A kind of CO2 enrichment and conversion equipment and method in a confined space
A closed space, CO2 technology, applied in the field of aerospace catalysis, can solve the problems of large resistance drop in microchannel reactors, and achieve the effects of reducing weight, avoiding side reactions, and saving space and volume
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Embodiment 1
[0058] Use MDEA as absorbent to enrich CO through continuous or intermittent operation 2 , And then desorb; by adjusting H 2 Flow control of hydrogen and CO 2 The molar ratio is 3.5:1. Packing NiO-Al in the methanation reactor 2 O 3 Co-precipitation methanation catalyst, catalyst light-off temperature 240 ℃. The reaction pressure is 1.7atm. The raw material gas is preheated and preheated twice in the reactor, and the inlet temperature of the catalyst I is higher than 240℃; the methanation reaction in the reaction bed generates heat and the heat is removed in time. When the feed gas is preheated, the outlet temperature of the catalyst I bed is 500°C; it is cooled to about 240°C through an air-cooled heat exchanger, and then enters the catalyst II to continue the methanation reaction. The temperature of the second stage methanation bed (catalyst II) of the reactor is at At about 330°C, it exchanges heat with hydrogen and further cools the temperature. The methanation reactor outl...
Embodiment 2
[0060] Use ionic liquid as absorbent to enrich CO through continuous or intermittent operation 2 , And then desorb; by adjusting H 2 Flow control of hydrogen and CO 2 The molar ratio is 3.5:1. Fill the methanation reactor with Ru / Ce made by immersion method 0.8 Zr 0.2 O 2 The catalyst, the catalyst light-off temperature is 120°C. The reaction pressure is 1.7atm, the raw material gas is preheated and preheated twice in the reactor, the inlet temperature of the catalyst I is higher than the light-off temperature; the methanation reaction in the reaction bed releases heat, and the heat is removed in time It is used to preheat the raw material gas. The outlet temperature of the catalyst I bed is 450°C; it is cooled to about 160°C through an air-cooled heat exchanger and enters the catalyst II to continue the methanation reaction. The temperature of the second stage methanation bed (catalyst II) of the reactor At about 260°C, it exchanges heat with hydrogen to cool the temperature f...
Embodiment 3
[0062] Use alcohol ethers as absorbents to enrich CO through continuous or intermittent operation 2 , And then desorb; by adjusting H 2 Flow control of hydrogen and CO 2 The molar ratio is 3:1. Loading Co in the methanation reactor 3 O 4 -Al 2 O 3 Co-precipitation methanation catalyst, catalyst ignition temperature 300 ℃. The reaction pressure is 6atm. The raw material gas is preheated and preheated twice in the reactor. The inlet temperature of the catalyst I is higher than 300℃; the methanation reaction in the reaction bed generates heat, and the heat is removed in time. Preheat the raw material gas, the outlet temperature of the catalyst I bed is 650℃; it is cooled to about 300℃ through the air-cooled heat exchanger, and then enters the catalyst II to continue the methanation reaction. The temperature of the second stage methanation bed (catalyst II) of the reactor is 350 ℃ or so, and then exchange heat with hydrogen to further cool the temperature, the methanation reactor o...
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