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A kind of agricultural tire sidewall rubber filled with tire reclaimed rubber

A technology of reclaimed rubber and sidewall rubber, applied in the field of tire manufacturing, can solve the problems of poor wetting ability of compounding agents, narrow relative molecular chain distribution, large expansion rate of semi-finished products, etc. slow effect

Active Publication Date: 2017-10-17
徐州汉邦橡胶有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] A phenyl group is introduced into the side group of the SBR molecular main chain of styrene-butadiene rubber, and a vinyl side group is formed in the 1,2-structure of butadiene, which has large steric hindrance, poor molecular chain flexibility, narrow relative molecular chain distribution, and lack of low molecular weight. Level of plasticization, so poor processability
The specific manifestations are poor wettability to the compounding agent during mixing, rapid temperature rise, and large equipment load; large shrinkage of the rubber during calendering; difficult operation during extrusion, large expansion rate of semi-finished products; poor self-adhesiveness during molding
Agricultural tires use a large amount of tread. If the rubber material heats up quickly and the mixing time is long, not only the rubber material is easy to scorch, but also the power of the equipment is large and many other problems.

Method used

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  • A kind of agricultural tire sidewall rubber filled with tire reclaimed rubber
  • A kind of agricultural tire sidewall rubber filled with tire reclaimed rubber
  • A kind of agricultural tire sidewall rubber filled with tire reclaimed rubber

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0017] An agricultural tire sidewall rubber filled with tire reclaimed rubber, which includes the following raw materials and their parts by mass:

[0018] 20# standard rubber, 20 parts; butadiene rubber 9000, 20 parts; styrene-butadiene rubber 1502, 30 parts; tire reclaimed rubber (TRR), 30 parts; zinc oxide, 4.0 parts; stearic acid, 3.0 parts; antioxidant 4020 , 2.0 parts; antioxidant RD, 1.0 parts; protective wax, 2.5 parts; high wear-resistant carbon black N330, 25 parts; general carbon black, 35 parts; aromatic oil, 4.0 parts; pine tar, 3.0 parts; Coumarone, 3.0 parts; sulfur, 1.6 parts; accelerator NOBS, 0.8 parts; uniform dispersant MS, 0.8 parts.

[0019] The sum of the mass parts of styrene-butadiene rubber 1502 and tire reclaimed rubber is 60 parts.

[0020] The sum of the mass parts of 20# standard rubber and butadiene rubber 9000 is 40 parts.

[0021] Preparation method: Adopt one-stage mixing method: first mix NR, BR, SBR, TRR normally, then add 35 parts of gene...

Embodiment 2

[0024] An agricultural tire sidewall rubber filled with tire reclaimed rubber, which includes the following raw materials and their parts by mass:

[0025] 20# standard rubber, 20 parts; butadiene rubber 9000, 20 parts; styrene-butadiene rubber 1502, 20 parts; tire reclaimed rubber (TRR), 40 parts; zinc oxide, 4.0 parts; stearic acid, 3.0 parts; antioxidant 4020 , 2.0 parts; antioxidant RD, 1.0 parts; protective wax, 2.5 parts; high wear-resistant carbon black N330, 25 parts; general carbon black, 35 parts; aromatic oil, 4.0 parts; pine tar, 3.0 parts; Coumarone, 3.0 parts; sulfur, 1.6 parts; accelerator NOBS, 0.8 parts; uniform dispersant MS, 0.8 parts.

[0026] The sum of the mass parts of styrene-butadiene rubber 1502 and tire reclaimed rubber is 60 parts.

[0027] The sum of the mass parts of 20# standard rubber and butadiene rubber 9000 is 40 parts.

[0028] Its preparation method is with embodiment 1.

[0029] The vulcanization characteristics of the agricultural tire...

Embodiment 3

[0031] An agricultural tire sidewall rubber filled with tire reclaimed rubber, which includes the following raw materials and their parts by mass:

[0032] 20# standard rubber, 20 parts; butadiene rubber 9000, 20 parts; styrene-butadiene rubber 1502, 10 parts; tire reclaimed rubber (TRR), 50 parts; zinc oxide, 4.0 parts; stearic acid, 3.0 parts; antioxidant 4020 , 2.0 parts; antioxidant RD, 1.0 parts; protective wax, 2.5 parts; high wear-resistant carbon black N330, 25 parts; general carbon black, 35 parts; aromatic oil, 4.0 parts; pine tar, 3.0 parts; Coumarone, 3.0 parts; sulfur, 1.6 parts; accelerator NOBS, 0.8 parts; uniform dispersant MS, 0.8 parts.

[0033] The sum of the mass parts of styrene-butadiene rubber 1502 and tire reclaimed rubber is 60 parts.

[0034] The sum of the mass parts of 20# standard rubber and butadiene rubber 9000 is 40 parts.

[0035] Its preparation method is with embodiment 1.

[0036] The vulcanization characteristics of the agricultural tire...

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Abstract

The invention discloses high-filling agricultural tire sidewall rubber containing TRR (tire reclaimed rubber). The high-filling agricultural tire sidewall rubber comprises raw materials in parts by mass as follows: 15-25 parts of 20# standard rubber, 15-25 parts of cis-butadiene rubber 9000, 10-30 parts of butadiene-styrene rubber 1502, 30-50 parts of TRR, 3.0-5.0 parts of zinc oxide, 2.0-4.0 parts of stearic acid, 1.5-2.5 parts of an anti-ageing agent 4020, 0.8-1.2 parts of an anti-ageing agent RD, 2.0-3.0 parts of protective wax, 20-30 parts of high-wear-resistant carbon black N330, 30-40 parts of universal carbon black, 3.5-4.5 parts of aromatic hydrocarbon oil, 2.5-3.5 parts of pine tar, 2.5-3.5 parts of coumarone, 1.4-1.8 parts of sulfur, 0.6-1.0 parts of an accelerator NOBS and 0.6-1.0 parts of a uniform dispersing agent MS. The cost of the prepared sidewall rubber is low, and no crack is formed and a specimen is intact after 90,000 times of yielding.

Description

technical field [0001] The invention relates to an agricultural tire side rubber highly filled with tire reclaimed rubber, which belongs to the field of tire manufacturing. Background technique [0002] China is not only a big importer of rubber, but also a big producer of waste rubber. The total amount of scrap tires is very large every year. The disposal of scrap tires has become a recognized international problem, and China is no exception. As a good way of waste utilization, recycled rubber is one of the effective ways to solve the problem of tire recycling in China. After process processing, tire reclaimed rubber is produced and put into the production of new products, so that rubber resources can be fully and reasonably recycled, which is a good way to deal with resources and the environment. [0003] A phenyl group is introduced into the side group of the SBR molecular main chain of styrene-butadiene rubber, and a vinyl side group is formed in the 1,2-structure of b...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L9/06C08L17/00C08L9/00C08L7/00C08K13/02C08K3/22C08K5/09C08K3/04C08K3/06
CPCC08K2201/014C08L9/06C08L17/00C08L2205/02C08L2205/035C08L2207/24C08L9/00C08L7/00C08K13/02C08K2003/2296C08K5/09C08K3/04C08K3/06
Inventor 徐云慧王艳秋孙鹏宋帅帅
Owner 徐州汉邦橡胶有限公司
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