Method for producing aluminum oxide through sintering sulfur-containing monohydrallite and lime

A technology of lime sintering and bauxite, which is applied in the direction of alumina/hydroxide, etc., can solve the problems of undisclosed sulfur element hazards, low alumina dissolution rate, and low concentration of dissolution liquid, and achieve low raw material cost and high sintering temperature. The effect of reducing and desulfurization process is simple

Active Publication Date: 2016-05-04
HEBEI UNIVERSITY OF SCIENCE AND TECHNOLOGY
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  • Abstract
  • Description
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  • Application Information

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Problems solved by technology

However, the main problems of this method are: the sintering temperature is very high, the energy consumption is high, the dissolution rate of alumina is relatively low, and the concentration of the dissolution solution is also low.
However, it does not disclose the solution to the hazards caused by sulfur in the sintering and alumina leaching processes of high-sulfur medium-low-grade bauxite

Method used

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  • Method for producing aluminum oxide through sintering sulfur-containing monohydrallite and lime

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0040] The mass percentage is: Al 2 o 3 55.5%, SiO 2 21.8%, Fe 2 o 3 7.5%, the rest is impurities, and the sulfur-containing low-grade bauxite is crushed and ground to a particle size of less than 200 mesh, accounting for more than 85%. Add limestone and desulfurization slag according to the calcium ratio C / A=1.0. The mass percentage of each element in limestone is: CaO50.9%, MgO1.2%, and the rest are impurities; the mass percentage of each element in desulfurization slag is: CaO42 .2%, SO 3 49.2%, of which the amount of desulfurization slag added is 9.0% of the total mass of sulfur-containing bauxite and limestone.

[0041] After the raw materials are mixed evenly according to the proportion, they are kept at 1300 degrees Celsius for 15 minutes, and then naturally cooled in the furnace. The clinker obtained by sintering was subjected to alumina dissolution, the dissolution temperature was 75°C, the time was 30 minutes, and the concentration of sodium carbonate solution ...

Embodiment 2

[0043] The mass percentage is: Al 2 o 3 36.3%, SiO 2 24.8%, Fe 2 o 3 12.4%, the rest is impurities, and the sulfur-containing low-grade bauxite is crushed and ground to a particle size of less than 200 mesh, accounting for more than 85%. Add limestone and desulfurization slag according to the calcium ratio C / A=0.8. The mass percentage of each element in limestone is: CaO52.1%, MgO1.0%, and the rest are impurities; the mass percentage of each element in desulfurization slag is: CaO43 .3%, SO 3 45.2%, of which the amount of desulfurization slag added is 3.5% of the total mass of sulfur-containing bauxite and limestone.

[0044] After mixing the raw materials evenly according to the proportion, keep the temperature at 1250 degrees Celsius for 30 minutes, and then cool naturally in the furnace. The clinker obtained by sintering was subjected to alumina dissolution, the dissolution temperature was 60°C, the time was 15 minutes, and the concentration of sodium carbonate soluti...

Embodiment 3

[0046] The mass percentage is: Al 2 o 3 41.1%, SiO 2 11.0%, Fe 2 o 3 10.3%, the rest is impurities, and the sulfur-containing low-grade bauxite is crushed and ground to a particle size of less than 200 mesh, accounting for more than 85%. Add limestone and desulfurization slag according to the calcium ratio C / A=0.95. The mass percentage of each element in limestone is: CaO54.6%, MgO0.7%, and the rest are impurities; the mass percentage of each element in desulfurization slag is: CaO44 .6%, SO 3 40.8%, of which the amount of desulfurization slag added is 6.8% of the total mass of sulfur-containing bauxite and limestone.

[0047] After the raw materials are mixed evenly according to the proportion, they are kept at 1150 degrees Celsius for 60 minutes, and then naturally cooled in the furnace. The clinker obtained by sintering was subjected to alumina dissolution, the dissolution temperature was 70°C, the time was 20 minutes, and the concentration of sodium carbonate solutio...

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Abstract

The invention relates to the technical field of aluminum oxide, and in particular relates to a method for producing aluminum oxide through sintering sulfur-containing monohydrallite and lime. According to the method, through properly adding a small amount of flue gas desulfurization slag and the lime into sulfur-containing monohydrallite for sintering, the aluminum oxide is produced, enabling aluminum element and sulphur element in a raw material to form a 4Cao.3Al2O3.SO3 phase, and by enabling silicon element to form a gamma-2CaO.SiO2 phase, and then adopting a low-temperature dissolution technology to perform aluminum oxide production, the deleterious effect of the sulphur element is reduced, the aluminum oxide dissolution performance of clinker is improved, and better market application value and social benefit are realized.

Description

technical field [0001] The invention relates to the technical field of alumina production, in particular to a process for producing alumina by a lime sintering method containing sulfur in raw materials such as low-grade bauxite or limestone. Background technique [0002] The rapid development of the alumina industry has caused a sharp decline in the grade of available bauxite resources, and the development of new available bauxite resources has become the focus of current research work. my country is rich in high-sulfur bauxite resources, with a sulfur content between 0.7% and 4%. The current proven reserves are 150 million tons, accounting for 11% of the total reserves of bauxite resources. Therefore, there is an urgent need for a sulfur-containing aluminum The comprehensive utilization method of soil ore. [0003] At present, there are two kinds of alumina production technologies for industrial application. One is the Bayer alumina production process. The Bayer process has...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01F7/02
CPCC01F7/02
Inventor 王波楚维钦荣朔郝圆亮孙会兰
Owner HEBEI UNIVERSITY OF SCIENCE AND TECHNOLOGY
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