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High-performance silicone/fluoroether composite rubber glove and preparation method thereof

A technology of fluoroether rubber and composite rubber, which is applied in the field of high-performance silicone/fluoroether composite rubber gloves and its preparation, to achieve excellent oil resistance, excellent high and low temperature resistance, processability, and increased dispersion

Inactive Publication Date: 2017-05-24
顺泰精密橡胶(深圳)有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] However, there are still few researches and reports about the blending of silicone rubber and fluoroether rubber to prepare special rubber-based composite new materials. A high-performance silicone / fluoroether composite rubber glove with excellent performance and can withstand extreme environments to meet the current and future development needs of rubber gloves

Method used

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  • High-performance silicone/fluoroether composite rubber glove and preparation method thereof
  • High-performance silicone/fluoroether composite rubber glove and preparation method thereof
  • High-performance silicone/fluoroether composite rubber glove and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] A high-performance silicone / fluoroether composite rubber glove, comprising a fiber glove liner, coated with a silicon / fluoroether rubber layer on the surface of the fiber glove liner, the silicon / fluoroether rubber layer is impregnated with silicon / fluoroether rubber glue The method of slurry is coated on the surface of the fiber glove lining; wherein the silicon / fluoroether composite rubber is made of the following components in parts by weight: 80 parts of fluoroether rubber, 40 parts of methyl vinyl silicone rubber, and 1 part of oxidation vulcanizing agent DCP, 5 parts of zinc oxide, 15 parts of phenolic resin, 0.5 part of accelerator, 0.1 part of antioxidant 1010, 15 parts of hydroxyethyl methacrylate modified graphene, 3 parts of dioctyl phthalate, 0.8 parts of B-naphthyl-p-phenylenediamine, 50 parts of tetrahydrofuran; wherein, the accelerator is a mixture of accelerator ZBX and accelerator ZDEC in a weight ratio of 1:1.

Embodiment 2

[0028] A high-performance silicone / fluoroether composite rubber glove, comprising a fiber glove liner, coated with a silicon / fluoroether rubber layer on the surface of the fiber glove liner, the silicon / fluoroether rubber layer is impregnated with silicon / fluoroether rubber glue The way of slurry is coated on the surface of the fiber glove lining; wherein the silicon / fluoroether composite rubber is made of the following components in parts by weight: 120 parts of fluoroether rubber, 60 parts of methyl vinyl silicone rubber, and 3 parts of oxidation curing agent DCP, 8 parts of zinc oxide, 30 parts of phenolic resin, 1.5 parts of accelerator, 0.5 part of antioxidant 1010, 30 parts of graphene modified by hydroxyethyl methacrylate, 6 parts of dioctyl phthalate, 1.6 parts of B-naphthyl-p-phenylenediamine, 100 parts of tetrahydrofuran; wherein, the accelerator is a mixture of accelerator ZBX and accelerator ZDEC in a weight ratio of 1:1.

Embodiment 3

[0030] A high-performance silicone / fluoroether composite rubber glove, comprising a fiber glove liner, coated with a silicon / fluoroether rubber layer on the surface of the fiber glove liner, the silicon / fluoroether rubber layer is impregnated with silicon / fluoroether rubber glue The way of slurry is coated on the surface of the fiber glove lining; wherein the silicon / fluoroether composite rubber is made of the following components in parts by weight: 100 parts of fluoroether rubber, 50 parts of methyl vinyl silicone rubber, and 2 parts of oxidation vulcanizing agent DCP, 6 parts of zinc oxide, 24 parts of phenolic resin, 1 part of accelerator, 0.3 part of antioxidant DSTP, 22 parts of hydroxyethyl methacrylate modified graphene, 4 parts of dioctyl phthalate, 1.2 parts of B-naphthyl-p-phenylenediamine, 75 parts of tetrahydrofuran; wherein, the accelerator is a mixture of accelerator ZBX and accelerator ZDEC in a weight ratio of 1:1.

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Abstract

The invention provides a high-performance silicone / fluoroether composite rubber glove. The silicone / fluoroether composite rubber is prepared from the following components in parts by weight: 80 to 120 parts of fluoroether rubber, 40 to 60 parts of methyl vinyl silicone rubber, 1 to 3 parts of a peroxidation vulcanizing agent, 5 to 8 parts of zinc oxide, 15 to 30 parts of phenolic resin, 0.5 to 1.5 parts of an accelerant, 0.1 to 0.5 part of an antioxidant, 15 to 30 parts of hydroxyethyl methylacrylate modified graphene, 3 to 6 parts of dioctyl phthalate, 0.8 to 1.6 parts of B-naphthyl para-phenylenediamine and 50 to 100 parts of tetrahydrofuran. The fluoroether rubber and the silicone rubber are blended and the advantages of the fluoroether rubber and the silicone rubber are completely combined, so the prepared material has excellent high-temperature resistance, corrosion resistance, oil resistance and extremely excellent mechanical property, can be applied to the industrial extreme environment, and creates conditions for application of the future industry.

Description

technical field [0001] The invention belongs to the field of rubber products, in particular to a high-performance silicone / fluoroether composite rubber glove and a preparation method thereof. Background technique [0002] Among the plastic products, gloves occupy a very important position. In addition to being used in industry, agriculture, fishery and household, they are also widely used in the medical field. my country, the United States, Japan, Malaysia and other countries all have glove production, and the product output, scope of application, manufacturers, and enterprise benefits are all considerable. [0003] Silicone rubber refers to the rubber whose main chain is composed of silicon and oxygen atoms alternately, and there are usually two organic groups attached to the silicon atoms. Ordinary silicone rubber is mainly composed of silicone chains containing methyl groups and a small amount of vinyl groups. The introduction of phenyl can improve the high and low temp...

Claims

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Application Information

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IPC IPC(8): D06N3/12D06N3/00C09D127/12C09D183/04C09D161/06C09D7/12C09D5/08
CPCC08L2201/08C08L2205/03C09D5/08C09D5/18C09D7/61C09D7/62C09D7/63C09D127/12D06N3/0059D06N3/0061D06N3/0063D06N3/0086D06N3/128D06N2209/06D06N2209/143D06N2209/145D06N2209/1685D06N2211/103C08L83/04C08L61/06C08K13/06C08K5/14C08K2003/2296C08K9/04C08K3/04C08K5/12C08K5/18C08K5/1345
Inventor 不公告发明人
Owner 顺泰精密橡胶(深圳)有限公司
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