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Method for preparing composite dielectric elastomers with high charge induction properties

A dielectric elastomer and charge induction technology, applied in the field of dielectric elastomer preparation, can solve the problems of low dielectric constant of composite dielectric elastomer, affecting response rate, low dielectric constant, etc., so as to improve mechanical properties, Good stability and high electro-deformation effect

Inactive Publication Date: 2017-05-10
CHANGZHOU DINGRI ENVIRONMENTAL PROTECTION TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The technical problem to be solved by the present invention: Aiming at the problem that the silicone rubber composite dielectric elastomer prepared in the prior art has a low dielectric constant and weak charge induction due to the non-polar molecule of silicone rubber, provide A method of preparing magnetic hydrogel particles, absorbing and drying the humic acid solution to prepare humic acid-rich gel particles, because humic acid provides negatively charged ligands in the reaction to interact with positively charged The metal ion complexation of the charge can directly act as a ligand, so it can affect the electrical properties, and then affect the response rate of the silicone rubber dielectric composite elastomer to the charge, effectively improving the low dielectric constant of the composite dielectric elastomer, and the charge induction. weaker question

Method used

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Examples

Experimental program
Comparison scheme
Effect test

example 1

[0016] First, weigh 0.3g of N,N'-methylenebisacrylamide, 22g of (3-acrylamidopropyl)trimethylammonium chloride and 8mL of deionized water in a three-necked flask, stir and mix for 25min, then the three-necked flask Add 2g of nanometer iron ferric oxide particles and 1g of potassium persulfate, and heat in a water bath at 65°C for 25min to prepare a magnetic gel; freeze-dry and grind the magnetic gel prepared above to collect the magnetic gel Particles, then put the humic acid powder in deionized water according to the mass ratio of 1:500, stir and mix and filter with a 0.45 μm microporous membrane, collect the filtrate to prepare a humic acid solution, then according to the mass ratio of 1:10, Stir and mix the magnetic gel particles and the humic acid solution, let it stand and age at room temperature for 20 hours, then filter and collect the filter cake, and vacuum freeze-dry to prepare the humic acid adsorption gel particles; weigh 5g of silicone rubber and put it in 80mL In...

example 2

[0018] First weigh 0.4g of N,N'-methylenebisacrylamide, 23g of (3-acrylamidopropyl)trimethylammonium chloride and 9mL of deionized water in a three-necked flask, stir and mix for 27min, then the three-necked flask Add 2g of nanometer iron ferric oxide particles and 2g of potassium persulfate, and heat in a water bath at 67°C for 27 minutes to prepare a magnetic gel; freeze-dry and grind the magnetic gel prepared above to collect the magnetic gel Particles, then put the humic acid powder in deionized water according to the mass ratio of 1:500, stir and mix and filter with a 0.45 μm microporous membrane, collect the filtrate to prepare a humic acid solution, then according to the mass ratio of 1:10, Stir and mix the magnetic gel particles and humic acid solution, let stand and age at room temperature for 22 hours, then filter and collect the filter cake, and vacuum freeze-dry to prepare humic acid adsorption gel particles; weigh 7g of silicone rubber and place in 90mL In tetrahy...

example 3

[0020] First, weigh 0.5g of N,N'-methylenebisacrylamide, 25g of (3-acrylamidopropyl)trimethylammonium chloride and 10mL of deionized water in a three-necked flask, stir and mix for 30min, and then the three-necked flask Add 3g of nanometer iron ferric oxide particles and 2g of potassium persulfate, and heat in a water bath at 70°C for 30 minutes to prepare a magnetic gel solution; freeze-dry and grind the magnetic gel solution prepared above, and collect the magnetic gel Particles, then put the humic acid powder in deionized water according to the mass ratio of 1:500, stir and mix and filter with a 0.45 μm microporous membrane, collect the filtrate to prepare a humic acid solution, then according to the mass ratio of 1:10, Stir and mix the magnetic gel particles and the humic acid solution, let it stand and age at room temperature for 24 hours, then filter and collect the filter cake, and vacuum freeze-dry to prepare the humic acid adsorption gel particles; weigh 8g of silicone...

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Abstract

The invention relates to a method for preparing composite dielectric elastomers with high charge induction properties, and belongs to the field of technologies for preparing dielectric elastomers. By the aid of the method, the problems of low dielectric constants and weak charge induction of currently prepared composite dielectric elastomers with silicone rubber due to the fact that the silicone rubber comprises non-polar molecules can be solved. The method has the advantages that magnetic hydrogel particles are prepared, humic acid solution can be adsorbed and dried by the hydrogel particles to obtain gel particles with abundant humic acid, ligands with negative electricity can be provided by the humic acid during reaction, complexation can be carried out on the ligands and metal ions with positive charge, ligand effects can be directly realized, accordingly the electric properties can be affected, and the charge response speeds of the dielectric composite elastomers with silicone rubber can be subsequently affected; the composite dielectric elastomers with the high charge induction properties are filled with the humic acid adsorption gel particles, accordingly, the mechanical properties of the composite dielectric elastomers which are composite materials can be improved, the composite materials are high in electrodeformation under the condition of low voltages, and the method includes simple preparation steps, is green and safe and is free of pollution.

Description

technical field [0001] The invention relates to a preparation method of a strong charge-sensitive composite dielectric elastomer, belonging to the technical field of dielectric elastomer preparation. Background technique [0002] With the continuous development of high technology, new material technology has become a frontier field of hot exploration and research by scientists, and is the pillar of modern scientific and technological development. Material technology is the key to restricting the development of all engineering fields, and the innovation of new materials leads the emergence and development of revolutionary new technologies. Among them, dielectric materials are a very important class of materials among many new materials, and are the necessary material basis for people's life and production. In a broad sense, dielectric materials refer to all substances that can establish polarization under the action of an electric field. The discovery of ultra-pure semicond...

Claims

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Application Information

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IPC IPC(8): C08L83/04C08L99/00C08L33/24C08K5/57C08K3/22C08F220/60C08F222/38C08F2/44
CPCC08L83/04C08F2/44C08F220/60C08K2201/01C08K2201/011C08L2205/025C08L2205/035C08F222/385C08L99/00C08L33/24C08K5/57C08K2003/2275
Inventor 周丽花蒋玉芳
Owner CHANGZHOU DINGRI ENVIRONMENTAL PROTECTION TECH
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