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Method and system for preparing liquefied natural gas from coal-to-oil purified synthesis gas

A technology for liquefied natural gas and synthesis gas, which is applied in the petroleum industry, gas fuel, fuel, etc., can solve the problems of low conversion rate of synthesis unit, increase of cold box unit equipment, increase of compressor load, etc., and achieve small rectification tail gas volume , the number of equipment is small, the effect of small pressure drop loss

Active Publication Date: 2016-05-11
SYNEFUELS CHINA
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Problems solved by technology

If you do not put CH in Aiki 4 Extraction will cause the conversion rate of the synthesis unit to be too low, while the CH 4 Cycling through the system increases the load on the compressor
The traditional direct cryogenic method is to pass all the purified syngas through the cold box unit. This method increases the equipment of the cold box unit, consumes more cooling capacity of the cold box, and loses the synthesized H at the same time. 2 and CO effective gas, a large amount of nitrogen stripping is also required

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  • Method and system for preparing liquefied natural gas from coal-to-oil purified synthesis gas

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Embodiment 1

[0042] Example 1. Coal-to-oil purification of synthetic gas to produce liquefied natural gas

[0043] (1) A system for producing liquefied natural gas by purifying synthetic gas from coal to oil

[0044] Such as figure 1 As shown, the system for producing liquefied natural gas from coal-to-oil purification synthesis gas of the present invention includes a methane separation and extraction device 101 (vacuum pressure swing adsorption device, the adsorbent is carbon molecular sieve) for separating and extracting methane in coal-to-oil purification synthesis gas ), a methane-rich gas compression device 102 for compressing methane-rich gas, a methane-rich gas pretreatment device 103 (using a temperature swing adsorption device, and the adsorbents are respectively B-type silica gel with a mass ratio of 85wt% and 4A molecular sieves with a mass ratio of 15wt%), Cold box 104 for cooling and rectifying methane-rich gas, liquefied natural gas storage device 105, liquefied natural gas ...

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Abstract

The invention discloses a method and system for preparing liquefied natural gas from coal-to-oil purified synthesis gas. The method comprises the following steps that 1, methane in purified synthesis gas in the coal-to-oil technology is separated and extracted, and methane-rich gas is obtained; 2, the methane-rich gas obtained in the first step is compressed to remove impurities; 3, the methane-rich gas treated in the second step is cooled and rectified, and the liquefied natural gas and rectified tail gas are obtained. According to the method and system preparing the liquefied natural gas from the coal-to-oil purified synthesis gas, CH4 in the purified synthesis gas in the coal-to-oil technology is removed before the purified synthesis gas enters a synthesis unit, the content of inert gas is decreased, the partial pressure of H2 and CO is increased, and the yield of the synthesis process is improved; meanwhile, the power consumption of a recycle compressor of a subsequent synthesis system is reduced. Compared with a traditional method for enabling all gases to enter a cooling box, the gas entering the cooling box unit in the preparation method is less than 30% of that in the traditional method, the equipment dimension of the cooling box is greatly decreased, and the energy loss of the cooling box is greatly reduced; the pressure drop loss of the synthesis gas is small, the quantity of the rectified tail gas in the cooling box is small, and the compression work consumed during recycling is small.

Description

technical field [0001] The invention relates to a method and system for preparing liquefied natural gas from coal-to-oil purification synthesis gas. Background technique [0002] my country is relatively rich in coal resources and is one of the few countries in the world that uses coal as its main energy source. "Short of oil, less gas, rich in coal" (96% of coal, 4% of oil + gas) is the basic national condition of our country, and coal resources are important energy resources that our country can rely on in the medium and long-term development. At present, my country's oil demand is increasingly dependent on imports. By the end of 2014, China's oil dependence on foreign countries was close to 60%. Oil shortage has become the main structural contradiction in my country's energy supply and demand and the "bottleneck" restricting the rapid development of the national economy. . Unstable factors in the relationship between supply and demand in the international oil market, pol...

Claims

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Application Information

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IPC IPC(8): C10L3/08
CPCC10L3/08
Inventor 陈林峰董根全史建中刘利军陈倩曹峰李永旺曹立仁
Owner SYNEFUELS CHINA