One-step synthetic method for carbon dot/poly(1,4-diphenyldiacetylene) hybrid photocatalysis material

A technology of diphenylbutadiyne and photocatalytic material, applied in the field of nanomaterials, can solve the problem of difficulty in mass production of poly-1,4-diphenylbutadiyne, and achieve excellent visible light absorption and excellent photocatalytic performance. , is conducive to the effect of industrial large-scale production

Inactive Publication Date: 2016-12-14
ZHONGBEI UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0004] The purpose of the present invention is to solve the difficulties of mass production of existing poly-1,4-diphenylbutadiyne, and provide a one-step synthesis of carbon dots / poly-1,4-diphenylbutadiyne hybrid photocatalytic material Methods

Method used

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  • One-step synthetic method for carbon dot/poly(1,4-diphenyldiacetylene) hybrid photocatalysis material
  • One-step synthetic method for carbon dot/poly(1,4-diphenyldiacetylene) hybrid photocatalysis material
  • One-step synthetic method for carbon dot/poly(1,4-diphenyldiacetylene) hybrid photocatalysis material

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Effect test

Embodiment 1

[0022] A method for synthesizing carbon dots / poly-1,4-diphenylbutadiyne hybrid photocatalytic material in one step, adopts the following steps:

[0023] (1) Take 1 gram of 1,4-diphenylbutadiyne solid powder, and evenly disperse it to the bottom of a 250 ml hydrothermal reaction kettle with a thickness of 3mm;

[0024] (2) Put the lined tank filled with 1,4-diphenylbutadiyne solid powder into the steel tank and then vacuumize it so that the internal pressure is less than 0.1 atmosphere, and then fill it with a mixed gas of oxygen and nitrogen to 1 Atmospheric pressure, finally sealed, wherein the volume ratio of oxygen to nitrogen is 2;

[0025] (3) Put the sealed reaction kettle into a blast oven, keep it warm at 95°C for 50 minutes, and then cool it to room temperature to obtain a hybrid photocatalyst of conductive poly-1,4-diphenylbutadiyne and carbon dots Material.

[0026] The performance test and characterization of the synthesized carbon dots / poly-1,4-diphenylbutadiene...

Embodiment 2

[0028] A method for synthesizing carbon dots / poly-1,4-diphenylbutadiyne hybrid photocatalytic material in one step, adopts the following steps:

[0029] (1) Take 1.5 grams of 1,4-diphenylbutadiyne solid powder, and evenly disperse it to the bottom of a 250 ml hydrothermal reaction kettle with a thickness of 5mm;

[0030] (2) Put the lined tank filled with 1,4-diphenylbutadiyne solid powder into the steel tank and then vacuumize it so that the internal pressure is less than 0.1 atmosphere, and then fill it with a mixed gas of oxygen and nitrogen to 1 Atmospheric pressure, finally sealed, wherein the volume ratio of oxygen to nitrogen is 3;

[0031] (3) Put the sealed reactor into a blast oven, keep it warm at 135°C for 150 minutes, and then cool it to room temperature to obtain a hybrid photocatalyst of conductive poly-1,4-diphenylbutadiyne and carbon dots Material.

Embodiment 3

[0033] A method for synthesizing carbon dots / poly-1,4-diphenylbutadiyne hybrid photocatalytic material in one step, adopts the following steps:

[0034] (1) Take 2 grams of 1,4-diphenylbutadiyne solid powder, and evenly disperse it to the bottom of a 250 ml hydrothermal reaction kettle with a thickness of 7 mm;

[0035] (2) Put the lined tank filled with 1,4-diphenylbutadiyne solid powder into the steel tank and then vacuumize it so that the internal pressure is less than 0.1 atmosphere, and then fill it with a mixed gas of oxygen and nitrogen to 1 Atmospheric pressure, finally sealed, wherein the volume ratio of oxygen to nitrogen is 2;

[0036] (3) Put the sealed reactor into a blast oven, keep it warm at 120°C for 100 minutes, and then cool it to room temperature to obtain a hybrid photocatalyst of conductive poly-1,4-diphenylbutadiyne and carbon dots Material.

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Abstract

The invention discloses a one-step synthetic method for a carbon dot / poly(1,4-diphenyldiacetylene) hybrid photocatalysis material. According to the method, a 1,4-diphenyldiacetylene molecule functions as both monomer for formation of poly(1,4-diphenyldiacetylene) and a carbon source for formation of carbon dots; and the conductive carbon dot / poly(1,4-diphenyldiacetylene) hybrid photocatalysis material is prepared through three steps, i.e., mixing, sealing, and heat preservation and cooling. The method provided by the invention does not need a soft template and an initiator; a synthesized carbon dot / poly(1,4-diphenyldiacetylene) hybrid structure has more excellent visible light absorption capability and photocatalysis performance; and the method is free of complex purification, easier to control and beneficial for industrial large-scale production.

Description

technical field [0001] The invention belongs to the technical field of nanometer materials, and in particular relates to a method for synthesizing a carbon dot / poly-1,4-diphenylbutadiyne hybrid photocatalytic material in one step. Background technique [0002] Carbon dots are a new type of zero-dimensional carbon nanomaterials, which often contain hydrogen, oxygen, and nitrogen elements in addition to carbon elements. It not only has many excellent properties similar to traditional semiconductor quantum dots, but also can be used as an electron donor and acceptor to hybridize with other nanostructures or materials, thereby improving the overall performance of the material. An effective way to prepare carbon dots is to use the carbonization process of organic molecules, that is, at a suitable temperature, the hydrogen in the organic molecules reacts with oxygen in the molecules or provided by the outside to form water, and the original molecular structure is destroyed and rec...

Claims

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Application Information

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IPC IPC(8): B01J31/06
CPCB01J31/069B01J37/084B01J35/39
Inventor 胡胜亮常青孟勋韩雪军薛超瑞董英鸽杨金龙
Owner ZHONGBEI UNIV
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