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A kind of water-based pressure-sensitive adhesive and preparation method thereof

A pressure-sensitive adhesive, water-based technology, applied in the direction of adhesives, grafted polymer adhesives, adhesive types, etc., can solve environmental pollution and other problems, and achieve the effect of high peeling force

Active Publication Date: 2018-07-24
珠海格力绿色再生资源有限公司 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The embodiment of the present invention aims to provide a water-based pressure-sensitive adhesive and its preparation method that can be applied to polyvinyl chloride advertising stickers, and its purpose is to solve the problem that the existing pressure-sensitive adhesives used in PVC advertising stickers are solvent-based pressure-sensitive adhesives. , will bring technical problems of environmental pollution

Method used

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  • A kind of water-based pressure-sensitive adhesive and preparation method thereof
  • A kind of water-based pressure-sensitive adhesive and preparation method thereof
  • A kind of water-based pressure-sensitive adhesive and preparation method thereof

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preparation example Construction

[0028] The present invention also provides the preparation method of the water-based pressure-sensitive adhesive, please refer to figure 1 , the preparation method comprises the steps of:

[0029] S11: Weighing the resin, the resin is composed of a first resin, a second resin and a UV monomer.

[0030] Wherein, when the UV monomer is hexanediol diacrylate, the quality of hexanediol diacrylate is 3.5-8% of the total mass of the resin; when the UV monomer is trimethylol propane tripropionate, the trihydroxy The mass of methylpropane tripropionate is 2-7% of the total mass of the resin, and when the UV monomer is triethylene glycol dimethacrylate, the mass of triethylene glycol dimethacrylate is 2.5% of the total mass of the resin -6%;

[0031] S12: adding an emulsifier and an initiator to the first resin and the UV monomer.

[0032] S13: Adding deionized water, and then stirring, and obtaining pre-emulsified monomer without delamination after standing, the mass ratio of the d...

Embodiment 1

[0040] The resin is weighed, and the resin is composed of a first resin, a second resin and a UV monomer. The first resin composition is: methyl methacrylate, acrylic acid, butyl acrylate, and ethyl acrylate. The second resin composition is: butyl acrylate and methyl methacrylate.

[0041] In the first step, the first resin and UV monomer are pre-emulsified. The emulsifier is BYK306, and the addition amount is 1% of the total amount of the resin; the initiator is ammonium persulfate, and the addition amount is 1% of the total amount of the resin. 2.5%.

[0042] In the first resin, the addition of methyl methacrylate is 30% of the total amount of the resin, the addition of acrylic acid is 1% of the total amount of the resin; the addition of butyl acrylate is the total amount of the resin 42%, the addition of ethyl acrylate is 16% of the total amount of the resin;

[0043] The UV monomer is hexanediol diacrylate, and the addition amount is 3.5% of the total amount of the resi...

Embodiment 2

[0050] The resin is weighed, and the resin is composed of a first resin, a second resin and a UV monomer. The first resin composition is: methyl methacrylate, acrylic acid, butyl acrylate, and ethyl acrylate. The second resin composition is: butyl acrylate and methyl methacrylate.

[0051] In the first step, the first resin and UV monomer are pre-emulsified. The emulsifier is BYK306, and the addition amount is 1% of the total amount of the resin; the initiator is ammonium persulfate, and the addition amount is 1% of the total amount of the resin. 2.5%.

[0052] In the first resin, the addition of methyl methacrylate is 30% of the total amount of the resin, the addition of acrylic acid is 1% of the total amount of the resin; the addition of butyl acrylate is the total amount of the resin 40%, the addition of ethyl acrylate is 16% of the total amount of the resin;

[0053] The UV monomer is hexanediol diacrylate, the addition amount is 5.5% of the total amount of the resin, a...

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Abstract

The invention relates to the field of adhesives, and discloses a water-based pressure-sensitive adhesive. The raw materials of the water-based pressure-sensitive adhesive include: resin, emulsifier and initiator; wherein, the resin includes UV monomer; the UV monomer is hexanediol diacrylate, trimethylol propane tripropionate or triethylene glycol Glycol dimethacrylate, wherein, the mass of hexanediol diacrylate is 3.5-8% of the total mass of the resin, the mass of trimethylolpropane tripropionate is 2-7% of the total mass of the resin, triethylene diacrylate The mass of alcohol dimethacrylate is 2.5%-6% of the total mass of the resin. The water-based pressure-sensitive adhesive has the characteristics of high peeling force and can be applied to polyvinyl chloride advertising stickers.

Description

technical field [0001] The embodiments of the present invention relate to the field of adhesives, in particular to a water-based pressure-sensitive adhesive and a preparation method thereof. Background technique [0002] Acrylic pressure-sensitive adhesive is an acrylate copolymer obtained by copolymerizing various acrylate monomers. It is a very important type of resin-type pressure-sensitive adhesive. Compared with rubber-type pressure-sensitive adhesives, they have many advantages: the appearance is colorless and transparent and has good weather resistance; generally, good pressure-sensitive bonding can be obtained without the use of additives such as tackifying resins, softeners and anti-aging agents Performance; Copolymerization and crosslinking can be used to prepare pressure-sensitive adhesives that meet various performance requirements. In the past 20 years, this type of pressure-sensitive adhesive has developed very rapidly and has replaced the dominance of natural...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09J151/00C08F265/04C08F222/14
CPCC09J151/003C08F265/04C08F222/102C08F222/103
Inventor 吴钦文刘劲业周文斌王九飙康露郭鸿钊黄家榆陈莲
Owner 珠海格力绿色再生资源有限公司
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