthetic fat dispersed hafnium carbide and boron carbide-carbon fiber friction material. The preparation method is characterized by comprising the steps of performing carburizing treatment on a graphitized carbon fiber blanket of which the density is 0.1 to 1.8g / cm<3>, performing boron carbide deposition treatment, synthetic fat dispersed hafnium carbide filling treatment, and buried siliconizing treatment, then performing nitrogen treatment under nitrogen atmosphere to obtain the synthetic fat dispersed hafnium carbide and boron carbide-carbon fiber friction material. According to the preparation method provided by the invention, the graphitized carbon fiber blanket is adopted to prepare the friction material through the steps such as carburization, boron carbide deposition, hafnium carbide filling, buried siliconizing, nitriding and the like, the prepared friction material is high in strength, toughness and friction performance, and is a friction material which is adapted to various climates.

Description

technical field [0001] The invention relates to a preparation method of a friction material composited by carbon fiber and ceramic material, and belongs to the technical field of composite material preparation. Background technique [0002] At present, carbon fiber and carbon (C / C) composite materials are mainly used as friction materials. Since the wear resistance of C / C composite materials is relatively low, people are looking for a method for preparing friction materials with higher wear resistance. In addition, the friction performance of C / C composite materials will be reduced in a humid environment, which will bring serious safety hazards to the use. Contents of the invention [0003] The object of the present invention is to provide a method for preparing a friction material that can overcome the above-mentioned defects, achieve higher strength, higher friction performance and adapt to various climatic conditions. Its technical solution is: [0004] The preparatio...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B35/80C04B35/563C04B35/56C04B35/584C04B35/632C04B35/65C04B35/622
CPCC04B35/5622C04B35/563C04B35/584C04B35/622C04B35/632C04B35/65C04B2235/46C04B2235/428
Inventor 唐竹兴
Owner SHANDONG UNIV OF TECH