Method for enhancing interfacial properties of SMA (styrene maleic anhydride) reinforced resin intelligent composite materials

A technology for strengthening resin-based and composite materials, which is applied in the field of improving the interface performance of SMA-reinforced resin-based intelligent composite materials, and can solve problems such as fiber material damage, SMA wire surface nano-particle shedding, and dynamic performance degradation, so as to achieve not easy to fall off, improve Industrial production process, the effect of improving interface performance

Inactive Publication Date: 2016-08-24
HARBIN ENG UNIV
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Problems solved by technology

However, the test shows that the acid-base treatment and other methods to prepare the specimen through mechanical experiments found that although the static properties have increased, the dynamic properties have decreased, which is due to the damage caused by these modification methods to the fiber material itself. Although the method of surface coating nanoparticles can effectively enhance its interface properties, problems such as shedding of nanoparticles on the surface of SMA wires are often encountered during the experiment.

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  • Method for enhancing interfacial properties of SMA (styrene maleic anhydride) reinforced resin intelligent composite materials
  • Method for enhancing interfacial properties of SMA (styrene maleic anhydride) reinforced resin intelligent composite materials

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Embodiment Construction

[0019] The present invention will be described in more detail below with examples in conjunction with the accompanying drawings.

[0020] combine figure 1 , cut the SMA wire 1 into the required length, put it into the cleaning tank and wash it with clean water, and then put it into the industrial chemical reaction tank 3 filled with the concentrated nitric acid solution 2. This process should ensure that the nitric acid solution will completely clean the SMA wire. Submerged; the soaking time is 8h, the SMA wire is taken out, and rinsed with clear water 5 in the flow washing pool 4; 2 The particles are put into the isopropanone solution 6, and the mixed solution is stirred by a vacuum hydraulic lift mixer 7, the stirring time is set to 3h, and the stirring speed is set to 100r / min. This process is dispersed in the ultrasonic disperser 8; Deposition (PVD) method will nano-SiO 2 Particles covered on the surface of SMA: put the nitric acid-treated SMA wire into the nano-SiO 2 I...

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Abstract

The invention provides a method for enhancing interfacial properties of SMA (styrene maleic anhydride) reinforced resin intelligent composite materials. The method includes steps of firstly, washing SMA fibers by the aid of clear water; secondly, completely submerging the SMA fibers in concentrated nitric acid solution for the soaking time of 8-10 h, fetching the SMA fibers out of the concentrated nitric acid solution and thoroughly washing the SMA fibers by the aid of flowing water; thirdly, arranging nanometer SiO2 particles in isopropyl alcohol solution and stirring the nanometer SiO2 particles and the isopropyl alcohol solution to obtain mixed solution with nanometer SiO2; fourthly, covering the surfaces of SMA with the nanometer SiO2 particles by the aid of physical vapor deposition processes. The weight of the nanometer SiO2 particles accounts for 2% of the weight of the isopropyl alcohol solution. The method has the advantage that problems of easiness in falling of nanometer SiO2 particles on the surfaces of modified shape memory alloy fibers of existing industrial technological production methods and poor interfacial adhesive properties of resin composite materials with SMA used as reinforcement phases can be solved by the aid of the method.

Description

technical field [0001] The invention relates to a processing method for SMA smart materials, in particular to a method for improving the interface performance of SMA-reinforced resin-based smart composite materials. Background technique [0002] In recent years, shape memory alloy (SMA) has been used as a reinforced phase-reinforced resin-based composite material in industrial production, and related products have been mass-produced. However, the results of mass production show that the resin matrix composites using SMA as the reinforcing phase have the problem of poor interface bonding performance, and the SMA fiber reinforced resin matrix composites often fail to reach the ultimate strength of the material during the application process and delamination occurs at the interface. Viscous failure leads to the destruction of the macrostructure of the material. Since the interface strength between SMA and resin matrix plays a key role in the load transfer of fiber-reinforced r...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08K9/02C08K7/06
CPCC08K9/02C08K7/06
Inventor 佟丽莉张永超杨斌王丽君吕晨范亚博孙学良
Owner HARBIN ENG UNIV
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