Modified polylactic acid compound 3D printing material with wood property, as well as preparation method and application thereof

A 3D printing and polylactic acid technology, which is applied in the field of modified polylactic acid composite 3D printing materials and preparation, can solve the problems of no antibacterial, antifouling and self-cleaning functions, adverse effects on human health, enrichment of pollutants, etc., and achieve improvement of expansion plugging The phenomenon of scratches, the improvement of material strength, and the effect of good antibacterial ability

Active Publication Date: 2016-05-18
GUANGZHOU FEISHENG HIGH POLYMER MATERIAL CO LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] During the storage, transportation and use of wood-plastic furniture printed by 3D printing technology, due to the influence of humidity, harmful particles and gases in the surrounding environment and air, it is easy to breed bacteria and accumulate pollutants on the surface, which will have a negative impact on the environment. Human health is adversely affected, so compared with the patent application CN201310345147, the self-cleaning and antibacterial ability of the wood-plastic material is increased. At present, the popular wood-plastic 3D printing products and their raw materials on the market do not have antibacterial, antifouling and self-cleaning functions

Method used

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  • Modified polylactic acid compound 3D printing material with wood property, as well as preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0053] (1) Formula dosage (parts by mass): 70 parts of polylactic acid PLA (molecular weight: 70,000), 20.5 parts of natural sandalwood powder, 3 parts of silane coupling agent (KH570), 5 parts of thermoplastic elastomer (SEBS), nano antibacterial agent (nano titanium dioxide) 1.5 parts.

[0054] (2) Preparation process:

[0055] ① Put the PLA into the dryer and bake at 100°C for 3 hours to completely evaporate the water;

[0056] ②Then put the natural sandalwood powder into a sodium hydroxide solution with a concentration of 10% by mass for alkali treatment: soak the wood powder in a sodium hydroxide solution (10%), with a mass ratio of 1:15, and stir at room temperature After 24 hours, let stand to pour off the upper layer of lye, add distilled water to wash, filter with filter cloth, repeat several times until the filtrate is neutral, then dry to constant weight and use it as one of the raw materials for later use;

[0057] ③ Put each raw material into the mixer according...

Embodiment 2

[0059] (1) Formula dosage (parts by mass): 90 parts of polylactic acid PLA (molecular weight 70,000), 7.5 parts of environmentally friendly natural miscellaneous wood fiber powder (about 400 mesh), 1 part of silane coupling agent (KH590), thermoplastic elastomer (SEBS ) 1 part, 0.5 part of nano antibacterial agent (nano-titanium dioxide).

[0060] (2) Preparation process:

[0061] ① Put the PLA into the dryer and bake at 100°C for 3 hours to completely evaporate the water;

[0062] ②Then put the environment-friendly natural miscellaneous wood fiber powder into a sodium hydroxide solution with a concentration of 10% by mass for alkali treatment: soak the wood powder in a sodium hydroxide solution (10%), with a mass ratio of 1:15, at room temperature Stir for 24 hours, let stand and pour off the upper layer of lye, add distilled water to wash, filter with filter cloth, repeat several times until the filtrate is neutral, then dry to constant weight and use it as one of the raw m...

Embodiment 3

[0065] (1) Formula dosage (parts by mass): 80 parts of polylactic acid PLA (70,000 molecular weight), 15 parts of mahogany wood powder (about 300 mesh), 1.5 parts of silane coupling agent (KH550), 2.5 parts of thermoplastic elastomer (SEBS) , 1 part of nano antibacterial agent (nano titanium dioxide).

[0066] (2) Preparation process:

[0067] ① Put the PLA into the dryer and bake at 100°C for 3 hours to completely evaporate the water;

[0068] ②Then put the natural eucalyptus powder into a sodium hydroxide solution with a concentration of 10% by mass for alkali treatment: soak the wood powder in a sodium hydroxide solution (10%), with a mass ratio of 1:15, and stir at room temperature for 24 Hours, stand and pour off the upper layer of lye, add distilled water to wash, filter with filter cloth, repeat for many times until the filtrate is neutral, and then dry to constant weight as one of the raw materials for subsequent use;

[0069] ③Put each raw material into the mixer ac...

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Abstract

The invention discloses a modified polylactic acid compound 3D printing material with wood property, as well as a preparation method and application thereof. The printing material is prepared from the following components in parts by mass: 70-90 parts of a polylactic acid raw material, 7.5-20.5 parts of alkali-treated wood powdered particles, 1-3 parts of a silane coupling agent, 1-5 parts of a thermoplastic elastomer and 0.5-1.5 parts of a nano-antibacterial agent. The preparation method comprises the following steps: mixing the raw materials; cooling and molding the melt extruded by a single-screw plastic extruder; and drying, drawing and winding to obtain the printing material. The printing material has excellent toughness and mechanical performance, has texture, color and smell of woods, and can be used for improving the phenomenon that the end cap is easily blocked by wood powder and expanding the optional varieties of wood powder, so that the printing material can be used for printing wood-like furniture products; and the self-cleaning antibacterial capability of wood-plastic materials is increased, and the environmental-friendliness performance of furniture products printed by the materials can be greatly improved.

Description

technical field [0001] The invention belongs to the field of polymer composite materials, and in particular relates to a modified polylactic acid composite 3D printing material with woody properties, its preparation method and application. Background technique [0002] The 3D printing industry is developing more and more rapidly. With the popularization of 3D printers, consumers' demand for 3D printed patterns is getting higher and higher. In addition to plastic 3D printing consumables, 3D printing materials based on metals, ceramics, food and even human cells have appeared (Yu Dongmei, 2014). Recently, German inventor KaiParthy invented a 3D printing consumable called LAYWOO-D3, which contains a certain amount of recycled wood and harmless polymers. 3D printing between ℃. The works printed with LAYWOO-D3 materials not only look like wood, but also smell like wood. The biggest feature is that it can print different colors at different temperatures. Moreover, the printed p...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L67/04C08L97/02C08L53/02C08K3/22B29C47/92B29C48/92
CPCB29C48/05B29C48/92B29C2948/9259B29C2948/92704B29C2948/92895C08K2201/011C08L67/04C08L2205/03C08L2207/04C08L97/02C08L53/025C08K2003/2241
Inventor 屈阳谷文亮周武艺聂健良董先明
Owner GUANGZHOU FEISHENG HIGH POLYMER MATERIAL CO LTD
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