A kind of preparation method of high-purity urinary follicle-stimulating hormone
A high-purity technique for urofollitropin, which is applied in the field of extraction and preparation of urofollitropin, can solve the problems of high price of antibody immunoaffinity chromatography column, contamination of heterologous proteins, hindering application and promotion, etc.
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Embodiment 1
[0039] Such as figure 1 As shown, the crude product of HMG (manufactured by our company, batch number Z0203150901) is used as the starting material, its FSH biological potency is 30IU / mg, LH biological potency is 28IU / mg, and FSH specific activity is 43IU / mg protein.
[0040] 1. Capto DEAE anion exchange chromatography
[0041] Dissolve 8.0g HMG crude product with 200ml water, adjust the pH value of solution to 7.5, this solution loading sample is to the Capto DEAE chromatographic column (purchased from GE company) that column volume is 250ml, chromatographic column is pre-used with equilibrium liquid (0.02 M PB, pH7.5) is well balanced; after loading the sample, wash the unadsorbed protein with the equilibrium solution, and detect the absorbance value of the washing solution at 280nm until the absorbance value no longer decreases; then use the eluent (0.02M PB +0.15MNaCl) to elute FSH, and detect the absorbance value of the eluent at 280nm until the absorbance value no longe...
Embodiment 2
[0052] Using low-purity HMG (manufactured by our company, batch number Z0203150901) as the starting material, its FSH biological potency is 30IU / mg, LH biological potency is 28IU / mg, and FSH specific activity is 43IU / mg protein.
[0053] 1. Capto DEAE anion exchange chromatography
[0054] Dissolve 20g HMG with 500ml of water, adjust the pH value of solution 1 to 7.5, this solution loads the sample to the Capto DEAE chromatographic column (purchased from GE company) that column volume is 630ml, chromatographic column is pre-used with equilibrium liquid (0.02M PB , pH7.5) well balanced; after loading the sample, wash the unadsorbed protein with the balance solution, and detect the absorbance value of the washing solution at 280nm until the absorbance value no longer decreases; then use the eluent (0.02M PB+0.15 M NaCl) to elute FSH, and detect the absorbance value of the eluate at 280nm until the absorbance value no longer decreases, collect a total of 2.5L of the eluate efflue...
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