Semi-continuous casting process of vw64m high-strength heat-resistant magnesium alloy billet

A 1. VW64M, casting process technology, applied in the field of magnesium alloy casting, Mg-Gd-Y-Ag-Zn-Zr-Ca series magnesium alloy semi-continuous casting, can solve the problem of reducing the fluidity of the melt, increasing the difficulty of forming, Increase the difficulty of casting and other problems to achieve the effects of eliminating solute atom segregation, accelerating solute atom diffusion, and reducing oxide slag inclusion

Active Publication Date: 2018-12-18
CENT SOUTH UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] In the process of preparing large magnesium alloy ingots by conventional semi-continuous casting, the melt is easily burned, resulting in a large number of defects such as inclusions, pores, porosity, and central cracks inside the ingot, which reduces the quality of the ingot and directly affects the subsequent deformation process and structure. normal use of the
In the casting process of the rare earth magnesium alloy billet, due to the large amount of rare earth added, the density of the melt is increased, the fluidity of the melt is reduced, and the surface of the ingot is severely cold-shocked; the addition of rare earth causes a large amount of metal shrinkage, and the casting thermal stress increases sharply , making various casting defects more likely to appear, especially the penetrating cracks running through the billet, which significantly increases the difficulty of forming
Especially the addition of Zn element increases the tendency of edge cracking and hot cracking, which increases the difficulty of casting

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0015] In a smelting furnace with a capacity of 1 ton, high-purity magnesium ingots are melted, and the temperature of the melt is controlled at 690-700°C during melting. After the magnesium ingots are completely melted, Mg-Ca master alloy and 6# flux are added, and the Ca element accounts for 10% of the alloy mass percentage. 0.01%. Remove scum on molten surface, in SF 6 with CO 2 Under the protection of mixed gas, raise the temperature to 750-780°C, add Mg-Gd master alloy, high-purity zinc, Mg-Y master alloy, Mg-Zr master alloy, high-purity silver in turn, and add 6# flux. After all the raw materials are melted, the scum on the surface of the melt is removed, and argon gas is introduced to stir and degas for 10 minutes. After capping and sealing the melt in SF 6 with CO 2 Adjust the temperature of the melt to 760-770°C under the protection of the hood, and keep it warm for 20 minutes. Turn off the power of the resistance furnace, keep the temperature of the melt at 680-...

Embodiment 2

[0017] In a smelting furnace with a capacity of 1 ton, high-purity magnesium ingots are melted, and the temperature of the melt is controlled at 680-690°C during melting. After the magnesium ingots are melted, Mg-Ca master alloy and 6# flux are added, in which the Ca element accounts for 0.02% by weight of the alloy. %. Remove scum on molten surface, in SF 6 with CO 2 Under the protection of mixed gas, the temperature is raised to 760-790°C, and Mg-Gd master alloy, high-purity zinc, Mg-Y master alloy, Mg-Zr master alloy, high-purity silver are added in sequence, and 6# flux is added. After all the raw materials are melted, the scum on the surface of the melt is removed, and argon gas is introduced to stir and degas for 15 minutes. After capping and sealing the melt in SF 6 with CO 2 Adjust the temperature of the melt to 760-770°C under the protection of the hood, and keep it warm for 25 minutes. Turn off the power of the resistance furnace, keep the temperature of the mel...

Embodiment 3

[0019] In a smelting furnace with a capacity of 1 ton, high-purity magnesium ingots are melted, and the melting temperature is controlled at 670-680°C during melting. After the magnesium ingots are melted, Mg-Ca master alloy and 6# flux are added, and the Ca element accounts for 0.05% of the alloy mass percentage. %. Remove the scum on the surface of the melt and pass it into SF 6 with CO 2 The mixed gas protects the melt and raises the temperature to 760-790°C, then add Mg-Gd master alloy, high-purity zinc, Mg-Y master alloy, Mg-Zr master alloy, high-purity silver, and add 6# flux. After all the raw materials are melted, the scum on the surface of the melt is removed, and argon gas is introduced to stir and degas for 20 minutes. After capping and sealing the melt in SF 6 with CO 2 Adjust the temperature of the melt to 770-780°C under the protection of the hood, and keep it warm for 30 minutes. Turn off the power of the resistance furnace, keep the temperature of the melt...

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Abstract

The invention discloses a semi-continuous casting process of a VW64M high-strength heat-resistant magnesium alloy big ingot blank. An alloy contains, by weight, 5.0-7.0% of Gd, 2.5-4.0% of Y, 0.1-0.3% of Ag, 0.15-1.0% of Zn, 0.25-0.65% of Zr, 0.002-0.050% of Ca and the balance Mg. The process mainly includes the following steps that a magnesium ingot is molten at the temperature ranging from 670 DEG C to 720 DEG C; a Mg-Ca intermediate alloy and a fluxing agent are added; alloy elements are added at the temperature of 750 DEG C to 800 DEG C; refining and slagging-off are performed; gas feeding and stirring are performed; the temperature is adjusted to reach 680 DEG C to 700 DEG C and maintained for still standing for 1.5-3.5 hours; and low-temperature low-speed electromagnetic casting is performed. By coordinating the process parameters of all the steps, the magnesium alloy ingot blank being free of cracks, smooth in surface, small in grain size, uniform in structure and free of solute segregation and having the diameter phi of 300-630 mm and the length of at least 1000 mm is obtained.

Description

technical field [0001] The invention relates to the field of magnesium alloy casting, in particular to the field of semi-continuous casting of Mg-Gd-Y-Ag-Zn-Zr-Ca series magnesium alloy with a diameter of 300-630 mm. Background technique [0002] In recent years, magnesium and magnesium alloys have been used as important structural materials. Their advantages lie in low density, high specific strength, high damping performance, and good cutting performance. They are used in automobiles, information electronics, and aerospace, which require lightweight and high-strength materials. Large-scale magnesium alloy structural parts have broad application prospects. Adding rare earths to magnesium can greatly improve the strength and heat resistance of the alloy, but the plasticity is low. The study found that the Mg-Gd-Y-Ag-Zn-Zr-Ca series magnesium alloy has high strength, good heat resistance, strong plastic deformation ability and high ductility. After plastic deformation, elon...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22C23/06C22C1/03C22C1/06B22D11/115
CPCB22D11/001B22D11/115C22C1/03C22C1/06C22C23/06
Inventor 高永浩王俊凯刘楚明蒋树农王必正余世伦
Owner CENT SOUTH UNIV
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