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A kind of nano-silver antibacterial material and preparation method thereof

A nano-silver antibacterial and nano-silver particle technology, which is applied to nano-silver antibacterial materials and the preparation field of the above-mentioned nano-silver antibacterial materials, can solve problems such as the preparation process of nano-silver composite materials and the limited mechanical strength of nano-silver composite materials, and achieve Improved antibacterial stability, less environmental impact, and improved mechanical properties

Active Publication Date: 2018-11-06
宁波国际材料基因工程研究院有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The existing technology is only limited screening of the ratio of silver particles and matrix materials within a limited range, and the composite material with better antibacterial effect and mechanical properties in the selected ratio is selected. The prepared nano-silver composite material has limited mechanical strength, and Chemical cross-linking agents such as epichlorohydrin and glutaraldehyde are often used to cross-link the prepared membrane materials, which is contrary to the "green" preparation process of nano-silver composite materials.

Method used

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  • A kind of nano-silver antibacterial material and preparation method thereof
  • A kind of nano-silver antibacterial material and preparation method thereof
  • A kind of nano-silver antibacterial material and preparation method thereof

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Embodiment 1

[0038] By weight, the nano-silver antibacterial material of the present embodiment comprises the following components:

[0039]

[0040] The preparation method of nano-silver antibacterial material in the present embodiment comprises the following steps:

[0041] (1) Preparation of Dialdehyde Sodium Alginate

[0042] Dissolve sodium alginate and sodium periodate in deionized water at a weight ratio of 1:0.1, and react in the dark for 6 hours at room temperature. The product is precipitated with ethanol, washed and dried in a vacuum environment at 35°C to obtain dialdehyde alginic acid sodium;

[0043] (2) Preparation of nano-silver particles-dialdehyde sodium alginate-casein composite material

[0044] Dissolve dialdehyde sodium alginate, casein, and silver nitrate in deionized water, and stir evenly to form a premixed solution. During this process, dialdehyde sodium alginate and casein undergo a cross-linking reaction, and at the same time, silver ions are The premixed ...

Embodiment 2

[0053] By weight, the nano-silver antibacterial material of the present embodiment comprises the following components:

[0054]

[0055] The preparation method of nano-silver antibacterial material in the present embodiment comprises the following steps:

[0056] (1) Preparation of Dialdehyde Sodium Alginate

[0057] Dissolve sodium alginate and sodium periodate in deionized water at a weight ratio of 1:0.5, and react in the dark for 24 hours at room temperature. The product is precipitated with acetone, washed and dried in a vacuum environment at 50°C to obtain dialdehyde alginic acid sodium;

[0058] (2) Preparation of nano-silver particles-dialdehyde sodium alginate-casein composite material

[0059] Dissolve dialdehyde sodium alginate, casein, and silver nitrate in deionized water, and stir evenly to form a premixed solution. During this process, dialdehyde sodium alginate and casein undergo a cross-linking reaction, and at the same time, silver ions are The premixed...

Embodiment 3

[0067] By weight, the nano-silver antibacterial material of the present embodiment comprises the following components:

[0068]

[0069]

[0070] The preparation method of nano-silver antibacterial material in the present embodiment comprises the following steps:

[0071] (1) Preparation of Dialdehyde Sodium Alginate

[0072] Dissolve sodium alginate and sodium periodate in deionized water at a weight ratio of 1:0.3, and react in the dark for 10 hours at room temperature. The product is precipitated with ether, washed and dried in a vacuum environment at 45°C to obtain dialdehyde alginic acid sodium;

[0073] (2) Preparation of nano-silver particles-dialdehyde sodium alginate-casein composite material

[0074] Dissolve dialdehyde sodium alginate, casein, and silver nitrate in deionized water, and stir evenly to form a premixed solution. During this process, dialdehyde sodium alginate and casein undergo a cross-linking reaction, and at the same time, silver ions are Th...

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Abstract

The invention relates to a nano-silver antibacterial material and preparation method for the same. According to the material, dialdehyde sodium alginate and casein are cross-linked in situ to form a composite material matrix with a network structure, and in a forming process of the material matrix, silver ions are reduced into silver nanoparticles in situ for uniform dispersion in the cross-linked network structure of the matrix by virtue of aldehyde groups in the dialdehyde sodium alginate, so that the antibacterial stability of the material is improved; the material is further cross-linked by virtue of calcium ions to form a network structure between the calcium ions and the dialdehyde sodium alginate, and the structure is combined with the cross-linked network structure formed between the dialdehyde sodium alginate and the casein to form a dual-network structure to reinforce the network structure between the dialdehyde sodium alginate and the casein, so that the mechanical performance of the material is improved, and the durability of the material is improved; a preparation process is environment-friendly, and the prepared material has better antibacterial effects on gram-positive bacteria and gram-negative bacteria.

Description

technical field [0001] The invention relates to the technical field of nano-silver composite materials, in particular to a nano-silver antibacterial material, and also relates to a preparation method of the nano-silver antibacterial material. Background technique [0002] With the development of science and technology and people's higher and higher requirements for healthy life, antibacterial technology and antibacterial materials have received extensive attention. As an antibacterial material, silver has a long history, but its weak bactericidal effect and wide antibacterial spectrum limit its application. Nano-silver has the advantages of broad-spectrum, long-lasting, and safety that cannot be compared with traditional silver-based antibacterial materials, and its application prospects are very broad. [0003] At present, the preparation of nano silver is mainly divided into physical method and chemical reduction method. Among them, physical methods mainly include laser ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L5/04C08L89/00C08K3/08C08K3/16C08B37/04
CPCC08B37/0084C08K2201/011C08L5/04C08L89/005C08L2203/02C08L2205/04C08L2312/00C08K2003/0806C08K2003/162
Inventor 李楠楠向勇
Owner 宁波国际材料基因工程研究院有限公司
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