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Car refinishing paint in blue-phase ultra-black color and preparation method thereof

A technology for automotive refinishing paint and refinishing paint, applied in the field of automotive refinishing paint, can solve the problem of weather resistance and solvent resistance of pigment systems, reduce product blackness and blue phase, and cannot take into account the problems of blackness and blueness, and achieves an optimized color formula , Reduce the cost of color matching, cost-effective effect

Inactive Publication Date: 2017-05-17
DONGLAI COATING TECH SHANGHAI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, black with red and yellow hue is the main color, and black with blue phase is supplemented. However, the occasions where special black with blue phase is used are increasing day by day. Many high-end models use more and more black with black phase. High density, heavy blue phase, clear and pure, no red and yellow phase, black appears turbid, easy to adjust from high blackness to low blackness, easy to adjust from blue phase to red and yellow phase, and vice versa
In order to achieve the characteristics of the blue phase, the existing manufacturers often use the method of mixing and grinding with blue pigments, but this method reduces the purity and blackness of the product, and cannot take into account both blackness and blue phase
[0003] Chinese patent CN 102146245 B discloses a blue-phase special black automotive refinish paint and its preparation method, which is made of the following raw materials in parts by weight: 74.29-78.29 parts of acrylic resin, 2.40-2.60 parts of high pigment carbon black powder, super dispersion aid 1.90-2.10 parts of agent, 0.95-1.05 parts of multiplier, 0.07-0.09 parts of high-pigment dye, 0.45-0.55 part of nano-titanium dioxide, and 16.63-18.63 parts of mixed solvent, but the high-pigment dye and nano-titanium dioxide added in the invention will affect the high-pigment dye and nano-titanium dioxide. The purity of pigment carbon black reduces the blackness and blue phase of the product, and the addition of dyes will affect the weather resistance and solvent resistance of the pigment system

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] Weigh 6.6kg of carbon black pigment M1400 with an electronic scale, add 22kg of 150# solvent oil into a small vat, stir evenly, and soak for 18 hours. Use an electronic scale to weigh acrylic resin 44kg, CAB551-0.2 60kg, CAB531-1 36kg, Efka4310 12kg, gas phase SiO 2 Add 0.6kg into the reaction kettle, stir evenly on a high-speed mixer at 800rpm, add the carbon black solvent mixture soaked in a small tank while stirring, and continue to disperse at 800rpm for 30min after adding. Grind the mixed material once on a horizontal sand mill, and then grind it circularly until the fineness is ≤10μm. Clean the grinder and mixer with 12.8kg of butyl acetate, then add 1kg of leveling agent and 1kg of UV additive, and put it on a high-speed mixer at 600rpm Stir for 20 minutes until uniform, add an appropriate amount of butyl acetate to adjust the viscosity to the acceptable range, and filter to obtain the final blue phase special black paint product.

[0027] The color measuring i...

Embodiment 2

[0029] Weigh 6.9kg of carbon black pigment S90B with an electronic scale, add 21kg of 150# solvent oil into a small vat, stir evenly, and soak for 16 hours. Use an electronic scale to weigh acrylic resin 46kg, CAB551-0.2 58kg, CAB531-1 39kg, 32500 12kg, gas phase SiO 2 Add 0.56kg into the reaction kettle, stir evenly on a high-speed mixer at 800rpm, add the carbon black solvent mixture soaked in a small tank while stirring, and continue to disperse at 800rpm for 25min after adding. Grind the mixed material once on a horizontal sand mill, and then grind it circularly until the fineness is ≤10μm. Clean the grinder and mixer with 13.4kg of butyl acetate, then add 0.96kg of leveling agent and 1.04kg of UV additive, and put it in a high-speed mixer Stir at 600 rpm for 30 minutes until uniform, add appropriate amount of butyl acetate to adjust the viscosity to the acceptable range, and filter to obtain the final blue phase special black paint product.

[0030] The color measurin...

Embodiment 3

[0032] Weigh 6.8kg of carbon black pigment M1300 with an electronic scale, add 23kg of 150# solvent oil into a small vat, stir evenly, and soak for 19 hours. Weigh 45kg of acrylic resin, CAB551-0.2 63kg, CAB531-1 35kg, BYK-16313.5kg, gas phase SiO 2Add 0.55kg into the reaction kettle, stir evenly on a high-speed mixer at 800rpm, add the carbon black solvent mixture soaked in a small tank while stirring, and continue to disperse at 800rpm for 30min after adding. Grind the mixed material once on a horizontal sand mill, and then grind it circularly until the fineness is ≤10μm. Clean the grinder and mixer with 13.7kg of butyl acetate, then add 0.98kg of leveling agent and 0.95kg of UV additive, and put it in a high-speed mixer. Stir at 600 rpm for 20 minutes until uniform, add appropriate amount of butyl acetate to adjust the viscosity to the acceptable range, and filter to obtain the final blue phase special black paint product.

[0033] The color measuring instrument tests the ...

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PUM

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Abstract

The invention relates to a car refinishing paint in a blue-phase ultra-black color and a preparation method thereof. The black paint comprises the following components in parts by weight: 18-26 parts of acrylic resin, 43-53 parts of cellulose acetate butyrate, 4-8 parts of dispersing auxiliary, 0.1-0.5 part of anti-settling agent, 9-13 parts of soaking solvent, 2.5-4.1 parts of pigment, 5-7.8 parts of solvent, 0.1-1 part of flatting agent and 0.1-1 part of UV auxiliary. According to the invention, a high pigment coating system carbon black pigment is adopted; the dispersing auxiliary with special dispersing effect for such a color, compared with the traditional dispersing auxiliary, has an obvious effect; the car refinishing paint can promote the tinting strength, blackness and blue-phase value; the pure black and black pearl color in high blackness can be conveniently and quickly regulated; and compared with the prior art, the car refinishing paint has the advantages of high saturation degree, pure color, sufficient blackness, obvious blue-phase feature and capability of meeting the market requirement for high-class car refinishing paint product.

Description

technical field [0001] The invention relates to an automobile refinish paint, in particular to a blue phase extra black automobile refinish paint and a preparation method thereof. Background technique [0002] According to the survey and statistics of the color and color development trend of automobiles every year, black occupies a large share, including plain black, black pearl, etc., and is one of the most popular colors for consumers. Whether it is the original whole car painting or partial repair, black is a main color masterbatch with a large amount. At present, black with red and yellow hue is the main color, and black with blue phase is supplemented. However, the occasions where special black with blue phase is used are increasing day by day. Many high-end models use more and more black with black phase. It has the characteristics of high density, heavy blue phase, clear and pure, without red and yellow phase, black appears turbid, it is easy to adjust from high blac...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D101/14C09D133/00C09D7/12
CPCC09D101/14C08K2201/003C08K2201/011C08L2205/025C08L2205/03C08L2205/035C09D7/61C08L33/00C08K13/02C08K3/04C08K3/36
Inventor 朱忠敏喻业茂李白
Owner DONGLAI COATING TECH SHANGHAI
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