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Fluorine-containing fabric waterproof agent and preparation method thereof

A technology of fluorine-containing fabrics and water repellents, applied in the directions of plant fibers, textiles and papermaking, fiber types, etc., can solve problems such as unsatisfactory oil-repellent performance, reduce pilling and static electricity, reduce friction, and good scratch resistance. performance effect

Active Publication Date: 2016-07-20
GUANGZHOU HENGJIN CHEM TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0006] The patents CN1942541B, CN1305993C, CN101006149A and CN1878846B of Daikin Industry Co., Ltd. respectively reported that polyfluoroalkyl groups or polyfluoroalkenyl groups with 1-6 carbon atoms were polymerized monomers to prepare waterproof and oil-proof products with excellent stability. Composition, although the obtained composition has good water repellency, oil repellency is not ideal enough

Method used

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  • Fluorine-containing fabric waterproof agent and preparation method thereof
  • Fluorine-containing fabric waterproof agent and preparation method thereof
  • Fluorine-containing fabric waterproof agent and preparation method thereof

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preparation example Construction

[0046] The preparation method of the above-mentioned fluorine-containing fabric waterproofing agent specifically comprises the following steps:

[0047] Step 1, take the following raw materials respectively by mass percentage:

[0048] Perfluoroalkyl ethyl acrylate 6% to 14%, acrylic resin 9% to 17%, octamethyltetrasiloxane 9% to 13%, carboxymethyl cellulose 1% to 5%, polyvinyl alcohol 5 %~13%, cross-linking monomer 1%~9%, surfactant 0.2%~0.5%, initiator 0.5%~0.9%, deionized water 60%~70%;

[0049] The total content of the above raw materials is 100%;

[0050] Among the above raw materials:

[0051] Acrylic resin adopts methyl methacrylate or octadecyl methacrylate;

[0052] N, N-methylenebisacrylamide is used as the crosslinking agent;

[0053] The surfactant adopts reactive allyloxy nonylphenol polyoxyethylene (10) ether ammonium sulfate;

[0054] The initiator adopts potassium persulfate;

[0055] Step 2, mixing the surfactant weighed in step 1 with deionized water, s...

Embodiment 1

[0062] Weigh the following raw materials according to mass percentage: 7.5% perfluoroalkyl ethyl acrylate, 10.5% methyl methacrylate, 10.5% octamethyltetrasiloxane, 1% carboxymethyl cellulose, 5.5% polyvinyl alcohol %, N, N-methylenebisacrylamide 1%, allyloxy nonylphenol polyoxyethylene (10) ether ammonium sulfate 0.2%, potassium persulfate 0.8%, deionized water 63%.

[0063] The sum of the contents of the above raw materials is 100%.

[0064] Mixing the weighed surfactant and deionized water, so that the surfactant is completely dissolved in the deionized water, to obtain an aqueous surfactant solution;

[0065] Add the weighed perfluoroalkyl ethyl acrylate, acrylic resin, octamethyltetrasiloxane, carboxymethyl cellulose and cross-linking monomer into the aqueous surfactant solution, and stir to obtain a mixed solution; Mechanical stirring is used during the stirring process, and the stirring time is 25 minutes;

[0066] Add the weighed polyvinyl alcohol and initiator to th...

Embodiment 2

[0068] Weigh the following raw materials according to mass percentage: 6% perfluoroalkyl ethyl acrylate, 12% methyl methacrylate, 12% octamethyltetrasiloxane, 1% carboxymethyl cellulose, 7% polyvinyl alcohol %, N, N-methylenebisacrylamide 1%, allyloxy nonylphenol polyoxyethylene (10) ether ammonium sulfate 0.3%, potassium persulfate 0.7%, deionized water 60%.

[0069] The sum of the contents of the above raw materials is 100%.

[0070] Mixing the weighed surfactant and deionized water, so that the surfactant is completely dissolved in the deionized water, to obtain an aqueous surfactant solution;

[0071] Add the weighed perfluoroalkyl ethyl acrylate, acrylic resin, octamethyltetrasiloxane, carboxymethyl cellulose and cross-linking monomer into the aqueous surfactant solution, and stir to obtain a mixed solution; Mechanical stirring was used during the stirring process, and the stirring time was 28 minutes;

[0072] Add the weighed polyvinyl alcohol and initiator to the mixe...

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Abstract

The invention discloses a fluorine-containing fabric waterproof agent. The fluorine-containing fabric waterproof agent is composed of, by mass, 6-14% of perfluoroalkylethyl acrylate, 9-17% of acrylic resin, 9-13% of octamethyl tetrasiloxane, 1-5% of carboxymethylcellulose, 5-13% of polyvinyl alcohol, 1-9% of cross-linked monomer, 0.2-0.5% of surfactant, 0.5-0.9% of initiator and 60-70% of deionized water. The invention further discloses a preparation method of the fluorine-containing fabric waterproof agent. The preparation method includes: mixing the surfactant with the deionized water to obtain obtain a surfactant water solution; adding perfluoroalkylethyl acrylate, the acrylic resin, octamethyl tetrasiloxane, carboxymethylcellulose and the cross-linked monomer into the surfactant water solution to form mixed liquid; mixing polyvinyl alcohol and the initiator with the mixed liquid, and filtering to obtain the waterproof agent. The fluorine-containing fabric waterproof agent is capable of making fabric soft, durable, waterproof and oil-proof.

Description

technical field [0001] The invention relates to a fluorine-containing fabric waterproofing agent, and also relates to a preparation method of the above-mentioned fluorine-containing fabric waterproofing agent. Background technique [0002] Usually, in the process of chemical fiber weaving and pretreatment, many factors may cause the fabric to feel rough. At this time, it is often necessary to add a softener to give the fabric a soft feel. [0003] Softener is a daily chemical product that can give clothes and fabrics a soft and pleasant feeling in hand, wearing and use. After the softener is adsorbed on the surface of the fiber, it can prevent the direct contact between the fiber and the fiber, reduce the dynamic friction coefficient and the static friction coefficient between the fiber and the fiber, so as to achieve the effect of soft, smooth and comfortable to wear. [0004] However, most of the existing softeners have the problems of high cost, single performance and po...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08F220/14C08F220/24C08F222/38D06M15/277D06M13/513D06M15/09D06M15/333D06M15/53D06M101/06D06M101/32D06M101/34
CPCC08F220/14C08F220/24D06M13/513D06M15/09D06M15/277D06M15/333D06M15/53D06M2101/06D06M2101/32D06M2101/34C08F222/38
Inventor 魏鹏勃崔艳娇施潘光魏新刚王龙昌
Owner GUANGZHOU HENGJIN CHEM TECH CO LTD
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