Liquid self-cleaning glass film, preparation method of self-cleaning glass and product obtained through preparation method

A self-cleaning, glass film technology, applied in the direction of coating, etc., can solve the problems of uneven distribution of nanoparticles, poor film cleaning effect, and affecting film quality, etc., and achieve good hydrophilicity, easy industrial production, and firm combination Effect

Inactive Publication Date: 2016-10-12
UNIV OF JINAN
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

One of the existing technologies is to cover a layer of highly hydrophilic or highly hydrophobic film on the glass surface at high temperature, which is expensive
Another method is to coat the surface with TiO 2 Photocatalyst layer, this method is low in cost, but the duration is short and the effect is relatively poor
At present, most of the existing technologies use TiO 2 or SiO 2 Nanoparticles are directly coated on the glass surface to form a self-cleaning film. For example, the published patent CN103468086A discloses a method using TiO 2 or SiO 2 films made of nanoparticles, these films incorporate TiO 2 or SiO 2 Nanoparticle

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] (1) Add 1mL tetrabutyl titanate and 4mL tetraethyl orthosilicate to 30mL ethanol, stir at 40°C for 10 hours to obtain a transparent solution;

[0027] (2) Add 50 mL of water and 50 μL of hydrochloric acid to the transparent solution obtained in step (1), and stir at room temperature for 5 hours to obtain a transparent solution;

[0028] (3) Concentrate the transparent solution obtained in step (2) to 56mL with a rotary evaporator to obtain a liquid self-cleaning glass film;

[0029] (4) Spray the liquid self-cleaning glass film obtained in step (3) on the glass surface, and obtain self-cleaning glass after drying. The glass film on the surface of the self-cleaning glass is uniform, transparent and smooth without cracks. The transparent solution obtained in step (2) is directly sprayed onto the glass surface without concentration, and the glass film formed after drying is cracked.

Embodiment 2

[0031] (1) Add 0.21mL tetrabutyl titanate and 3.9mL methyl orthosilicate to 40mL ethanol, stir at 40°C for 10 hours to obtain a transparent solution;

[0032] (2) Add 42 mL of water and 42 μL of hydrochloric acid to the transparent solution obtained in step (1), and stir at room temperature for 5 hours to obtain a transparent solution;

[0033] (3) Concentrate the transparent solution obtained in step (2) to 52mL with a rotary evaporator to obtain a liquid self-cleaning glass film;

[0034] (4) Spin-coat the liquid self-cleaning glass film obtained in step (3) onto the glass surface, and obtain self-cleaning glass after drying. The glass film on the surface of the self-cleaning glass is uniform, transparent and smooth without cracks.

Embodiment 3

[0036] (1) Add 0.5mL tetrabutyl titanate and 4mL orthopropyl silicate to 30mL ethanol, stir at 40°C for 10 hours to obtain a transparent solution;

[0037] (2) Add 23 mL of water and 45 μL of hydrochloric acid to the transparent solution obtained in step (1), and stir at room temperature for 5 hours to obtain a transparent solution;

[0038] (3) Concentrate the transparent solution obtained in step (2) to 40mL with a rotary evaporator to obtain a liquid self-cleaning glass film;

[0039] (4) Apply the liquid self-cleaning glass film obtained in step (3) to the surface of the glass by printing, and dry to obtain the self-cleaning glass. The glass film on the surface of the self-cleaning glass is uniform, transparent and smooth without cracks.

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PUM

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Abstract

The invention discloses a liquid self-cleaning glass film, a preparation method of self-cleaning glass and a product obtained through the preparation method. The preparation method comprises the preparation steps of mixing butyl titanate, alkoxysilane and ethanol, and performing stirring until the butyl titanate and the alkoxysilane are uniformly and sufficiently mixed so as to obtain a clear solution; adding water and acid, performing continuous stirring until the butyl titanate and the alkoxysilane are sufficiently hydrolyzed; after sufficient hydrolyzing, concentrating the obtained solution, obtaining a liquid self-cleaning glass film, coating the surface of the glass with the glass film, and drying so as to obtain the self-cleaning glass. The method is performed at the room temperature, and simple in technology; the glass film and a glass base material are firmly combined, so that the self-cleaning capacity is high, the hydrophilicity is good, the photodegradation organic pollutant is good in effect, and the service life is long. Compared with a conventional method, the preparation method disclosed by the invention has the advantages that the technology is simple, the cost is low, the industrialized production is facilitated, and the liquid self-cleaning glass film can be widely applied in the fields of glass curtain walls, window glass, solar power plants and the like.

Description

technical field [0001] The invention relates to a preparation method of a liquid self-cleaning glass film and the obtained liquid self-cleaning glass film, and also relates to a preparation method of the self-cleaning glass and the obtained self-cleaning glass, belonging to the technical field of nano-coating self-cleaning. Background technique [0002] Environmental pollution seriously affects people's normal life and disturbs the development of social economy. The pollution of the outer surface of the building not only affects the appearance of the building, but also increases the maintenance cost. Stain resistance has become an important factor for evaluating the quality of building exterior wall coatings. Indicators; and for the current various solar power plants, they are also troubled by cleaning problems, and directly affect the power generation. Therefore, self-cleaning has become a hot spot, and coating a layer of transparent self-cleaning coating directly on the gl...

Claims

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Application Information

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IPC IPC(8): C03C17/23
CPCC03C17/23C03C2217/70C03C2218/113
Inventor 杨萍王刚车全德
Owner UNIV OF JINAN
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