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Preparation method of high-light transmittance and self-cleaning polycarbonate sheet

A polycarbonate, self-cleaning technology, applied in the field of materials, can solve problems such as difficult coating, affecting the light transmittance of the sheet, fluorine atom poisoning, etc., achieve good compatibility, improve self-cleaning, high light transmittance Effect

Active Publication Date: 2016-05-04
佛山市达孚新材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, PTFE is a fluorine-containing compound, which is difficult to degrade in the natural environment, and its potential fluorine atoms also have certain toxic effects on organisms, so its application in daily life is limited.
On the other hand, due to the poor transparency of polytetrafluoroethylene, if polytetrafluoroethylene is coated on the surface of polycarbonate substrate, it will inevitably affect the light transmittance of the whole sheet, thereby affecting its use effect; , due to the poor compatibility of polytetrafluoroethylene and polycarbonate, it is difficult to effectively coat polytetrafluoroethylene on polycarbonate resin substrates, which affects the service life of the material

Method used

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  • Preparation method of high-light transmittance and self-cleaning polycarbonate sheet

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Embodiment 1

[0019] A high-transmittance self-cleaning polycarbonate sheet, made of a polycarbonate substrate and a self-cleaning film, the surface of the self-cleaning film has a micro-nano structure, prepared by coating the self-cleaning film on the polycarbonate substrate A highly light-transmitting self-cleaning polycarbonate sheet is obtained, wherein the polycarbonate substrate is a pure polycarbonate sheet with a thickness of 0.5 cm or 1 cm or 2 cm.

[0020] The preparation method of the highly light-transmitting self-cleaning polycarbonate sheet comprises the following steps:

[0021] Polycarbonate (molecular weight of 80,000-20,000) with a mass ratio of 2:1 or 3.5:1 or 5:1 and hydrophobic nano-silica (particle size of 20-40nm, the mass ratio is 3:1) Hydrophilic fumed silica and hexamethyldisilazane are prepared by alkylation reaction) into tetrahydrofuran (the mass ratio of tetrahydrofuran to polycarbonate is 1:2), ultrasonically or stirred for 30 minutes to form a mixed solution...

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Abstract

The invention belongs to the technical field of materials, and particularly discloses a high-light transmittance and self-cleaning polycarbonate sheet and a preparation method. The polycarbonate sheet is composed of a polycarbonate base material and a self-cleaning film, a micro-nano structure is formed on the surface of the self-cleaning film, and the polycarbonate base material is coated with the self-cleaning film, so that it is guaranteed that the sheet has good self-cleaning performance. The self-cleaning film is mainly prepared from polycarbonate and hydrophobic nano silica, polycarbonate and hydrophobic nano silica are dissolved in a tetrahydrofuran solution, sufficient ultrasonic dispersion or stirring dispersion is performed, and an uniform mixed solution is formed; then the polycarbonate base material is coated with the mixed solution, then the polycarbonate base material is placed into 50 DEG C oven, and the high-light transmittance and self-cleaning polycarbonate sheet is obtained after tetrahydrofuran is fully dried. The sheet has high light transmittance and also has good self-cleaning performance. The sheet does not contain fluoride, free of additives, non-toxic and high in light transmittance, has the self-cleaning performance and can be widely used in the fields of exterior wall decoration glass, safety glasses, instrument panels, lamp outer covers and the like.

Description

technical field [0001] The invention relates to the field of material technology, in particular to a method for preparing a highly light-transmitting self-cleaning polycarbonate sheet. Background technique [0002] Polycarbonate (PC) is one of the five widely used engineering plastics. It has comprehensive and balanced mechanical, electrical and heat resistance properties, especially known for its excellent impact strength and creep resistance, high light transmittance, and good mechanical properties. Especially impact toughness is the best among engineering plastics. [0003] Due to the excellent performance of PC, its products and blended materials have been widely used in electronics, electrical appliances, machinery, automobiles, textiles, light industry and construction industries; especially in glass and decorative materials, they have been widely used in recent years. promotion and application. However, polycarbonate products will be polluted by the air environment ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08J7/04C08L69/00C09D169/00C09D7/12C09D5/16
CPCC08J7/0427C08J2369/00C08J2469/00C08K3/36C08K9/06C08K2201/011C09D5/1618C09D7/62C09D169/00
Inventor 杜军戴洪湖汪连生王锋丁瑜郭连贵覃彩芹
Owner 佛山市达孚新材料有限公司
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