A kind of preparation method of positive electrode of lithium-ion secondary battery for electric toothbrush or electric shaver
An electric shaver, electric toothbrush technology, applied in secondary batteries, electrode manufacturing, battery electrodes, etc., can solve the problems of prolonging the use time of lithium batteries, short use time, long storage time, etc., to reduce self-discharge phenomenon, Avoid decomposition and reduce the effect of side reactions
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Embodiment 1
[0030] (1) Preparation of LiMPO with Ir-doped surface of positive electrode active material 4 , M is Co 1 / 3 Ni 1 / 3 Mn 1 / 3 , The core of the positive active material is LiMPO 4 , The shell is LiCo 1 / 3-x Ni 1 / 3 Mn 1 / 3 Ir x PO 4 , X=0.02.
[0031] Step 1. After preparing cobalt nitrate, nickel nitrate, manganese nitrate and phosphoric acid in a ratio of 1 / 3:1 / 3:1 / 3:1, add ethylene glycol and put it into a ball milling tank, using zirconium balls as the ball milling medium Perform ball milling and mixing. The ball milling speed is 200r / min and the ball milling time is 4 hours. Then, it is washed alternately with deionized water and ethanol and dried to obtain mixture A. The cobalt nitrate, nickel nitrate, manganese nitrate, iridium nitrate and phosphoric acid / 3-x): 1 / 3:1 / 3:x:1, add ethylene glycol, put it into the ball milling tank, use zirconium balls as the ball milling medium for ball milling and mixing, the ball milling speed is 300r / min, The ball milling time is 3 hours, and ...
Embodiment 2
[0040] (1) Preparation of LiMPO with Ir-doped surface of positive electrode active material 4 , M is Co 1 / 3 Ni 1 / 3 Mn 1 / 3 , The core of the positive active material is LiMPO 4 , The shell is LiCo 1 / 3 Ni 1 / 3-x Mn 1 / 3 Ir x PO 4 , X=0.03.
[0041] Step 1. After preparing cobalt chloride, nickel chloride, manganese chloride and phosphoric acid in a ratio of 1 / 3:1 / 3:1 / 3:1, add ethylene glycol and put it into a ball mill tank, and use zirconium balls For ball milling media, the ball milling speed is 300r / min, and the ball milling time is 3 hours. Then it is washed alternately with deionized water and ethanol and dried to obtain mixture A. Combine cobalt chloride, nickel chloride, manganese chloride, and chlorine After preparing the iridium and phosphoric acid in the ratio of 1 / 3: (1 / 3-x): 1 / 3: x:1, add ethylene glycol, put it into the ball milling tank, and use the zirconium ball as the ball milling medium for ball milling. The ball milling speed is 350r / min, and the ball milling ti...
Embodiment 3
[0050] (1) Preparation of LiMPO with Ir-doped surface of positive electrode active material 4 , M is Co 1 / 3 Ni 1 / 3 Mn 1 / 3 , The core of the positive active material is LiMPO 4 , The shell is LiCo 1 / 3 Ni 1 / 3 Mn 1 / 3-x Ir x PO 4 , X=0.04.
[0051] Step 1. After preparing cobalt chloride, nickel chloride, manganese chloride and phosphoric acid in a ratio of 1 / 3:1 / 3:1 / 3:1, add ethylene glycol and put it in a ball mill tank. For ball milling media, the ball milling speed is 300r / min, and the ball milling time is 3 hours. Then it is washed alternately with deionized water and ethanol and dried to obtain mixture A. Combine cobalt chloride, nickel chloride, manganese chloride, and chlorine After preparing the iridium and phosphoric acid in the ratio of 1 / 3: 1 / 3: (1 / 3-x): x:1, add ethylene glycol and put it into the ball milling tank. Use zirconium balls as the ball milling medium for ball milling and mixing. The ball milling speed is 350r / min, and the ball milling time is 2 hours. Then, ...
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