Conductive silver glue, preparation method and application thereof

A technology of conductive silver glue and silver powder, which is applied in the direction of conductive adhesives, adhesives, epoxy resin glue, etc., can solve the problems of reducing bond strength and operating performance, poor storage and transportation performance, and increasing the viscosity of conductive adhesives, etc., to achieve Improve handling performance, improve electrical conductivity, and promote the effect of dispersion

Active Publication Date: 2017-05-31
SHENZHEN INST OF ADVANCED TECH CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although conductive adhesives have replaced tin-lead solders in many electronic fields, there are still some disadvantages: high volume resistivity, insufficient bonding strength, poor storage and transportation performance, etc.
In order to improve the conductivity of conductive adhesives, people often increase the content of metal fillers (65%-90%). Although it can increase its conductivity to a certain extent, it will also lose some mechanical properties due to the reduction of resin content. The viscosity of the conductive adhesive is reduced, the bonding strength and operating performance are reduced, and the cost of the conductive adhesive is greatly increased

Method used

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  • Conductive silver glue, preparation method and application thereof
  • Conductive silver glue, preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0051] A conductive silver glue, comprising the following components by weight:

[0052] Ionic liquids ([BMIM][BF 4 ]) 1 serving

[0053] Silver powder (1~8μm) 80 parts

[0054] Epoxy resin (bisphenol A epoxy resin 828E) 16 parts

[0055] Curing agent (dicyandiamide) 1 part

[0056] Accelerator (1-cyanoethyl-2-ethyl-4-methylimidazole) 0.1 part

[0057] Coupling agent (KH560) 0.1 part

[0058] Diluent (1,4-butanediol diglycidyl ether) 1.75 parts

[0059] Anti-precipitation agent (fumed silica) 0.05 part;

[0060] Preparation:

[0061] Fill the ionic liquid into the epoxy resin according to the formula, stir and defoaming, so that the ionic liquid is fully dispersed, and the first basic resin with uniform components is prepared; diluent, anti-precipitation agent, coupling agent, curing agent, accelerator The silver powder is added to the first base resin according to the formula, and after mixing, it is ground evenly with a three-roll mill, mixed and defoamed to make a s...

Embodiment 2

[0073] The difference from Example 1 is that the conductive silver glue includes the following components in parts by weight:

[0074] Ionic liquids ([HEMIM][BF 4 ]) 1 serving

[0075] Silver powder (1~10μm) 80 parts

[0076] Epoxy resin (bisphenol A epoxy resin 828E) 16 parts

[0077] Curing agent (dicyandiamide) 1 part

[0078] Accelerator (1-cyanoethyl-2-ethyl-4-methylimidazole) 0.1 part

[0079] Coupling agent (KH560) 0.1 part

[0080] Diluent (1,4-butanediol diglycidyl ether) 1.75 parts

[0081] Anti-precipitation agent (fumed silica) 0.05 part;

Embodiment 3

[0083] The difference from Example 1 is that the conductive silver glue includes the following components in parts by weight:

[0084] Ionic liquid ([BMIM][DCA]) 1 part;

[0085] 80 parts of silver powder (3~6μm);

[0086] Epoxy resin (bisphenol A epoxy resin 828E) 16 parts

[0087] Curing agent (dicyandiamide) 1 part

[0088] Accelerator (1-cyanoethyl-2-ethyl-4-methylimidazole) 0.1 part

[0089] Coupling agent (KH560) 0.1 part

[0090] Diluent (1,4-butanediol diglycidyl ether) 1.75 parts

[0091] Anti-precipitation agent (fumed silica) 0.05 part;

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Abstract

The invention relates to conductive silver glue, the conductive silver glue comprises the following components by weight: 0.1-60 parts of an ionic liquid, 50-85 parts of silver powder, 10-50 parts of epoxy resin, 0.5-60 parts of a curing agent, 0.05-5 parts of an accelerator, 0.05-5 parts of a coupling agent, 1-10 parts of a diluent and 0.05-2 parts of an anti settling agent. The ionic liquid with catalytic activity is introduced into a conductive adhesive formula to promote the further curing of the epoxy resin, improve the volume shrinkage rate and greatly improve the conductivity of the conductive silver glue. By addition of the same amount of silver powder, the conductivity of the conductive silver glue is greatly increased (to 10<-5> orders of magnitudes and to reach a higher level in the market); the dispersion of a conductive filler is promoted, the viscosity of the conductive silver glue is reduced, and the operating performance of the product is improved. The method has the advantages of simple operation and low material cost, the cost of the conductive silver glue is reduced, and the conductive silver glue can be widely used in solar cells, integrated circuits and LED packaging and other fields.

Description

technical field [0001] The invention belongs to the field of semiconductor materials, and relates to a conductive silver paste and a preparation method and application thereof. Background technique [0002] As a substitute for traditional packaging materials in the field of electronic packaging - solder, conductive adhesive has many advantages: environmentally friendly, no toxic metals, no need for pre-cleaning and post-solder cleaning in the process; mild curing temperature, which greatly reduces thermal damage to electronic devices and Internal stress, especially suitable for heat-sensitive materials and non-weldable materials; high line resolution, its line resolution below 200μm is more suitable for fine pitch manufacturing. The many advantages of conductive adhesives adapt to the development trend of miniaturization, thinning and integration of electronic devices, and are widely used in IC packaging, LED packaging, solar cells, radio frequency antennas and other microel...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J163/00C09J9/02C09J11/06
CPCC08K3/08C08K5/3445C08K2003/0806C09J9/02C09J11/06C09J163/00
Inventor 孙蓉韩延康朱朋莉张保坦赵涛
Owner SHENZHEN INST OF ADVANCED TECH CHINESE ACAD OF SCI
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